The analysis of thermoluminescent glow peaks of natural calcite after beta irradiation

In this study, the thermoluminescence properties of natural calcite samples were examined in detail. The glow curve of the sample irradiated with beta radiation shows two main peaks, P1 (at 115 °C) and P4 (at 254 °C). The additive dose, variable heating rate, computer glow curve deconvolution, peak shape and three point methods have been used to evaluate the trapping parameters, namely the order of kinetics (b), activation energy (E) and the frequency factor (s) associated with the dosimetric thermoluminescent glow peaks (P1 and P4) of natural calcite after different dose levels with beta irradiation.     

Application of response surface methodology to optimize and investigate the effects of operating conditions on the performance of DMFC

In this study, the response surface methodology (RSM) has been applied to optimize the operating conditions of direct methanol fuel cell (DMFC). A quadratic model was developed through RSM in terms of related independent variable to describe the current as the response. The input data required in this model has been obtained experimentally. For this purpose, an experimental set up for testing of direct methanol fuel cell has been established to investigate the effects of temperature and flow rate parameters on the cell performance. Two different analyses for operating conditions were performed applying the response surface method to obtain the maximum power. These analyses were based on the unlimited and minimum methanol consumptions. Methanol flow rate, oxygen flow rate, methanol temperature, humidification temperature and cell temperature were the main parameters considered that they were varied between 2 and 50 ml/min, 100-1000 ml/min, 30-70 °C, 30 70 °C and 30-80 °C in the analyses respectively. The maximum current under the unlimited and minimum methanol consumptions was found as 1230 mA and 582 mA based on the contour plots and variance analysis.     

Dissolution study of BAMO/AMMO thermoplastic elastomer for the recycling and recovery of energetic materials

Abstract

This study involves the characterization and dissolution of a thermoplastic elastomer copolymer used as binder in the new generation of energetic materials. The thermoplastic binder is an oxetane based elastomer manufactured by Thiokol Corporation. Since the binder encapsulates other components in an energetic material formulation, its controlled dissolution is crucial to the recovery and recycle of all the energetic material ingredients. The polymeric binder was found to be highly soluble in ethyl acetate and THF. The dissolution rate data obtained under well defined flow dynamics was satisfactorily correlated with the film model. External mass transfer resistance was found to be generally important but became negligible for Reynolds numbers above 6.0×10⁴. The mass transfer coefficients calculated on the basis of the film model were found to be an Arrhenius function of temperature. The activation energy for the dissolution rates was estimated to be 4.8 kcal/mol.     

Physical elution in phage display selection of inorganic-binding peptides

Phage display is a commonly utilized in vivo approach in selecting peptides specific to solid inorganic materials. In this process, traditionally, high affinity peptides are recovered by a chemical elution method, which involves contacting the phage library with the desired inorganic, washing the weak binders, and eluting the tight binders under harsh buffer conditions. This process may result in incomplete removal of all strong binders, separation of the phage from the display protein, or may modify the material surface. To overcome these potential limitations, we developed a physical elution technique based on ultrasonication. Here, we report two optimized ultrasonication protocols by which we selected peptides specific to natural mineral mica. We first performed a 30-s physical elution after the chemical elution step and increased the efficiency of screening strong binders by about 100%. Encouraged by the results, we applied physical elution-only protocol where we obtained 45% of the selected sequences as strong binders. The approach has a far shorter total elution time, i.e., seconds compared to hours in traditional chemical elution. The novel physical elution approach using ultrasonication reported herein can be a highly efficient alternate step in the screening of solid material specific peptides.     

Bloch Lines Constituting Antiskyrmions Captured via Differential Phase Contrast

Much scientific capital has been directed toward exotic magnetic spin textures called Bloch lines, that is, Néel-type line boundaries within domain walls, because their geometry promises high-density magnetic storage. While predicted to arise in high-anisotropy magnets, bulk soft magnets, and thin films with in-plane magnetization, Bloch lines also constitute magnetic antiskyrmions, that is, topological antiparticles of skyrmions. Most domain walls occur as Bloch-type or Néel-type, in which the magnetization rotates parallel or perpendicular to the domain wall across its profile, respectively. The Bloch lines’ Néel-type rotation and their minute size make them difficult to directly measure. This work utilizes differential phase contrast (DPC) scanning transmission electron microscopy (STEM) to measure the in-plane magnetization of Bloch lines within antiskyrmions emergent in a non-centrosymmetric Heusler magnet with D_2d symmetry, Mn_1.4Pt_0.9Pd_0.1Sn, in addition to Bloch-type skyrmions in an FeGe magnet with B20-type crystal structure to benchmark the DPC technique. Both in-focus measurement and identification of Bloch lines at the antiskyrmion's corners are provided.     

In-Plane Magnetic Field-Driven Creation and Annihilation of Magnetic Skyrmion Strings in Nanostructures

In bulk chiral crystals, 3D structures of magnetic skyrmions form topologically protected skyrmion strings (SkS) that have shown potential as magnonic nano-waveguides for information transfer. Although SkS stability is expected to be enhanced in nanostructures of skyrmion-hosting materials, experimental observation and detection of SkS in nanostructures under an applied in-plane magnetic field is difficult. Here, temperature-dependent magnetic field-driven creation and annihilation of SkS in B20 FeGe nanostructures (nanowires and nanoplates) under in-plane magnetic field (H_||) are shown and the mechanisms behind these transformations are explained. Unusual asymmetric and hysteretic magnetoresistance (MR) features are observed but previously unexplained during magnetic phase transitions within the SkS stability regime when H_|| is along the nanostructure's long edge, which increase the sensitivity of MR detection. Lorentz transmission electron microscopy of the SkS and other magnetic textures under H_|| in corroboration with the analysis of the anisotropic MR responses elucidates the field-driven creation and annihilation processes of SkS responsible for such hysteretic MR features and reveals an unexplored stability regime in nanostructures.     

Tunable Néel–Bloch Magnetic Twists in Fe3GeTe2 with van der Waals Structure

The advent of ferromagnetism in 2D van der Waals (vdW) magnets has stimulated high interest in exploring topological magnetic textures, such as skyrmions for use in future skyrmion-based spintronic devices. To engineer skyrmions in vdW magnets by transforming Bloch-type magnetic bubbles into Néel-type skyrmions, a heavy metal/vdW magnetic thin film heterostructure has been made to induce interfacial Dzyaloshinskii–Moriya interaction (DMI). However, the unambiguous identification of the magnetic textures inherent to vdW magnets, for example, whether the magnetic twists (skyrmions/domain walls) are Néel- or Bloch-type, is unclear. Here we demonstrate that the magnetic twists can be tuned between Néel and Bloch-type in the vdW magnet Fe₃GeTe₂ (FGT) with/without interfacial DMI. We use an in-plane magnetic field to align the modulation wavevector q of the magnetizations in order to distinguish the Néel- or Bloch-type magnetic twists. We observe that q is perpendicular to the in-plane field in the heterostructure (Pt/oxidized-FGT/FGT/oxidized-FGT), while q aligns at a rotated angle with respect to the field direction in the FGT thin plate thinned from bulk. We find that the aligned domain wall twists hold fan-like modulations, coinciding qualitatively with our computational results.     

Rule-based inference and decomposition for distributed in-network processing in wireless sensor networks

Wireless sensor networks are application specific and necessitate the development of specific network and information processing architectures that can meet the requirements of the applications involved. A common type of application for wireless sensor networks is the event-driven reactive application, which requires reactive actions to be taken in response to events. In such applications, the interest is in the higher-level information described by complex event patterns, not in the raw sensory data of individual nodes. Although the central processing of information produces the most accurate results, it is not an energy-efficient method because it requires a continuous flow of raw sensor readings over the network. As communication operations are the most expensive in terms of energy usage, the distributed processing of information is indispensable for viable deployments of applications in wireless sensor networks. This method not only helps in reducing the total amount of packets transmitted in the network and the total energy consumed by the sensor nodes, but also produces scalable and fault-tolerant networks. For this purpose, we present two schemes that distribute information processing to appropriate nodes in the network. These schemes use reactive rules, which express relations between event patterns and actions, in order to capture reactive behavior. We also share the results of the performance of our algorithms and the simulations based on our approach that show the success of our methods in decreasing network traffic while still realizing the desired functionality.     

Isogeometric FEM‐BEM coupled structural‐acoustic analysis of shells using subdivision surfaces

We introduce a coupled finite and boundary element formulation for acoustic scattering analysis over thin‐shell structures. A triangular Loop subdivision surface discretisation is used for both geometry and analysis fields. The Kirchhoff‐Love shell equation is discretised with the finite element method and the Helmholtz equation for the acoustic field with the boundary element method. The use of the boundary element formulation allows the elegant handling of infinite domains and precludes the need for volumetric meshing. In the present work, the subdivision control meshes for the shell displacements and the acoustic pressures have the same resolution. The corresponding smooth subdivision basis functions have the C¹ continuity property required for the Kirchhoff‐Love formulation and are highly efficient for the acoustic field computations. We verify the proposed isogeometric formulation through a closed‐form solution of acoustic scattering over a thin‐shell sphere. Furthermore, we demonstrate the ability of the proposed approach to handle complex geometries with arbitrary topology that provides an integrated isogeometric design and analysis workflow for coupled structural‐acoustic analysis of shells.