Analysis of Cs-adsorption behavior using a column filled with microcapsule beads of potassium copper hexacyanoferrate

Ash-washing technology is a crucially important technology for removing radioactive Cs from contaminated ash. For that technology, Cs⁺ removal from the ash-washing solution by the adsorbent is necessary. This study was conducted to establish rapid preparation of appropriate adsorption columns for Cs⁺ uptake. A one-site model was not used for analysis because the model cannot accommodate sites with different adsorption speed. Results demonstrated that the adsorption behavior of the column filled with the granules of potassium copper hexacyanoferrate was well reproduced by a two-site adsorption model with parameters chosen through analysis of batch adsorption test results.     

Gigacycle fatigue data sheets for advanced engineering materials

Gigacycle fatigue data sheets have been published since 1997 by the National Institute for Materials Science. They cover several areas such as high-cycle-number fatigue for high-strength steels and titanium alloys, the fatigue of welded joints, and high-temperature fatigue for advanced ferritic heat-resistant steels. Some unique testing machines are used to run the tests up to an extremely high number of cycles such as 10¹⁰ cycles. A characteristic of gigacycle fatigue failure is that it is initiated inside smooth specimens; the fatigue strength decreases with increasing cycle number and the fatigue limit disappears, although ordinary fatigue failure initiates from the surface of a smooth specimen and a fatigue limit appears. For welded joints, fatigue failure initiates from the notch root of the weld, because a large amount of stress is concentrated at the weld toe. The fatigue strength of welded joints has been obtained for up to 10⁸ cycles, which is an extremely high number of cycles for large welded joints. The project of producing gigacycle fatigue data sheets is still continuing and will take a few more years to complete. r 2007 Published by Elsevier Ltd.     

Sensitivity analysis of fuel pin failure performance under slow-ramp type transient overpower condition by using a fuel performance analysis code FEMAXI-FBR

The FEMAXI-FBR is a fuel performance analysis code and has been developed as one module of core disruptive evaluation system, the ASTERIA-FBR. The FEMAXI-FBR has reproduced the failure pin behavior during slow transient overpower. The axial location of pin failure affects the power and reactivity behavior during core disruptive accident, and failure model of which pin failure occurs at upper part of pin is used by reflecting the results of the CABRI-2 test. By using the FEMAXI-FBR, sensitivity analysis of uncertainty of design parameters such as irradiation conditions and fuel fabrication tolerances was performed to clarify the effect on axial location of pin failure during slow transient overpower. The sensitivity analysis showed that the uncertainty of design parameters does not affect the failure location. It suggests that the failure model with which locations of failure occur at upper part of pin can be adopted for core disruptive calculation by taking into consideration of design uncertainties.     

The effect of electro-degradation processing on microstructure of polyaniline/single-wall carbon nanotube composite films

Mesostructured polyaniline/single-wall carbon nanotube (PAni/SWCNT) composite film has been prepared through electrochemical polymerization/degradation processing. The microstructures of the films are observed before and after electro-degradation. Initial twisty SWCNT bundles are broken down and linked by the polymerization of PAni. Both crystalline and disordered PAni regions coexist in the PAni/SWCNT composite nanowires. The disordered regions are gradually dissolved while the crystalline regions are basically preserved after electro-degradation. The formation mechanism of the composite with special construction has been proposed. In addition, cyclic voltammetry measurements demonstrate that the electroactive performance of PAni/SWCNT composite is enhanced after electro-degradation. It is found that the specific capacitance of electro-degraded composite reaches up to 848.7 F/g, more than twice over the untreated film, which is ascribed to its profitable charge accessible interface and increased available crystalline PAni regions.     

Estimating the unconfined compressive strength of intact rocks from Equotip hardness

In order to utilize the Equotip hardness tester, originally developed in the field of metallic engineering, as an indirect method to predict the unconfined compressive strength (UCS) of rock, laboratory tests were undertaken to establish the UCS, Equotip hardness (L-value) and porosity of nine rock types. Using existing data from Verwaal and Mulder (Int J Rock Mech Min Sci Geomech Abstr 30:659–662, 1993) and the results of laboratory tests, an equation relating UCS (MPa) and L-value obtained from single impacts (L _s) and porosity (n %) was derived, which provides a close approximation of the UCS value. An equation to relate UCS and Equotip hardness is also presented, although this is less accurate. It is considered Equotip testing has advantages over the commonly used Schmidt hammer test.      

Identification of Aloe species by random amplified polymorphic DNA (RAPD) analysis

Juice and integument of leaves of 3 Aloe species, Aloe vera, A. ferox and A. africana, are not allowed to be used as food according to the Pharmaceutical Affairs Law in Japan. On the other hand, whole leaves of A. arborescens can be used as food. The present study was designed to distinguish Aloe species by random amplified polymorphic DNA (RAPD) analysis. DNA was isolated from fresh and dried leaves of the 4 Aloe species. Five out of 32 different 10-mer primers examined were useful for analysis. By comparison of the characteristic bands of PCR products on agarose gel, it was possible to distinguish the 4 species. Thus, the botanical species of Aloe in commercial food products can be identified by RAPD analysis.     

Enhanced Development of Azoxymethane-Induced Colonic Preneoplastic Lesions in Hypertensive Rats

Metabolic syndrome is associated with an increased risk of colorectal cancer. This study investigated the impact of hypertension, a component of metabolic syndrome, on azoxymethane (AOM)-induced colorectal carcinogenesis using SHRSP/Izm (SHRSP) non-diabetic/hypertensive rats and SHRSP.Z-Lepr^fa/IzmDmcr (SHRSP-ZF) diabetic/hypertensive rats. Male 6-week-old SHRSP, SHRSP-ZF, and control non-diabetic/normotensive Wister Kyoto/Izm (WKY) rats were given 2 weekly intraperitoneal injections of AOM (20 mg/kg body weight). Two weeks after the last injection of AOM, the SHRSP and SHRSP-ZF rats became hypertensive compared to the control WKY rats. Serum levels of angiotensin-II, the active product of the renin-angiotensin system, were elevated in both SHRSP and SHRSP-ZF rats, but only the SHRSP-ZF rats developed insulin resistance, dyslipidemia, and hyperleptinemia and exhibited an increase in adipose tissue. The development of AOM-induced colonic preneoplastic lesions and aberrant crypts foci, was significantly accelerated in both SHRSP and SHRSP-ZF hypertensive rats, compared to WKY normotensive rats. Furthermore, induction of oxidative stress and exacerbation of inflammation were observed in the colonic mucosa and systemically in SHRSP and SHRSP-ZF rats. Our findings suggest that hypertension plays a role in the early stage of colorectal carcinogenesis by inducing oxidative stress and chronic inflammation, which might be associated with activation of the renin-angiotensin system.     

Thermal ratcheting of solder-bonded layered plates: cyclic recovery and growth of deflection

This paper describes computational analysis of the thermal ratcheting of solder-bonded layered plates subjected to cyclic thermal loading following solder-bonding. Finite element computations of Si/solder/Cu layered plates are performed by taking into account mechanical ratcheting of the copper as well as temperature-dependent creep of the solder. A sophisticated non-linear kinematic hardening model is used for appropriately representing mechanical ratcheting of the copper; a temperature-dependent power-law creep model is assumed for the solder. It is shown that the layered plates can exhibit either the cyclic recovery or the cyclic growth of deflection depending on the extent of plastic yielding in the copper layer, and that the cyclic recovery always occurs if the copper layer is elastic. It is also demonstrated that the cyclic recovery of deflection can be much greater than the static recovery of deflection at a constant temperature.     

Microstructures and mechanical responses of powder metallurgy non-combustive magnesium extruded alloy by rapid solidification process in mass production

Spinning Water Atomization Process (SWAP), which was one of the rapid solidification processes, promised to produce coarse non-combustible magnesium alloy powder with 1–4 mm length, having fine α-Mg grains and Al₂Ca intermetallic compounds. It had economical and safe benefits in producing coarse Mg alloy powders with very fine microstructures in the mass production process due to its extreme high solidification rate compared to the conventional atomization process. AMX602 (Mg–6%Al–0.5%Mn–2%Ca) powders were compacted at room temperature. Their green compacts with a relative density of about 85% were heated at 573–673 K for 300 s in Ar gas atmosphere, and immediately consolidated by hot extrusion. Microstructure observation and evaluation of mechanical properties of the extruded AMX602 alloys were carried out. The uniform and fine microstructures with grains less than 0.45–0.8 μm via dynamic recrystallization during hot extrusion were observed, and were much small compared to the extruded AMX602 alloy fabricated by using cast ingot. The extremely fine intermetallic compounds 200–500 nm diameter were uniformly distributed in the matrix of powder metallurgy (P/M) extruded alloys. These microstructures caused excellent mechanical properties of the wrought alloys. For example, in the case of AMX602 alloys extruded at 573 K, the tensile strength (TS) of 447 MPa, yield stress (YS) of 425 MPa and 9.6% elongation were obtained.