低成本钛合金制备技术研究进展

为了降低钛合金的生产成本,美、俄、日、中等国家都在此领域进行了广泛的研究。对国际上新出现的以降低钛合金生产成本为目的的新冶金方法、新的低成本合金化钛合金和新的加工生产技术进行了综述。目前,国际上研究较为活跃的低成本钛冶炼新方法有FFC剑桥法、Armstrong工艺、EMR复合阳极工艺、SRI工艺、Idaho钛工艺及OS工艺。其中,以FFC剑桥法为代表的TiO2直接电解还原方法,最有希望成为替代传统Kroll工艺的新方法。     

热型连铸过程的一维稳态传热模型

根据热型连铸技术原理，建立了热型连铸凝固过程一维稳态温度场的物理、数学模型。通过数值计算，得出了铸型出口温度、冷却距离、拉铸速度和喷水冷却强度等工艺参数对铸坯固液界面位置的影响。计算结果与试验结果吻合。     

镁渣膨胀性机理试验研究

通过镁渣形成过程、组成、粉化、颗粒分析和安定性试验,研究了镁渣产生体积膨胀性和膨胀滞后性的机理,提出了减轻或消除其膨胀性和膨胀滞后性危害的方法和措施,为镁渣在建筑、交通、水利等工程领域中的应用提供理论依据和指导。     

Synthesis and Characterization of 2-(Dimethylamino)ethyl Methacrylate Homopolymers via aqueous RAFT Polymerization and Their Application in Miniemulsion Polymerization

Summary Homopolymers of 2-(dimethylamino)ethyl methacrylate (DMAEMA) have been synthesized directly in aqueous media by reversible addition-fragmentation chain transfer polymerization (RAFT) using 4,4-azobis(4-cyanopentanoic acid) (V501) as a water-soluble azo initiator and 4-cyanopentanoic acid dithiobenzoate (CPADB) as a chain transfer agent. The resulting polymers were controlled in the range of narrow molecular weight distributions, with lower than 1.3. Using the produced dithioester-capped DMAEMA homopolymer as a macro chain transfer agent, miniemulsion RAFT polymerization of methyl methacrylate and styrene were carried out, respectively. ¹H NMR analysis showed that the diblock copolymer PDMAEMA-b-PMMA in the form of stable latices was obtained as expected. This revised version was published online at the end of November 2004. Unfortunately, the received date was incorrect due to a technical problem.     

JS118的杀虫活性与作用方式研究

室内生物测定研究了JS118的触杀、胃毒、拒食、内吸活性。结果表明(1)JS118对棉铃虫有明显的触杀活性和胃毒活性,对棉铃虫6龄幼虫的触杀毒力、胃毒毒力和综合毒力分别为2.486 mg/pest、0.606 mg/pest和0.4856 mg/pest。(2)JS118对试虫无明显的驱避效果。24 h内对试虫的取食影响不明显,但在24 h后,抑制试虫进食。(3)JS118无明显的根内吸活性。     

Quantitative description of the chloride effect on chlorine dioxide generation from the ClO2-HOCl reaction

The generation of chlorine dioxide from the reaction between hypochlorous acid and chlorite with or without an initial chloride addition has been studied under slightly acidic conditions. Chloride (Cl-), one of the products from the reaction, not only changes the reaction stoichiometry, but also alters the rate law. It was found that the formation of chlorine dioxide from the HOCI-ClO₂- system consists of two distinct parts, one is promoted by chloride, the other is independent of chloride. The overall kinetics of the chlorine dioxide generation from the reaction is: This model can very well predict the reaction under the following conditions: $ 273 - 303{\rm K},\left[ {ClO_2^ - } \right] = 0.001 - 0.00267\;{\rm mol}/{\rm L},\left[ {ClO_2^ - } \right]/\left[ {HOCl} \right] = 2,\;{\rm and}\;{\rm pH}\;3.86 - 4.91 $     

生料磨选粉机ATV71变频器参数设定

都江堰拉法基二线的生料磨选粉机电机型号为YSP315L2-6,功率为132kW,变频器为施耐德ATV71系列,型号为ATV71HC13N4。     

两性乳化剂体系对有机硅改性丙烯酸酯乳液合成的影响

采用新型琥珀酸类两性乳化剂(A1)与非离子乳化剂壬基酚聚氧乙烯醚(CA407)复配体系,合成了有机硅γ-甲基丙烯酰氧基丙三甲氧基硅烷(A174)改性的丙烯酸酯乳液。系统研究了两性乳化剂体系与非离子乳化剂复配比例、用量及乳化剂在种子乳液与预乳液中分布比例(R/F)E对乳液聚合及其性能的影响。研究表明:乳化剂配比m(A1)∶m(CA407)=30∶70时,乳液聚合稳定性及抗电解质稳定性较好;乳化剂用量越大,乳胶粒径越小,粒径分布越宽,乳液黏度越大,涂膜吸水率也越大;乳化剂在种子乳液与预乳液中的分布比例主要影响乳液聚合的稳定性。同时通过TEM乳胶粒形态分析及DSC涂膜的玻璃化转变温度分析认为,A174主要在乳液聚合时分布在乳胶粒表面,易水解交联。     

自适应天线匹配低频RFID读写器设计

在工业现场、野外甚至水中,RFID读写器天线电特性参数将发生改变,导致阻抗不匹配和发射功率大幅下降,最终降低RFID读写器读写范围和效率。为了解决这个问题,构建了一个自适应天线匹配RFID读写器系统,该系统在基本读写器系统上增加了自适应电容匹配矩阵、正弦波均方根检测和模/数转换器。该系统通过依次配置电容矩阵,扫描天线发射信号幅度,检测出最佳匹配电容,实现天线阻抗的最佳匹配。通过实验表明,在一定范围内该系统能够实现自动的阻抗匹配,获取最大发射功率。     

2-乙基-2- 唑啉的阳离子开环聚合及聚合物的表征

以对甲苯磺酸甲酯为引发剂进行２乙基２唑啉阳离子开环聚合研究，主要考察了不同的单体／引发剂配比、聚合温度和聚合时间对聚合转化率和聚合物分子量的影响。聚合物通过ＩＲ、１Ｈ核磁共振、ＤＳＣ进行表征，并考察了聚（２乙基２唑啉）与部分聚合物和共聚物的共混性能。