Controlling Horizontal Dipole Orientation and Emission Spectrum of Ir Complexes by Chemical Design of Ancillary Ligands for Efficient Deep‐Blue Organic Light‐Emitting Diodes

Deep‐blue emitting Iridium (Ir) complexes with horizontally oriented emitting dipoles are newly designed and synthesized through engineering of the ancillary ligand, where 2′,6′‐difluoro‐4‐(trimethylsilyl)‐2,3′‐bipyridine (dfpysipy) is used as the main ligand. Introduction of a trimethylsilyl group at the pyridine and a nitrogen at the difluoropyrido group increases the bandgap of the emitter, resulting in deep‐blue emission. Addition of a methyl group (mpic) to a picolinate (pic) ancillary ligand or replacement of an acetate structure of pic with a perfluoromethyl‐triazole structure (fptz) increases the horizontal component of the emitting dipoles in sequence of mpic (86%) > fptz (77%) > pic (74%). The organic light‐emitting diode (OLED) using the Ir complex with the mpic ancillary ligand shows the highest external quantum efficiency (31.9%) among the reported blue OLEDs with a y‐coordinate value lower than 0.2 in the 1931 Commission Internationale de L'Eclairage (CIE) chromaticity diagram.     

CVSkSA: cross-architecture vulnerability search in firmware based on kNN-SVM and attributed control flow graph

To prevent the same known vulnerabilities from affecting different firmware, searching known vulnerabilities in binary firmware across different architectures is crucial. Because the accuracy of existing cross-architecture vulnerability search methods is not high, we propose a staged approach based on support vector machine (SVM) and attributed control flow graph (ACFG) at the function level to improve the accuracy using prior knowledge. Furthermore, for efficiency, we utilize the k-nearest neighbor (kNN) algorithm to prune and SVM to refine in the function prefilter stage. Although the accuracy of the proposed method using kNN-SVM approach is slightly lower than the accuracy of the method using only SVM, its efficiency is significantly enhanced. We have implemented our approach CVSkSA to search several vulnerabilities in real-world firmware images. The experimental results show that the accuracy of the proposed method using kNN-SVM approach is close to the accuracy of the method using only SVM in most cases, while the former is approximately four times faster than the latter.

     

Layered CuNi-Cu2O/NiAlOx nanocatalyst for rapid conversion of p-nitrophenol to p-aminophenol

In order to well arrange active sites and avoid byproducts, the reasonable structured carrier nanocatalyst plays a crucial role in high catalytic performance, but still remains a challenge. Herein, the layered CuNi-Cu₂O/NiAlO_x nanosheets have been constructed through hydrothermal synthesis followed by calcination and H₂ reduction treatment process. The in-situ formed CuNi nanoalloys (NAs) and nano-Cu₂O were evenly distributed on the bilateral surface of layered NiAlO_x nanosheets. Based on the planar structure of nanosheet, the synergy between catalytic active CuNi NAs and photocatalytic active nano-Cu₂O endows CuNi-Cu₂O/NiAlO_x nanosheets with rapid conversion efficiency for catalyzing p-nitrophenol (p-NP, 14 mg·L⁻¹) to p-aminophenol (p-AP) in 32 s with the reaction rate constant k up to 0.1779 s⁻¹, and no obvious performance decay can be observed even over 27 cycles. Moreover, high concentration of p-NP at 10 and 20 g·L⁻¹ could be reduced to p-AP within 14 and 20 min, respectively. Such designed nanoalloy/bimetal-oxide heterostructure can provide a solution for rapid conversion of aminoaromatics from nitroaromatics wastewater even at a large concentration range.

     

状态导向与事件导向相结合的二回路管道破裂事故处理规程开发

华龙一号”采用征兆导向应急运行规程（SEOP）进行事故处理。本文对SEOP中二回路管道破裂事故相关规程进行研究，包括规程开发和支持性验证。在规程的开发过程中，构建了合理的规程框架以及不同事故采用的处理规程，并结合“华龙一号”的设计特征，确定了主要恢复策略以及相关的重要定值。在支持性验证过程中，选取典型二回路管道破裂事故进行论证，结果表明，对所选的工况，SEOP提供的缓解策略能够及时有效地将核电厂引导至预期的安全可控状态。此外，通过对不同类型事故规程进行比较，证明了SEOP在涵盖的事故范围和恢复操作的时效性方面的优势。通过本文的研究，为“华龙一号”二回路管道破裂事故处理规程的开发和验证建立了合理的方法。      

不同类型液体水化作用下海相页岩巴西劈裂破坏特征

为了研究不同类型液体水化作用对页岩内部裂缝形态、岩石抗拉强度和巴西劈裂张性破坏模式的影响,选取昭通国家级页岩气示范区下志留统龙马溪组页岩气储层岩心,采用清水及滑溜水分别进行了水化预处理,通过CT扫描对比了页岩中裂缝结构的变化;然后开展巴西劈裂试验,研究了水化预处理后页岩试件抗拉强度及张性破坏模式;在此基础上,选取研究区内的两口水平井,在其压裂施工现场开展了水化预处理先导性试验。研究结果表明:①相同时间内,自发渗吸过程清水水化作用对海相页岩裂缝复杂程度的提升效果优于滑溜水;②清水表面张力更大且黏度更低,清水水化作用不仅能够促使原始裂缝延伸,还能诱发新的微细裂缝或分支缝,而滑溜水水化则以促使原始裂缝扩展为主;③水化作用使海相页岩发生损伤,其抗拉强度降低,经过清水、滑溜水水化预处理后的页岩试件抗拉强度相对未水化试件分别降低了35.6%和18.1%;④根据主裂缝延伸形态将页岩水化后巴西劈裂张性破坏模式分为阶梯形、折线形、分支形和弧形4种或是其相互组合,而未水化页岩张性破坏模式仅为直线形;⑤水化作用能有效提升海相页岩压裂裂缝复杂程度,建议在施工条件允许的情况下,射孔后在限压范围内高排量注入一定量清水并关井直至主压裂施工开始,为了降低主压裂施工难度,可以通过"低砂浓度、长段塞"泵注的策略来满足设计加砂量。     

基于Hadoop的电力运维审计系统的设计

国家电网公司信息化程度越来越高，单机运维审计系统产生的数据量日益增多，对海量数据高效率存储分析性能严重下降，系统稳定性降低。为满足国家电网当前对运维审计系统数据存储分析以及系统稳定性的需求，在Hadoop开源架构的基础上，本文提出基于Hadoop集群的海量数据分布式存储方法和基于Heartbeat的心跳检测技术，实现基于Hadoop的电力运维审计系统。〖JP2〗实验测试结果表明，基于Hadoop的电力运维审计系统相比单机系统可用性提高了8.42%，大大提升了存储分析海量数据的性能，具有系统工作稳定和服务不间断等优势。     

大断面三孔小净距隧道围岩稳定性数值研究及工程实践

隧道支护设计的核心目标是提高围岩自稳能力，然而大断面三孔小净距隧道围岩失稳机制尚不明确，相关控制手段也鲜有研究。依托京张高铁长城站大断面三孔小净距隧道工程，系统研究其围岩稳定特性，提出相应的控制方法，并开展工程应用。研究表明：通过一系列三维数值分析，大断面三孔小净距隧道围岩稳定特征可以凝练为超前变形破坏大与夹岩变差易失稳；后行中洞由于受先行边洞开挖扰动的剧烈影响，造成过大超前变形和严重超前破坏，因此中洞安全状态最差；为防止围岩失稳破坏，提出纵向超前控制和横向夹岩控制两种方法，通过数值分析对超前支护参数进行优化，并研究管棚与帷幕注浆联合超前控制效果；控制措施在长城站得到工程实践，控制手段应用后，拱顶沉降减少62.5%，横向收敛缩小48.0%，围岩压力降低25.2%，有效保证隧道开挖安全。     

冷轧变形量及再结晶对TC4合金组织与性能的影响

通过XRD、OM、EDS、SEM和万能试验机等方法,研究了不同冷变形量对TC4合金微观组织及力学性能的影响以及相同再结晶处理对不同冷变形量合金再结晶程度的影响。结果表明,冷轧制使得TC4合金产生加工硬化,相较固溶试样,35%和48%冷变形量试样的抗拉强度分别提高451 MPa和228 MPa。再结晶工艺相同时,随着变形量的增大,合金的抗拉强度逐渐降低。     

A triple-shape memory material fabricated by in situ crosslinking of poly(butylene adipate-co-terephthalate)/ε-polycaprolactone via electron-beam irradiation and its triple-shape memory effects

In this work, we fabricated a triple-shape memory polymeric material though in situ crosslinking of poly(butylene adipate-co-terephthalate)/ε-polycaprolactone blends induced by electron beam irradiation. The intrinsic property of irradiation crosslinking, crosslinking rule in this heterogeneous system, formation of interfacial bridge molecular, and the resulted interfacial strength were investigated. No obvious interfacial slips were observed in tensile test, and the elongation at break was above 900%. The high-temperature relaxation and recovery experiments at nonlinear region confirmed the excellent hyperelasticity and recovery ratios (R_r ) can be as high as 95% for samples irradiated above 96 kGy. The mismatch between heating rate and relaxation kinetics resulted in both instable temporary shapes and heating-mode dependent recovery behavior during the recovery process. Self-stability of the temporary shape at middle temperature was also emphasized in view of the phenomenon that the second R_r was above 100% in our experiments. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48588.     

Thermal-Disrupting Interface Mitigates Intercellular Cohesion Loss for Accurate Topical Antibacterial Therapy

Bacterial infections remain a leading threat to global health because of the misuse of antibiotics and the rise in drug-resistant pathogens. Although several strategies such as photothermal therapy and magneto-thermal therapy can suppress bacterial infections, excessive heat often damages host cells and lengthens the healing time. Here, a localized thermal managing strategy, thermal-disrupting interface induced mitigation (TRIM), is reported, to minimize intercellular cohesion loss for accurate antibacterial therapy. The TRIM dressing film is composed of alternative microscale arrangement of heat-responsive hydrogel regions and mechanical support regions, which enables the surface microtopography to have a significant effect on disrupting bacterial colonization upon infrared irradiation. The regulation of the interfacial contact to the attached skin confines the produced heat and minimizes the risk of skin damage during thermoablation. Quantitative mechanobiology studies demonstrate the TRIM dressing film with a critical dimension for surface features plays a critical role in maintaining intercellular cohesion of the epidermis during photothermal therapy. Finally, endowing wound dressing with the TRIM effect via in vivo studies in S. aureus infected mice demonstrates a promising strategy for mitigating the side effects of photothermal therapy against a wide spectrum of bacterial infections, promoting future biointerface design for antibacterial therapy.