Joining of dense Si3N4 ceramics with tape cast Lu-Al-Si-O-N interlayer

Lu-Al-Si-O-N tapes with different thickness were used to join gas pressure sintered Si₃N₄ ceramics. The microstructure of the joints and the influences of the joint thickness and joining temperature on the bonding strength of the as-joined Si₃N₄ ceramics have been investigated. The highest bonding strength about ~ 300 MPa of the joined specimens was achieved by using 450 µm interlayer at 1450 °C. The existence of Si₃N₄ nanowires was beneficial for the improvement of the bonding strength by interweaving the oxynitride glass matrix in the joint region.     

挥发性有机废气净化技术研究进展

受现代工业的快速发展影响,挥发性有机废气对环境的影响不断提升。基于此,本文将简单分析挥发性有机废气净化技术研究现状,并深入探讨相关研究进展,希望研究内容能够给挥发性有机废气净化技术的选择提供依据。     

Extraction optimisation,antioxidant activity and inhibition on α-amylase and pancreatic lipase of polyphenols from the seeds of Syzygium cumini

The objectives of this study were to determine the optimal extraction conditions of polyphenols from Syzygium cumini seeds by response surface methodology and investigate their antioxidant activity and inhibition on α-amylase and pancreatic lipase. As results, the optimal extraction conditions in the ultrasonic extraction process which maximised total polyphenols content, minimised the IC₅₀ values of α-amylase and pancreatic lipase were determined as follows: extraction time 60 min, ethanol concentration 63% and solvent/solid ratio 44 mL g⁻¹. The main phenolic compounds in partially purified fraction of Syzygium cumini seeds were catechin, epicatechin, kaempferol, gallic, 5-caffeoylquinic, caffeic and ferulic acids. In addition, the partially purified fraction inhibited 87.66 ± 5.55 and 86.61 ± 3.15% of α-amylase and pancreatic lipase, respectively. The results suggested that Syzygium cumini seeds could be explored as a natural antioxidant and could be used as a source of highly antidiabetic and anti-obesity bioactive compounds.     

A Model for Laser Induced Lubricant Depletion in Heat-Assisted Magnetic Recording

The lubricant evaporation caused by the rapid laser heating is always a big concern in heat-assisted magnetic recording. In this article, we develop an empirical equation based on the existing measurement data to describe the relation between the evaporation coefficient of lubricant and temperature on the disk surface. The evaporation coefficient of lubricant is found to decrease from ~1.0 to ~0.003 for the temperature range from 406 to 512 K and follow the trend given by the Arrhenius formula. By incorporating this formula into a previously established evaporation model, we can get a new model, which enables us to predict the lubricant evaporation and depletion caused by the rapid laser heating more accurately than ever.     

光辐射本安设计在光纤传感器中的应用

光纤传感器已被越来越广泛地应用在易燃易爆危险环境中,光辐射防爆设计日趋重要。通过介绍国际电工委员会公布的IEC 60079-28-2006标准,对光辐射点燃机制、防爆保护类型及原理进行了阐述。对连续光辐射和脉冲光辐射的防爆设计准则进行了解析,提出了本质安全光纤传感器的设计思路及系统构架。随着光纤传感器的不断发展和推广,光辐射防爆国家标准的推出,掌握光辐射防爆设计的理论知识及设计准则显得越来越重要。     

Synthesis of polylactide‐based thermoset resin and its curing kinetics

A new class of biobased thermoset resins, methacrylated four‐armed star‐shaped polylactides (M4sPLAs), was prepared. The effect of star architecture, e.g. varying arm length, on the properties of the cured products was examined. Based on differential scanning calorimetry, the non‐isothermal and isothermal curing behaviors of these M4sPLAs were investigated. Various curing kinetic parameters were obtained and elucidated using autocatalytic reaction models. Experimental results indicate that the oligomers can be crosslinked into a rigid network within a curing time varying from several minutes to more than an hour upon thermal initiation. The curing processes of M4sPLAs with varying arm length are different and complex, as indicated by the change of various kinetic parameters, reaction orders and evolutions of activation energy under the test reaction conditions. High crosslinking density is especially effective for improving the thermal stability of polylactide, but also leads to slower degradation rate and deterioration of its impact properties. Copyright © 2012 Society of Chemical Industry     

A comparative study on UV light activated porous TiO2 and ZnO film sensors for gas sensing at room temperature

In order to find a new approach for screening the photoactivated gas sensing materials with high sensitivity, a comparative study was carried out. With the simple technique of screen printing, TiO₂ and ZnO were used to fabricate the UV light activated gas sensors which were applied at room temperature. To facilitate the simultaneous measurements of the current transients of the two materials, they were printed on the same alumina substrate. Compared with ZnO, TiO₂ exhibited a superior performance to ethanol and formaldehyde gases. It was found that the responses of TiO₂ increased with the concentration of test gas and amounted to 224 and 1700 to 100 ppm ethanol and formaldehyde gases, respectively, while the responses of ZnO to 100 ppm ethanol and formaldehyde gases were 0.14 and 1.5, respectively. The mechanism of such a huge difference between TiO₂ and ZnO was discussed in detail. Furthermore, it is suggested that metal oxide semiconductor with lower photo-to-dark current ratio can achieve higher photoactivated gas sensitivity.