Modeling uranium biosorption by Cystoseira sp. and application studies

The aim of the present work was to determine the applicability of raw and modified brown macroalga Cystoseira sp. as a biosorbent material for the sorption of uranium ions from aqueous solutions. Equilibrium of uranium biosorption was analyzed under isotherm models and thermodynamic parameters of the process. Recovery of uranium from acidic mine wastewater was also applied. The mechanism of biosorption was discussed considering experimental data and theoretical models. The bioremoval efficiency of modified biomass was higher than raw Cystoseira sp. and the theoretical biosorption capacity of modified biosorbent was calculated to be 468.01 mg U/g.     

An improvement of quantitative strategic planning matrix using multiple criteria decision making and fuzzy numbers

The Quantitative Strategic Planning Matrix (QSPM) is a useful tool to prioritize strategies at any level including corporate, business and functional. The ratings and attractive scores used in QSPM, however, require judgmental decisions and should be based on expert's opinion to ensure the applicability of chosen strategies. Application of a fuzzy multi-criteria decision making method is proposed in this paper with the goal of improving the output of conventional QSPM by allowing the experts to employ linguistic terms (qualitative data) in their judgments. Namely, a multi-criteria decision making index via the technique for Order Preference by Similarity to Ideal Solution (TOPSIS) is adapted to the fuzzy QSPM in finding the sum total attractive scores of strategies. As a case study, the proposed method has been applied for strategy prioritization in a Tile Company. The results have been verified with expert knowledge and showed an improvement compared to the non-fuzzy QSPM.     

Photoluminescence emission of nanoporous anodic aluminum oxide films prepared in phosphoric acid

The photoluminescence emission of nanoporous anodic aluminum oxide films formed in phosphoric acid is studied in order to explore their defect-based subband electronic structure. Different excitation wavelengths are used to identify most of the details of the subband states. The films are produced under different anodizing conditions to optimize their emission in the visible range. Scanning electron microscopy investigations confirm pore formation in the produced layers. Gaussian analysis of the emission data indicates that subband states change with anodizing parameters, and various point defects can be formed both in the bulk and on the surface of these nanoporous layers during anodizing.     

An overview of the environmental,economic, and material developments of the solar and wind sources coupled with the energy storage systems

There is a constant growth in energy consumption and consequently energy generation around the world. During the recent decades, renewable energy sources took heed of scientists and policy makers as a remedy for substituting traditional sources. Wind and photovoltaic (PV) are the least reliable sources because of their dependence on wind speed and irradiance and therefore their intermittent nature. Energy storage systems are usually coupled with these sources to increase the reliability of the hybrid system. Environmental effects are one of the biggest concerns associated with the renewable energy sources. This study summarizes the last and most important environmental and economic analysis of a grid‐connected hybrid network consisting of wind turbine, PV panels, and energy storage systems. Focusing on environmental aspects, this paper reviews land efficiency, shaded analysis of wind turbines and PV panels, greenhouse gas emission, wastes of wind turbine and PV panels' components, fossil fuel consumption, wildlife, sensitive ecosystems, health benefits, and so on. A cost analysis of the energy generated by a hybrid system has been discussed. Furthermore, this study reviews the latest technologies for materials that have been used for solar PV manufacturing. This paper can help to make a right decision considering all aspects of installing a hybrid system. Copyright © 2017 John Wiley & Sons, Ltd.     

Creep behavior of nylon fiber-reinforced asphalt concrete

This study aims to investigate the permanent deformation behavior of asphalt concrete reinforced by nylon fibers. Nylon fibers (12 mm length) have been added to a typical asphalt concrete at different percentages of 0.05, 0.1, 0.15, 0.2, 0.25, and 0.3% (based on total weight of mixture), and the permanent deformation behavior of the mixtures have been investigated by dynamic creep tests at different stress levels of 200 and 400 kPa, and different temperatures of 40, 50, and 60 °C on the mixtures. A three-stage model (developed by Zhou et al.) has been used for modeling the creep curve of the mixtures and determining the flow number and creep strain slope of the mixtures, which are used to describe the permanent deformation of asphaltic mixtures. The parameters of the models were determined in MATLAB using an algorithm established by Zhou et al. The results showed that the mixture reinforced by 0.1% of nylon fibers has the highest resistance to permanent deformation. The three-stage model was well fitted with the dynamic creep test results of the mixtures. The results also showed that the mixture containing 0.1% of nylon fibers has the lowest creep strain slope and the highest flow number, indicating that this mixture has the highest resistance to permanent deformation.     

A green separation process for recovery of healthy oil from pumpkin seed

In this study, pumpkin seeds, called as “Ürgüp Sivrisi” and grown in Cappadocia region, were used as plant materials because of high aroma contents. In the supercritical fluid extraction of pumpkin seed oil, the effect of main process parameters as the particle size (250-2360 μm), the volumetric flow rate of supercritical solvent (0.06-0.30 L/h), the operating pressure (20-50 MPa), the operating temperature (40-70 °C), the type of entrainer (ethanol and n-hexane) and those concentrations (0-10 vol.%) on the extraction yield, the oil solubility and the initial extraction rate were investigated. A cross-over effect for the extraction of pumpkin seed oil using supercritical CO₂ was determined at the operating pressure of 20-30 MPa. The maximum extraction yield obtained with entrainer free was reached 0.50 g oil/g dry seed at 600-1180 μm, 0.12 L/h, 50 MPa and 70 °C for the operation time of 5 h. The maximum extraction yield obtained with ethanol as an entrainer in the experiments was reached 0.54 g oil/g dry seed at the conditions of 600-1180 μm, 0.12 L/h, 30 MPa, 40 °C and 8 vol.% for the operating time of 2 h. The oil compositions were determined by gas chromatography analysis and the results showed that the compositions of pumpkin seed oil which were obtained by means of organic solvent extraction and supercritical fluid extraction were similar. The average oil compositions determined as 9.3 (±0.43)% palmitic acid, 7.5 (±0.6)% stearic acid, 32.3 (±0.6)% oleic acid, 48.1 (±0.6)% linoleic acid and 0.7 (±0.3)% linolenic acid. The morphological changes in the seeds were determined by the scanning electron microscopy analysis.     

Comparison on efficiency factors of F and C types of fly ashes

Fly ashes are obtained from thermal power plants and they are pozzolanic materials, which can act as partial replacement material for both portland cement and fine aggregate. With their economical advantages and potential for improving fresh and hardened concrete performance, they have some benefits for using in concrete industry. In this study, the objective was to find the efficiency factors of Turkish C and F-type fly ashes and to compare their properties. Three different cement dosages were used (260, 320, 400 kg/m³), two different ratios (10% and 17%) of cement reduced from the control concretes and three different ratios (depending on cement reduction ratio) of fly ash were added into the mixtures. At the ages of 28 and 90 days, compressive strength, modulus of elasticity and ultrasound velocity tests were carried out. From the compressive strength results, the k efficiency factors of C and F-type fly ashes were obtained. As a result, it is seen that efficiency factors of the concrete produced by the replacement of F and C type fly ashes with cement increase with the increase in cement dosage and concrete age.     

L-cystein modified bentonite-cellulose nanocomposite (cellu/cys-bent) for adsorption of Cu2+, Pb2+, and Cd2+ ions from aqueous solution

In this study, L-cystein modified bentonite-cellulose (cellu/cys-bent) nanocomposite was synthesized and characterized by XRD, FTIR, SEM with EDS, TGA, and TEM techniques. In order to optimize the process the effect of various operational parameters such as pH, adsorbent dosage, contact time, and temperature were also investigated. The adsorption experiments were carried out in initial concentrations range of 20-100 mg L^?1and the adsorbent affinity for metal ions was found to be in order of Cu²⁺ > Pb²⁺ > Cd²⁺. The optimum pH for adsorption of Cu²⁺ and Cd²⁺ was observed at 5 while for Pb²⁺ it was pH 6. Based on the Langmuir model, the maximum adsorption capacity of Cu²⁺, Pb²⁺, and Cd²⁺ at 50^?C was found to be 32.36, 18.52, and 16.12 mg g^?1, respectively. The Langmuir isotherm and pseudo-second order model were found to be better fitted than the other isotherms and kinetic models. The results of thermodynamic parameters confirmed the process to be endothermic and spontaneous in nature.     

Aloe vera gel: a new thickening agent for pigment printing

An attempt was made to print cotton fabric with pigments using a new thickening agent based on Aloe vera gel in combination with sodium alginate. The results were compared with the standard conventional printing recipe containing synthetic thickener, and a favourable effect of Aloe vera introduction was achieved. The results show that the properties of the printed fabric (sharpness, colour yield, overall fastness properties, softness, and water vapour transmission) are dependent on the percentage of Aloe vera gel in the thickener combination, the concentration of printing auxiliaries, and the curing conditions. Optimal printing properties were achieved by using a printing paste containing 80% Aloe vera/20% sodium alginate (700 g kg^?1), pigment (50 g kg^?1), binder (145 g kg^?1), fixer (10 g kg^?1), and ammonium sulfate (5 g kg^?1), followed by drying at 85 °C for 5 min and curing at 150 °C for 3 min. The sample printed with the new recipe showed superior rubbing fastness and handle properties, with a slightly lower colour yield, when compared with the sample printed with synthetic thickener. Finally, economic issues arising from synthetic thickener substitution are highlighted.