Oxygen enrichment from air through multilayer thin low‐density polyethylene films

Several multilayer thin low‐density polyethylene (LDPE) films were fabricated by blown thin film having a thickness of 7 μm and an area of 130 cm². They were characterized for their oxygen‐enrichment performance from air by a constant pressure–variable volume method in a round permeate cell with an effective area of 73.9 cm². The relationship between oxygen‐enrichment properties, including oxygen‐enriched air (OEA) flux, oxygen concentration, permeability coefficients of OEA, oxygen, nitrogen, as well as separation factor through the multilayer LDPE films, and operating parameters, including transfilm pressure difference, retentate/permeate flux ratio, temperature, as well as layer number, are all discussed in detail. It is found that all of the preceding oxygen‐enrichment parameters increase continuously with an increase of transfilm pressure difference from 0.1 to 0.65 MPa, especially for the trilayer and tetralayer LDPE films. The oxygen concentration and separation factor appear to rapidly increase within the retentate/permeate flux ratio below 200, and then become unchangeable beyond that, whereas the OEA flux and the permeability coefficients of OEA, oxygen, and nitrogen seem to remain nearly constant within the whole retentate/permeate flux ratio investigated, especially for the monolayer and bilayer LDPE films. The selectivity becomes inferior, whereas the permeability becomes superior, as the operating temperature increases from 23 to 31°C. The highest oxygen concentration was found to be 44.8% for monolayer LDPE film in a single step with air containing oxygen of 20.9% as a feed gas and operating pressure of 0.5 MPa at a retentate/permeate flux ratio of 340 and 23°C. The results demonstrate a possibility to prepare an oxygen‐enriching membrane directly from air, based on the easily obtained thin LDPE films. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 3013–3021, 2002; DOI 10.1002/app.2331     

ENR／CSM的自硫化研究

研究在没有任何硫化剂的情况下环氧化天然橡胶（ＥＮＲ－５０）和氯磺化聚乙烯（ＣＳＭ－４０）共混物的自硫化，以及共混比、填料品种及用量、间苯撑双马来酰亚胺与马来酸酐等活性剂、硫化温度和时间对交联程度和性能的影响。结果表明ＥＮＲ／ＣＳＭ共混体可以产生自硫化；共混比为５０／５０时交联密度最大，性能最佳，炭黑和白炭黑对该体系有好的补强作用，但白炭黑的补强作用比炭黑的好；间苯撑双马来酰亚胺及马来酸酐能活化自硫化体系；延长硫化时间及提高硫化温度均可增加交联作用，该自硫化体系没有返原现象。     

玻纤增强PET/蒙脱土阻燃工程塑料的研究

以PET／蒙脱土为基材树脂，通过添加玻纤、阻燃剂、增韧剂制备出可在低模温下成型的玻纤增强PET／蒙脱土阻燃工程塑料。研究了阻燃剂、增韧剂对PET／蒙脱土工程塑料的性能影响。结果表明，采用十溴联苯醚和三氧化二锑复配阻燃体系，当添加的质量分数达到8％时，体系阻燃性能达到UL94 V0；在相同添加量的情况下，增韧剂对体系的增韧效果为：POE-MAH〈EPDM—MAH〈PTW；增韧剂PTW不仅使复合材料抗冲击性能大幅度提高，同时也使复合材料的拉伸强度、弯曲强度进一步提高。     

SiC晶须增强陶瓷基复合材料的研究

用不同的Al_2O_3粉料,采用SiC晶须补强以及加入第三相SiC粒子弥散增韧的方式,研究了SiC晶须Al_2O_3基复合材料的力学性能,得到强度σ_f=780MPa,K_(Ic)=7.6MPa·m~(1/2)的结果。通过不同的分敌途径,对晶须分散效果进行了实验观察和探讨;并讨论了晶须的分散均匀性对力学性能的影响。同时,就晶须团聚体在增韧过程中所起的作用提出了一种新的、可能的增韧机制,合理地解释了实验结果。最后,就三元复合系统中晶须补强和弥散增韧两种途径的迭加效果进行了讨论。     

一种基于SIFT算法的图像镜像变换识别方法

SIFT(scale invariant feature transform)算法提取的图像特征对图像自身的镜像变换匹配精度不够。针对此问题,对SIFT算法进行了改进,提出FI-SIFT(flip invariant SIFT)算法:利用纵坐标方向的梯度初步判断图像是否为镜像变换,若是则把特征向量映射为极坐标,对极坐标进行重组后,再逆变换到直角坐标系,更新特征向量;然后基于欧式距离匹配两幅图像中的关键点。实验结果表明,采用FI-SIFT算法提取的图像特征进行镜像变换匹配,匹配精度有了很大提高,由改进之前的0.6上升到0.9。     

ZBAF中沸石对铵氮的吸附特性试验研究

用化学方法和生物方法对沸石滤料曝气生物滤池(ZBAF)中长期运行吸铵饱和的沸石进行再生,并通过吸附动力学和吸附热力学对新鲜沸石和再生沸石的吸附容量和吸附速率进行了试验研究。研究结果表明:再生沸石对铵氮良好的吸附和交换性能仍然存在;再生沸石的吸附速率较新鲜沸石有所下降;化学再生沸石的吸附容量较新鲜沸石基本不变,而生物再生沸石的吸附容量下降较大。     

PHASE-SPACE DIFFUSION EQUATIONS FOR SINGLE BROWNIAN PARTICLE MOTION NEAR SURFACES

In numerous physical processes involving the motion of micron and submicron sized particles near surfaces, such as the filtration of hydrosols and aerosols, the particle motion is the net result of the combined effects of fluid convection, external forces, particle inertia, Brownian particle motion, and particle-surface fluid dynamic interactions. The most general method of describing particle motion under the combined action of these effects is through the so-called Fokker-Planck equation. In the absence of particle-surface fluid dynamic interactions, the Fokker-Planck equation is well-known, and it has been applied in a general way to problems involving the adsorption or deposition of Brownian particles onto surfaces through a solution technique known as the Brownian dynamics simulation method.

In this study, the Fokker-Planck equation for Brownian particle motion near surfaces is generalized to include particle-surface fluid dynamic interactions. The Fokker-Planck equation is shown to follow from the Liouville equation for the Brownian particle and n-fluid molecules present in the system, thus, establishing a firm theoretical foundation for the Fokker-Planck equation and the various other phase-space diffusion equations that follow from it.

Based on diagonalization of the Fokker-Planck equation, its short-time behavior is also derived here which enables a generalization of the Brownian dynamics method for the study of particle motion near surfaces including fluid dynamic interactions. Additionally, a perturbation solution of the Fokker-Planck equation under the conditions of small, but finite particle Stokes number is also derived. These solutions are shown to agree with previously given representations of the Smoluchowski or convective-diffusion equation for Brownian particle motion near surfaces, as well as with inertial corrections to the Smoluchowski equation available in the literature. This latter equation is also generalized here to include particle-surface fluid dynamic interactions.     

基于Modbus/TCP协议实现人机界面与下位机通信

在以通用伺服电机控制系统为下位机的基础上,开发了以实时内核μC/OS-II、DSP、CPLD控制模块为核心的软硬件平台。通过移植uIP协议栈到DSP,在通信应用层上将Modbus帧嵌入到TCP帧中,简单可靠地实现了Modbus/TCP协议。同时将Modbus/TCP协议与μC/OS-II实时内核进行整合,更好地保证了系统调度的实时性。     

数字信号控制器的中断系统分析与实现方法

数字信号控制器(DSC)具有数字信号处理能力和MCU控制接口,其中断系统功能非常丰富,这为应用带来方便,同时也带来设置的复杂性。本文以MC56F8257为例,详细分析DSC中断系统及其设置方法;以MC56F8257中的QSCI模块中断及CAN模块中断为例,从不带中断优先级、带中断优先级和优先级嵌套三个方面,分析DSC中断设置过程及响应结果。分析结果进一步验证DSC中断具有优先级及屏蔽等特点,为推广DSC芯片的应用提供指导。     

ZigBee和3G的远程无线测光系统设计

设计了基于ZigBee短距离无线通信技术与3G远距离无线通信技术相结合的远程无线测光系统;该系统处理器选用的是三星S5PV210处理器,短距离无线通信模块采用TI公司的CC2530芯片,3G上网卡设备用的是中兴MF190无线上网模块。文中给出了系统具体的软硬件设计方案。结果表明,该系统可以达到稳定高效的监测效果,具有良好的实用性和应用价值。