Reactions of phenols with tung oil

As regards the aromatic ring substitution reactions of various kinds of phenols with tung oil under acidic conditions, an investigation was made on the influences of the kinds and substitution positions of alkyl groups of the phenlos on the reaction. Alkyl phenols increased in reactivity in the order of ortho, meta, and para in the position of alkyl substitution. This can be attributed to the preferential para addition of tung oil to the phenol nucleus as reported in the previous paper. The larger alkyl group gave increased reactivities in the reactions of alkyl phenols with tung oil. This has something to do with compatibilities between phenols and tung oil (differences in solubility parameter between phenols and tung oil).     

Effect of pre-oxidation on reactivity of chars in steam

The effects of pre-oxidation of char from Taiheiyo coal, a non-caking bituminous coal, in the 400–550 °C temperature range on its gasification reactivity with N₂-H₂O at 0.1 MPa (steam partial pressure of 13.2 kPa) have been investigated. The pre-oxidation of char markedly enhances gasification rates at temperatures between 800 and 900 °C. Reactivity is found to parallel the burn-off level during preoxidation at low temperatures (400–430 °C), whereas at relatively high temperatures (480–550 °C), the burn-off level only affects the reactivity slightly. The amount of CO and CO₂ evolved from the preoxidized char by heat treatment is proportional to the burn-off level at low temperatures (400–430 °C), being closely related to the enhancement of the gasification reactivity in steam.     

Conformational studies of poly(N-methyl-l-alanine) by n.m.r. spectroscopy

Nuclear magnetic resonance (n.m.r.) and circular dichroism of $\text{poly}\text{(N-}\text{methyl-}\text{l}\text{-alanine}\text{)}$ in methylene $\text{chloride}\text{-d}{}_2\text{dichloroacetic acid}$ were investigated. In methylene chloride-d₂$\text{poly}\text{(N-}\text{methyl-}\text{l}\text{-alanine}\text{)}$ was found to consist of nearly all-trans amide bonds and assume a stable secondary structure. Trace amounts of cis amide bonds were also present. The addition of dichloroacetic acid destroyed the secondary structure and induced a drastic change of the n.m.r. spectrum, which was similar to that observed with the monomeric amide, $\text{N-}\text{acetyl}\text{-N-}\text{methyl-}\text{l}\text{-alanine}$ dimethylamide. In comparison of the polymer with the monomeric amide, it was concluded that the transition of $\text{poly}\text{(N-}\text{methyl-}\text{l}\text{-alanine}\text{)}$ was caused by the isomerization of amide bonds. The complex n.m.r. spectrum was interpreted in terms of the distribution along the polymer chain of various non-planar amide links as well as planar cis and trans amide links. The difference of the mechanism of conformational transition between poly(amino acid) and poly(imino acid) is also discussed.     

Pervaporation via silicon-based membranes: Correlation and prediction of performance in pervaporation and gas permeation

Pervaporation (PV) is a membrane technology that holds great promise for industrial applications. To better understand the PV mechanism, PV dehydrations of various types of organic solvents (methanol, ethanol, iso-propanol, tert-butanol, and acetone) were performed on five types of organosilica and two types of silicon carbide-based membranes, all with different pore sizes. Water permeance was dependent on the types of organic aqueous solutions, which suggested that organic solvents penetrated the pores and hindered the permeation of water. In addition, water permeance of various types of membranes in PV was well correlated with hydrogen permeance in single-gas permeation. Furthermore, a clear correlation was obtained between the permeance ratio in PV and that in single-gas permeation, which was confirmed via the modified-gas translation model. These correlations make it possible to use single-gas permeation properties to predict PV performance.     

Magnetic order and evolution of the electronic state aroundx=0.12 in La2?xBaxCuO4 and La2?xSrxCuO4

Muon spin rotation ( ⁺SR) measurement provides clear evidence of the antiferromagnetic order of Cu moments below 35 K for La_2–x Ba _x CuO₄ and below 15 K for La_2–x Sr _x CuO₄ in the narrow range ofx where the high-T _c superconductivity (SC) is suppressed remarkably. The results suggest that the change of the electronic state coupled with the lattice instability is relevant to the local suppression of SC and freezing of spin fluctuations of the Cu moment.     

Sensory evaluation of beef patties and sausages containing lipids with various component fatty acids

Sensory scores of beef patties and emulsion-type sausages containing varying levels of lipids with various component fatty acids were investigated. Sensory scores of beef patties containing solid fat were relatively constant at every fat level examined. However, scores of beef patties containing liquid oil decreased with increasing level of added oil. In the case of sausages, on the other hand, sensory evaluation scores markedly decreased with increasing the level of solid fat, while no significant change was observed in panel scores when liquid oil was mixed into sausages. Even 10% level of added lipids satisfactorily gave preferable acceptability to beef patties and sausages.     

Phonon anomalies in YNi2 11B2C

Recently we have discovered a new peak with phonon character which appears only below T_c in an intermetallic superconductor, YNi₂ ¹¹B₂C (Tc14-2K) by neutron inelastic scattering measurements. The peak intensity of the new peak shows the order-parameter-like temperature dependence of the superconductivity. The new peak grows by absorbing the spectral weight from the above-lying soft phonon mode. In the present study we investigate the magnetic field dependence of the new peak. With increasing magnetic field, the new peak is gradually suppressed and disappears by H=H_c2 (4.7T at T=5.5K). Beyond H_c2, the profile of the scattering function recovers that of the non-superconducting state above T_c These results strongly indicate that this new peak is undoubtedly associated with the superconducting state in YNi₂ ¹¹B₂C.     

Gap symmetry and intrinsic intraplane pinning of untwinned YBa2Cu3O7 single crystals

The interplane (cb) and intraplane (ab) anisotropy of untwinned YBa₂ Cu₃0₇ single crystals has been investigated by means of the torque magnetometry. To extract the reversible and irreversible components, the torque was measured as a function of increasing angle as well as decreasing angle. The interplane irreversible torque _irr shows two-fold peaks at _c =90 ° and270 ° (of half width11 ° at77 K) due to the well-known intrinsic interplane pinning. A novel intrinsic pinning has been discovered in the intraplane irreversible torque, i.e., _irr shows four-fold peaks of half width20° at77 K when _a =0 °, 90 °, 180 ° and270 °. We argue that the intrinsic intraplane pinning comes from the four-fold nature of the gap parameter.     

Characteristics of sol-gel derived PZT thin films with lead oxide cover layers and lead titanate interlayers

The sol-gel derived PbZr_0.53Ti_0.47O₃ (PZT) films were fabricated on the bare Pt/Ti/SiO₂/Si substrates or the same substrates coated by the PbTiO₃ (PT) interlayers. The post-deposition annealing temperature and time were optimized when the PbO cover layers and PbO vapour-containing atmosphere were compared with each other and adopted as the method to diminish the lead-loss problem during the high-temperature post-deposition annealing. The X-ray diffraction patterns, microstructures, and electrical properties such as relative permittivity, _r, remanent polarization, P _r, and coercive electrical field, E _c, were investigated in relation to the annealing conditions. The PZT films deposited on the bare Pt/Ti/SiO₂/Si substrates under the PbO vapour-containing atmosphere showed better electrical properties. This indicates that the PbO vapour-containing atmosphere may be the better method of lead-loss-prevention to process the lead-containing films rather than the PbO cover layer method. The electrical characteristics of the PZT films, _r=1150, a dissipation factor of 0.039, P _r=26 C cm^–2, and E _c=40.5 kV cm^–1 were measured at 1 kHz. When PZT films were deposited on substrates coated by the PT layers, PZT-PT films with single perovskite phase were derived by post-deposition annealing at 500 °C for 1 h. However, the relative electrical properties are very poor, i.e. E _r=160, P _r=2.0 C cm^–2 and E _c=75 kVcm^–1. The optimum combination for preparing PZT-PT films is a 40 nm PbTiO₃ interlayer and annealing conditions of 6 h at 550 °C in a PbO vapour-containing atmosphere; the derived films exhibit electrical properties of E _r=885, P _r=21.5 C cm^–2 and E _c=64 kV cm^–1. The combination of inserting a PT interlayer and annealing in a PbO vapour-containing atmosphere can prevent the formation of electrical short paths. In this case, nearly pin-hole-free PZT films can be grown on the PT (interlayer) /Pt/Ti/SiO₂/Si substrates. It is believed that it is possible to prepare the PZT films with nano-scale uniformity, reproducible quality, which may be worth considering for commercial applications.     

Information gathering and searching approaches on the Web

The information accessible through the Internet is increasing explosively as the Web is getting more and more widespread. In this situation, the Web is indispensable information resource for both of information gathering and information searching. Though traditional information retrieval techniques have been applied to information gathering and searching in the Web, they are insufficient for this new form of information source. Fortunately some Al techniques can be straightforwardly applicable to such tasks in the Web, and many researchers are trying this approach. In this paper, we attempt to describe the current state of information gathering and searching technologies in the Web, and the application of AI techniques in the fields. Then we point out limitations of these traditional and AI approaches and introduce two aapproaches: navigation planning and a Mondou search engine for overcoming them. The navigation planning system tries to collect systematic knowledge, rather than Web pages, which are only pieces of knowledge. The Mondou search engine copes with the problems of the query expansion/modification based on the techniques of text/web mining and information visualization. Seiji Yamada, Dr. Eng.: He received the B.S., M.S. and Ph.S. degrees in control engineering and artificial intelligence from Osaka University, Osaka, Japan, in 1984, 1986 and 1989, respectively. From 1989 to 1991, he served as a Research Associate in the Department of Control Engineering at Osaka University. From 1991 to 1996, he served as a Lecturer in the Institute of Scientific and Industrial Research at Osaka University. In 1996, he joined the Department of Computational Intelligence and Systems Science at Tokyo Institute of Technology, Yokohama, Japan, as an Associate Professor. His research interests include artificial intelligence, planning, machine learning for a robotics, intelligent information retrieval in the WWW, human computer interaction, He is a member of AAAI, IEEE, JSAI, RSJ and IEICE. Hiroyuki Kawano, Dr.Eng.: He is an Associate Professor at the Department of Systems Science, Graduate School of Informatics, Kyoto University, Japan. He obtained his B.Eng. and M.Eng. degrees in Applied Mathematics and Physics, and his Dr.Eng. degree in Applied Systems Science from Kyoto University. His research interests are in advanced database technologies, such as data mining, data warehousing, knowledge discovery and web search engine (Mondou). He has served on the program committees of several conferences in the areas of Data Base Systems, and technical committes of advanced information systems.