非平稳ARMA信号自校正滤波器及其应用

本文处理带白色观测噪声的非平稳ARMA信号估计问题.应用状态空间方法和现代时 间序列分析方法[1],基于ARMA新息模型,提出了非平稳ARMA信号自校正滤波器,推广了 Hagander和Wittenmafk的结果[2],并给出了在雷达跟踪系统和检测数据数字滤波方面的应 用.仿真结果说明了本文结果的实用性和有效性.     

Thermal Shock Behavior of Porous Silicon Carbide Ceramics

Using the water-quenching technique, the thermal shock behavior of porous silicon carbide (SiC) ceramics was evaluated as a function of quenching temperature, quenching cycles, and specimen thickness. It is shown that the residual strength of the quenched specimens decreases gradually with increases in the quenching temperature and specimen thickness. Moreover, it was found that the fracture strength of the quenched specimens was not affected by the increase of quenching cycles. This suggests a potential advantage of porous SiC ceramics for cyclic thermal-shock applications.     

2.5-dimensional VLSI system integration

The excessive interconnection delay and fast increasing development cost, as well as complexity of the single-chip integration of different technologies, are likely to become the major stumbling blocks for the success of monolithic system-on-chips. To address the above problems, this paper investigates a new VLSI integration paradigm, the so-called 2.5-dimensional (2.5-D) integration scheme. Using this scheme, a VLSI system is implemented as a three-dimensional stacking of monolithic chips. A cost analysis framework was developed to justify the 2.5-D integration scheme from an economic point of view. Enabling technologies for the new integration scheme are also reviewed.     

SIS热塑性嵌段共聚物的生产方法及应用

概述了SIS热塑性弹性体的合成方法以及国内外SIS生产和应用情况。综述了SIS在胶黏剂应用上的特点以及以茂金属为催化剂的SIS新低压加氢工艺的进展和国内SIS发展现状，提出了大力开发C5资源促进我国SIS产业发展的建议。     

PetaStar: a petabit photonic packet switch

This paper presents a new petabit photonic packet switch architecture, called PetaStar. Using a new multidimensional photonic multiplexing scheme that includes space, time, wavelength, and subcarrier domains, PetaStar is based on a three-stage Clos-network photonic switch fabric to provide scalable large-dimension switch interconnections with nanosecond reconfiguration speed. Packet buffering is implemented electronically at the input and output port controllers, allowing the central photonic switch fabric to transport high-speed optical signals without electrical-to-optical conversion. Optical time-division multiplexing technology further scales port speed beyond electronic speed up to 160 Gb/s to minimize the fiber connections. To solve output port contention and internal blocking in the three-stage Clos-network switch, we present a new matching scheme, called c-MAC, a concurrent matching algorithm for Clos-network switches. It is highly distributed such that the input-output matching and routing-path finding are concurrently performed by scheduling modules. One feasible architecture for the c-MAC scheme, where a crosspoint switch is used to provide the interconnections between the arbitration modules, is also proposed. With the c-MAC scheme, and an internal speedup of 1.5, PetaStar with a switch size of 6400 /spl times/ 6400 and total capacity of 1.024 petabit/s can be achieved at a throughput close to 100% under various traffic conditions.     

悬浮床加氢裂化油溶性催化剂与沥青质的作用

在高压釜反应器中对添加了油溶性 Ni 催化剂(UPC-O)和水溶性 Ni 催化剂(UPC-W)的辽河稠油常压渣油(LHAR)进行了悬浮床加氢裂化实验。通过元素分析和傅里叶变换红外光谱(FTIR)分析对抑制反应生焦效果好的 UPC-O 与 LHAR 沥青质的作用进行了研究。元素分析结果显示,在 LHAR 中加入 UPC-O1000μg/g,沥青质和脱沥青质油中 Ni 含量分别出476μg/g和110μg/g 增加到7 559μg/g 和1 024μg/g,表明 UPC-O 在沥青质中有富集的趋势。FTIR 表征结果显示,UPC-O 和沥青质发生了相互作用。UPC-O 可在沥青质原位硫化为活性组分,对沥青质在悬浮床加氢裂化反应中的缩合起到好的抑制作用。     

降低汽油烯烃含量裂化催化剂LBO-12的研制与开发

探讨了催化裂化过程降低汽油烯烃的反应原理，研究了催化剂各组分对裂化汽油性质影响的规律性，围绕提高氢转移活性，提出制备降烯烃裂化催化剂的技术路线，并研制开发了新型LBO-12降烯烃催化剂，固定流化床反应器对中试样品的评价和工业应用结果表明，该催化剂在不损失汽油辛烷值的前提下，降低催化裂化汽油烯烃能力较强，并具有较高的水热活性稳定性和良好的抗重金属污染特性。     

端羟基聚乳酸微球的制备与降解

以1,4-丁二醇和D,L-乳酸为原料,经缩合聚合法制备了端羟基聚乳酸,并用溶剂挥发法制备了端羟基聚乳酸微球.考察了乳化剂浓度、油水相比例及聚乳酸浓度对微球平均粒径和形貌的影响,并在pH=7.4缓冲溶液中进行了微球的降解.结果表明以二氯甲烷为溶剂,PVA作为乳化剂,室温和600r/min搅拌速度下可制得平均粒径0.5-1.0m的较均匀的、表面平滑的端羟基聚乳酸微球.随着在pH=7.4下降解时间增加,微球表面变得粗糙.     

Photocatalytic degradation of 2,2‐bis(4‐hydroxy‐3‐methylphenyl) propane (BPP) based on molecular recognition interaction

BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO₂/UV–visible (λ_max = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 10³ L mol^?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO₂/UV–visible (λ_max = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO₂/UV‐visible (λ_max = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry     

DCA-112催化裂化抑焦剂的工业应用

针对改善催化裂化反应微环境研制开发的DCA - 112催化裂化抑焦剂 ,具有抑制生焦、改善产品分布、应用流程简单、加注方便等特点 ,经中石化长炼分公司 1Mt/a重油催化装置工业应用表明 ,在相近的工艺条件下 ,掺渣比提高 4 13个质量百分点 ,总液收提高 1 0 2个质量百分点。