Stability studies on methyl and ethyl fatty acid esters of sunflowerseed oil

Fatty acid esters, high in linoleic acid, were prepared and stored for long-term engine tests. Storage tests with these esters were undertaken to obtain more information on optimal storage requirements and general stability characteristics. Samples were kept at three temperature levels (20 C, 30 C and fluctuating around 50 C) for a 90-day period and were removed at regular intervals for chemical and physical analysis. The influence of air, temperature, light, TBHQ and contact with mild steel was evaluated by comparing the free fatty acid, peroxide, anisidine, ultraviolet absorption, viscosity and induction periods. A statistical model was used to evaluate the data and to reduce the large number of data points to comparable curves. Storage of esters in contact with air, especially at a temperature above 30 C, resulted in significant increases in peroxide, ultraviolet absorption, free fatty acid, viscosity and anisidine values. Exclusion of air retarded oxidation at all temperature levels. A direct relationship between viscosity increases and oxidation parameters was evident. Exposure to light caused a small increase in the oxidation parameters of esters stored at the highest temperature level. Addition of TBHQ prevented oxidation of samples stored under moderate conditions. Under unfavorable storage conditions the anti-oxidant was no longer effective. Mild steel had very little effect on the oxidation parameters. Only the anisidine values of samples stored at the highest temperature level were slightly increased. Methyl esters performed slightly better than ethyl esters during the storage test. The following practical guidelines for storage of fatty acid ester fuels are: (i) airtight containers should be used; (ii) the storage temperature should be <30 C; (iii) mild steel (rust free) containers may be used, and (iv) TBHQ has a beneficial effect on oxidation stability.     

连轧机用人字轮齿轴断裂失效分析

用宏观断口分析、化学检验、力学性能测定、低倍检查、金相组织及夹杂物评定鉴别、受力分析及强度寿命定量估算的方法，对人字轮被动齿轴端断裂失效原因进行分析，并提出改进措施。     

Implementation of secure digital communication by hyperchaoticsynchronisation

By active-passive-decomposition synchronisation, the application of the one-way coupled ring map lattice hyperchaotic system in secure digital speech communication is demonstrated. Synchronisation guarantees strong security and recovery without error     

NH_4Cl水溶液在成膜过程中的致孔作用

本文以ＮＨ４Ｃｌ饱和水溶液做添加剂，对ＰＶＤＦ／ＮＭＰ体系在成膜过程中的致孔作用做了研究。铸膜液中随ＮＨ４Ｃｌ水溶液加入量的改变，膜孔径也发生变化，并出现最大值。通过Ｘ－射线衍射扫描发现制膜液中存在无机盐时膜中无定形态结构增加，表明无机盐的加入有助于膜孔形成     

在柔性变焦系统中的压力变焦镜

从理论上和实验上对水冷镜的镜面曲率半径随压力变化的规律作了研究。对压力变形后镜面相对于球面作了波像差分析，分析表明压力变焦镜用于中红外激光系统是合适的     

定向爆破拆除煤矿主井井塔

文章论述了井塔拆除爆破中，把框架承重立柱的裸露钢筋骨架失稳看作为压杆失稳以及井塔在倾斜撞地时下部不解体破坏的估算。     

Heuristic lipophilicity potential for computer-aided rational drug design

In this contribution we suggest a heuristic molecular lipophilicity potential (HMLP), which is a structure-based technique requiring no empirical indices of atomic lipophilicity. The input data used in this approach are molecular geometries and molecular surfaces. The HMLP is a modified electrostatic potential, combined with the averaged influences from the molecular environment. Quantum mechanics is used to calculate the electron density function rho(r) and the electrostatic potential V(r), and from this information a lipophilicity potential L(r) is generated. The HMLP is a unified lipophilicity and hydrophilicity potential. The interactions of dipole and multipole moments, hydrogen bonds, and charged atoms in a molecule are included in the hydrophilic interactions in this model. The HMLP is used to study hydrogen bonds and water-octanol partition coefficients in several examples. The calculated results show that the HMLP gives qualitatively and quantitatively correct, as well as chemically reasonable, results in cases where comparisons are available. These comparisons indicate that the HMLP has advantages over the empirical lipophilicity potential in many aspects. The HMLP is a three-dimensional and easily visualizable representation of molecular lipophilicity, suggested as a potential tool in computer-aided three-dimensional drug design.     

含硫氰基团化合物的摩擦学性能及其摩擦化学机理研究

以三烷基磷酸酯络合硫氰酸钙为模型化合物研究了含硫氰基团的络合物的摩擦学行为，发现它有高的承载能力，良好的抗磨减摩性。用俄歇能谱（ＡＥＳ）、Ｘ－射线衍射（ＸＲＤ）、扫描电镜（ＳＥＭ）及Ｘ－射线能谱（ＥＤＸ）研究了摩擦表面元素组成及其可能物相。探讨了摩擦化学机理，认为化合物中的硫氰基团对摩擦学性能起主要作用，并在摩擦过程中发生类似于化学热处理中的硫氰共渗。