Heat propagation in thermally conductive polymers of PA6 and hexagonal boron nitride

Thermally conductive polymers offer new possibilities for the heat dissipation in electric and electronic components, for example, by a three‐dimensional shaping of the heat sinks. To face safety regulations, improved fire performance of those components is required. In contrast to unfilled polymers, those materials exhibit an entirely different thermal behavior. To investigate the flammability, a phosphorus flame retardant was incorporated into thermally conductive composites of polyamide 6 and hexagonal boron nitride. The flame retardant decreased the thermal conductivity only slightly. However, the burning behavior changed significantly, due to a different heat propagation, which was investigated using a thermographic camera. An optimum content of hexagonal boron nitride for a sufficient thermal conductivity and fire performance was found between 20 and 30 vol%. The improvement of the fire performance was due to a faster heat release out of the pyrolysis zone and an earlier decomposition of the flame retardant. For higher contents of hexagonal boron nitride, the heat was spread faster within the part, promoting an earlier ignition and increasing the decomposition rate of the flame retardant.     

脉冲高度权重技术测量197Au中子俘获截面

脉冲高度权重技术是利用C_6D_6探测器测量中子俘获截面的一种数据处理方法。在中国散裂中子源(China Spallation Neutron Source,CSNS)的反角白光中子源(Back-n)靶站上,通过测量金靶(~(197)Au)的中子俘获截面,验证了该方法的可靠性。首先利用Geant4蒙特卡罗程序模拟给出了不同靶条件下的探测器效率,脉冲高度权重函数等基本项,使得加权后的探测器效率与γ能量成正比。然后通过实验测量了~(197)Au中子俘获截面。结果表明:测量获得的中子俘获截面数据和ENDF/B-VⅢ.0评价数据相符合,同时发现随着实验靶尺寸的不同和质子束功率的增加,会使得实验本底的扣除误差越来越大。     

300M超高强钢在中性盐雾环境中的腐蚀行为及机制

摘要：为了研究300M超高强钢在中性盐雾环境中的腐蚀行为及腐蚀机制，采用失重法，宏观、微观腐蚀形貌分析，三维表面轮廓分析及电化学分析的研究方法，来表征腐蚀实验现象并进行分析。结果表明：300M超高强钢在中性盐雾环境中的腐蚀产物为FeOOH、Fe2O3、Fe(OH)3和Fe3O4；腐蚀速率随着腐蚀时间逐渐降低，腐蚀后期（72h）腐蚀速率降低50%；腐蚀初期以点蚀为主，点蚀坑通过横向扩展，逐渐发展为后期的均匀腐蚀，腐蚀表面形貌呈沟壑状；外腐蚀层对基体的保护能力很弱，Cr元素在锈层靠近基体的一侧偏聚使内腐蚀层具有一定的抗腐蚀性。     

高氯酸铵含量对高铝富燃料推进剂中重要组分高氯酸铵/铝 一次燃烧性能和铝粉团聚的影响

采用CO2激光点火装置联合高速摄影系统及扫描电子显微镜等凝聚相燃烧产物分析技术，研究了高氯酸铵(AP)含量对高Al富燃料推进剂中重要组分AP/Al一次燃烧过程中燃烧现象、引燃时间、燃烧扩散时间、燃尽时间、燃烧效率、颗粒团聚及凝聚相燃烧产物的表面形貌、粒径及其分布的影响。结果表明，各AP/Al混合粉体的燃烧过程均可分为表面引燃、燃烧扩散和火焰熄灭3个阶段，但各样品在不同燃烧阶段的燃烧现象存在明显差异。AP含量由10wt%增至30wt%，样品燃烧剧烈程度增强，燃烧过程中固相颗粒的溅射现象越加明显；在火焰熄灭阶段，各样品燃烧由以停留在样品燃面处的燃烧为主逐渐变为以溅射颗粒的燃烧为主，且随反应进行，燃面已燃固相颗粒最先熄灭，各样品表面引燃时间、燃烧扩散时间、燃烧持续时间均缩短，即燃烧反应速率逐渐加快。在AP/Al混合物中，铝粉的燃烧效率、凝聚相燃烧产物粒度及其团聚程度随AP含量增加而增加。     

Flotation Behavior,Collector Adsorption Mechanism of Quartz and Feldspar-Quartz Systems Using PEA as a Novel Green Collector

Silicon - A novel green cationic surfactant Poly (propylene glycol) bis (2-aminopropyl ether) (PEA) with multiple amine groups was utilized as a collector for flotation separation of quartz from...     

Cerebral microbleeds and cognitive decline in a hemodialysis patient: Case report and review of literature

Cerebral microbleeds (CMBs) are small hemosiderin deposits indicative of prior cerebral microscopic hemorrhage and previously thought to be clinically silent. Recent population‐based cross‐sectional studies and prospective longitudinal cohort studies have revealed association between CMB and cognitive dysfunction. In the general population, CMBs are associated with age, hypertension, and cerebral amyloid angiopathy. In the chronic kidney disease (CKD) population, diminished estimated glomerular filtration rate has been found to be an independent risk factor for CMB, raising the possibility that a uremic milieu may predispose to microbleeds. In the end‐stage renal disease (ESRD) population on hemodialysis, the incidence of microbleeds is significantly higher compared with a control group without history of CKD or stroke. We present an ESRD patient on chronic hemodialysis with a history of gradual cognitive decline and progressive CMBs. Through this case and literature review, we illustrate the need to develop detection and prediction models to treat this frequent development in ESRD patients.     

聚酯帘线的发展趋势

从聚酯的结构设计、帘线浸胶工艺和在轮胎中的应用3个方面阐述聚酯结构特点与产品性能的关系。聚酯帘线行业应该密切关注汽车行业的发展态势,把握市场先机,进一步发展壮大;在新能源汽车逆势增长的形势下,高性能聚酯帘线需求量较大,帘线企业应拓展高性能聚酯帘线在轮胎冠带层、带束层和胎体等部件中的应用,同时联合轮胎企业开发特种聚酯材料和混纺材料等新产品。     

化工原理课程思政建设探索与实践

将思想政治教育融入课程教学的各个环节,实现全程育人、全方位育人,是落实立德树人根本任务的重要途径。文章从介绍课程发展史、传承“时钧精神”、践行绿色发展理念、培养哲学思维、探寻科学家事迹、突出中国传统元素、介绍国家重大工程、引入警示性案例等方面入手,探索如何将思政元素融入化工原理课程教学,并通过创新教学内容与方法,提升教学效果和育人成效。教改践行了“价值引领、知识传授、能力培养”三位一体的教育教学理念。