High-resolution electron microscopy of the twinning and intergrowth in Ca4Al6SO16 and Ca3SrAl6SO16

The microstructures of unhydrated calcium aluminosulphate Ca₄Al₆SO₁₆ and Ca₃SrAl₆SO₁₆ have been studied by high-resolution electron microscopy (HREM). The results showed that twinning and twinned slabs could be introduced taking the [1 1 2] direction as the twin axis so that it seems to be coincident with the law of twinning formed in body-centred cubic structures. A previously reported superlattice with a repeat period twice that of the fundamental structure along the 〈1 1 0〉 direction has also been found in both matrix and twin variants. The close intergrowth of Ca₃SrAl₆SO₁₆ and another phase, possibly Sr₃Al₂O₆ existing as an inclusion between these two twin variants, was determined and clearly revealed by electron diffraction and HREM images. The coherent interphase boundaries and orientation relationship between them can also be deduced.     

锦州市区抽取地下水与地面沉降问题的探讨

本文通过分析锦州市区地质构造条件、水文地质条件及地面沉降的原因,提出了锦州市区一般不会因为抽取地下水而引起地面沉降的探讨结论。     

Preparation, sintering, and microstructures of strontium barium bismuth tantalate layered perovskite ceramics

The solid solutions of Ba-doped SrBi₂Ta₂O₉ layered perovskite ceramic powders have been successfully prepared via a two-step process using BiTaO₄ as a precursor. The lattice constants of the solid solutions monotonically increase with increasing barium-ion content. The sinterability of (Sr_1–xBa_x)Bi₂Ta₂O₉ powders is significantly improved by increasing the barium-ion content. When the specimens with high barium-ion contents are sintered at 1100°C, they thermally decompose to form rod-like grains and the matrix expands, leading to a lower density. The addition of barium ions to SrBi₂Ta₂O₉ also results in significant variation in the morphology of the sintered specimens and the occurrence of c-axis preferred orientation which is ascribed to the anisotropic growth of plate-like grains. The precise control of the barium-ion content as well as the sintering conditions is critical for obtaining densified barium-ion doped SrBi₂Ta₂O₉ ceramics with a pure, layered perovskite structure.     

上海外环隧道水下最终接头的施工技术

沉管隧道采用水下最终接头,可以大大缩短工期和减少成本,但施工难度较大,而且有一定风险。文章以上海外环隧道工程为例,对沉管隧道水下最终接头的施工工艺中管段轴线精度控制、安装保护罩、间隙间的安全排水和混凝土施工等四大难点进行探讨,并介绍了水密性施工和管内结构施工的具体工艺和步骤。指出其成果对今后类似工程具有较大的参考价值。     

Protein binding study of isoflavone, perillyl alcohol and S-ibuprofen by high-performance frontal analysis

High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein), enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total binding affinities (nK) of drugs to HSA were calculated, respectively.     

应用PIMS选油模型实施进口原油优化选购

应用AspenTech公司PIMS软件，模拟炼油企业生产经营过程，综合考虑原油成本、产品价格以及长岭分公司炼油厂加工流程特点和产品质量等要求，建立了适用于该厂的原油选购模型。利用该模型对该企业2002年第三季度进口原油品种进行优化选择，对综合效益好的原油实施采购。实际生产数据表明，该模型比较准确。     

大坝洪水漫顶风险评估

洪水漫顶是导致大坝溃坝的主要原因之一,大坝洪水漫顶风险评估是大坝风险评估的重要组成部分。为此,简要介绍了大坝洪水漫顶的风险模型,并通过实例详细地讨论了模型中各有关参数的不确定性处理方法,探讨了入库洪水的不确定性对洪水漫顶风险率的影响以及按规范设计的大坝的防洪能力问题。     

山西沁南煤层气井试气工艺分析

对山西沁南地区三口煤层气井试气施工工艺进行总结分析，改进了注入压降测试管柱，采用电潜泵法对煤层排采测气。对今后煤层气井的施工具有一定的指导意义。