Acoustic Detection of Phase Transitions at the Nanoscale

Materials near structural phase transitions find applications in a wide range of devices. Typically, phase transitions are determined macroscopically through measurements of relevant order parameters and related property coefficients. Here, a method for understanding electric field induced phase transitions in ferroelectrically active materials at the nanometer scale via acoustic detection with band‐excitation piezoresponse force microscopy (BE‐PFM) is introduced. Specifically, the field‐induced rhombohedral (R) to tetragonal (T) phase transition in single crystal 0.72PbMg_1/3Nb_2/3O₃‐0.28PbTiO₃ (PMN‐PT) is mapped. It is shown that due to sample heterogeneity, some regions are more prone to the R–T transition, and display signatures in the acquired piezoresponse loops, as well as pronounced softening in the elastic modulus (monitored via the resonant frequency and calibrated with models of cantilever dynamics) that occurs just prior to phase switching. Landau–Devonshire thermodynamic theory confirms the stability of the tetragonal phase under applied fields in PMN‐PT, while phase‐field modeling suggests that the transition evolves smoothly in the probed volume of the tip, both in agreement with the BE‐PFM results. These results confirm the validity and utility of utilizing acoustic changes at phase transitions to detect their onset in nanoscale probed volumes, allowing spatial mapping of their onset with unprecedented resolution.     

Geometric and material nonlinear analysis of three-dimensional steel frames

Results obtained through theoretical and empirical studies which examined the nonlinear behaviour of construction members enabled us to characterize the behaviour of construction systems under external effects more closely. The calculation methods that took into consideration the nonlinear behaviour of the construction members and the nonlinear effects of their geometrical variations had to be developed in order to evaluate these phenomena and to design structures according to their collapse load principle. In the presented study, a computer program was developed for the characterization of structural systems by taking into consideration the nonlinear conditions of material behaviours under increasing loads and by considering the second-order effects. A matrix-replacement method was used as the basis for developing the program, which takes into consideration the effects of axial forces on the stiffness of the member by using the stability functions and the effects of plastic hinges by systematically changing the stiffness matrix in each occurrence of the plastic hinges. In the study, based on the results obtained from the examples, which were solved by the developed program, it was identified that the program could yield rapid and reliable results depending on the user-defined values (number of nodes, error limit for the iteration) and it is observed that the results are consistent with the literature. The obtained results in this study have contributed to capability of converting two dimensional analyses to three-dimensional analysis of stability functions developed.     

Electroluminescence properties of a PIN structure made by nearly stoichiometric a-SiCx:H active layer

a-SiC_x:H PIN diode has been fabricated within a single pump-down process under the same deposition conditions used for doped and undoped PECVD grown thin films, whose optical and electrical properties are determined and compared with a-Si:H. Current-voltage characteristics of PIN diode are evaluated and concluded to be limited by tunnelling of holes at p-i interface into valence band tail states. Electroluminescence measurements revealed radiative monomolecular recombinations. Deconvolution of the luminescence spectra is utilized to analyse recombination mechanism to be dominated by the transitions between band tails and deep states, which are created by the large density of both silicon and carbon dangling bonds, probable in the stoichiometric a-SiC_x:H film. Finally, a small luminescence peak around 1.9 eV would be an evidence of reduced probability of tail to tail transitions, than that of the transitions between tail and deep states.     

An Indicator Based Assessment for Water Resources Management in Gediz River Basin,Turkey

In this study, a water resources management model that facilitates indicator-based decisions with respect to environmental, social and economic dimensions is developed for the Gediz River Basin in Turkey. The basic input of the proposed model is the quantity of surface water that is greatly allocated to irrigation purposes; therefore, supply and demand interrelations in agricultural water use constitute the main focus of the study. The model has been applied under three different hydro-meteorological scenarios that reflect baseline as well as better and worse conditions of water supply and demand, not only to reach an assessment of water budget, but also to evaluate the impacts of proposed management alternatives under different conditions. The Water Evaluation and Planning (WEAP) software is used as a simulation and evaluation tool to assess the performance of possible management alternatives, which is measured by nine proposed indicators. The results of the study have indicated that the Gediz River Basin is quite sensitive to drought conditions, and the agricultural sector is significantly affected by irrigation deficits that increase sharply in drought periods. Even if the optimistic scenario is assumed to occur, it is not possible to observe a significant improvement in the water budget; however, the negative impacts of climate change can possibly exacerbate the water crisis. The indicators also verified that, efficient water management is crucial to ensure the sustainable use of water resources with respect to environmental, social and economic dimensions.     

A numerical simulation study for the human passive thermal system

The objective of this study is to create a dynamic model representing a transient three-dimensional passive thermal model of the human body. The model is a multi-segmental, multi-layered representation of the human body with spatial subdivisions which simulates the heat transfer phenomena within the body and at its surface. In order to represent the mechanisms of heat transfer within the body, energy balance equations including conduction with adjacent tissue, heat storage, metabolic heat generation, and convective heat transfer due to the blood flow in the capillaries are taken into consideration for each tissue. The present model of the passive system accounts for the geometric and anatomic characteristics of the human body and considers the thermo-physical and the basal physiological properties of tissue materials. It is assumed that the body is exposed to combination of the convection, evaporation and radiation which are taken into account as boundary conditions when solving the passive thermal system equation. The model is capable of predicting human body temperature in any given environmental conditions. Finite difference solution scheme is used to find out the temperature distribution of human body. The results are compared with the experimental data of previous studies present in the literature. Consequently, the numerical results of present model show good agreement with the experimental data.     

Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure–property relationships of the cured materials have also been presented and discussed.     

Isolation of some active compounds from Origanum vulgare L. ssp. vulgare and determination of their genotoxic potentials

Origanum vulgare L. (oregano) is a flavoring herb widely used around the world. In the present study, crude extract of O. vulgare L. (oregano) and its petroleum ether, chloroform, ethyl acetate, n-butanol, water fractions were prepared in order to isolate and investigate antimutagenic compounds from the active extract through the bacterial genotoxicity assay guided fractionation procedures. The methanol extract and its n-butanol fraction showed significant antimutagenic activity. In the end of sub-fractionation process of the n-butanol extract, luteolin 7-O-glucuronide and luteolin 7-O-xyloside were isolated. These compounds showed significant antimutagenic activity against 9-Aminoacridine and N-Methyl-N′-nitro-N-nitrosoguanidine mutagenicity. The inhibition rates ranged from 22.1% (luteolin 7-O-xyloside: Salmonella typhimurium TA1537 – 0.4 mM/plate) to 67.8% (luteolin 7-O-glucuronide: S. typhimurium TA1537 – 0.8 μM/plate). In conclusion, the results revealed that luteolin 7-O-glucuronide and luteolin 7-O-xyloside are two of the antimutagenic compounds of O. vulgare L. ssp. vulgare.     

Synthesis and Characterization of Polyacetylene with Side-chain Thiophene Functionality

A new polyacetylene derivative with electroactive thiophene substituent, namely poly(2-methylbut-2-enyl thiophene-3-carboxylate) was synthesized and characterized. For this purpose, novel acetylene monomer was synthesized by the reaction of 3-thiophenecarboxylic acid with propargyl bromide and polymerized with a Rh catalyst to give the corresponding polymer. The chemical structure of the polymer was characterized to comprise the conjugated backbone and electroactive thiophene side group. UV spectral changes of the polymer with temperature were also studied. The polymer exhibited better thermal stability than the unsubstituted polyacetylenes.