Particle-phase dry deposition and air-soil gas-exchange of polybrominated diphenyl ethers (PBDEs) in Izmir, Turkey

The particle-phase dry deposition and soil-air gas-exchange of polybrominated diphenyl ethers (PBDEs) were measured in Izmir, Turkey. Relative contributions of different deposition mechanisms (dry particle, dry gas, and wet deposition) were also determined. BDE-209 was the dominating congener in all types of samples (air, deposition, and soil). Average dry deposition fluxes of total PBDEs (sigma7PBDE) for suburban and urban sites were 67.6 and 128.8 ng m(-2) day(-1), respectively. Particulate dry deposition velocities ranged from 11.5 (BDE-28) to 3.9 cm s(-1) (BDE-209) for suburban sites and 7.8 (BDE-28) to 2.8 cm s(-1) (BDE-154) for urban sites with an overall average of 5.8 +/- 3.7 cm s(-1). The highest sigma7PBDE concentration (2.84 x 10(6) ng kg(-1) dry wt) was found around an electronic factory among the 13 soil samples collected from different sites. The concentration in a bag filter dust from a steel plant was also high (2.05 x 10(5) ng kg(-1)), indicating that these industries are significant PBDE sources. Calculated net soil-air gas exchange flux of sigma7PBDE ranged from 11.8 (urban) to 23.4 (industrial) ng m(-2) day(-1) in summer, while in winter it ranged from 3.2 (urban) to 11.6 (suburban) ng m(-2) day(-1). All congeners were deposited at all three sites in winter and summer. It was estimated that the wet deposition also contributes significantly to the total PBDE deposition to soil. Dry particle, wet, and gas deposition contribute 60, 32, and 8%, respectively, to annual PBDE flux to the suburban soil.     

1.25(OH)2 cholecalciferol pulse therapy and the effects of different dialysis membranes on serum PTH levels of haemodialysis patients

Either oral, intravenous or subcutaneous 1.25(OH)2 cholecalciferol is used in the therapy of hyperparathyroidism, which is a serious complication in patients on haemodialysis. We studied a total of 30 patients (10 women and 20 men) and divided them into two groups depending on the different types of dialysis membranes used. In the polysulfone group, mean age was 43.7 +/- 0.97 years and the average dialysis period lasted 29.9 +/- 1.23 months. For the 15 cases in which we used cuprophane membrane the mean age was 40.2 +/- 1.31 years and the average dialysis period lasted 16.2 +/- 0.86 months. The calcium level of the dialysate in both groups was 1.5 mmol/l. According to the study protocol, the determined oral calcitriol dose was 0.07 mg/kg and it was administered intermittently. After one month on high dose calcitriol therapy, treatment was continued with a maintenance dose of 0.03 mg/kg for a further six months. As a phosphate binding agent, daily 3 g calcium carbonate was administered. Before starting this treatment protocol, patients went on a 1 mg/day calcitriol therapy, although the mean PTH level was 424.63 pg/ml and the mean serum alkaline phosphatase level was 290.2 U/l. During the pretreatment period, levels of PTH, alkaline phosphatase, ionized calcium, and total calcium remained significantly within normal limits as a result of the new therapy protocol applied. PTH and phosphorus clearance rates were compared in the patient groups in which different dialysis membranes had been used. PTH and phosphorus clearances were 15.2 +/- 3 ml/min and 239.1 +/- 19.2 ml/min, respectively, in the polysulfone membrane group, and 1.1 +/- 0.3 ml/min and 112.8 +/- 9.88 ml/min, respectively, in the cuprophane membrane group (p < 0.05).     

Congenital erythropoietic porphyria successfully treated by allogeneic bone marrow transplantation

The long-term biochemical and clinical effectiveness of allogenic bone marrow transplantation (BMT) was shown in a severely affected, transfusion-dependent 18-month-old female with congenital erythropoietic porphyria (CEP), an autosomal recessive inborn error of heme biosynthesis resulting from mutations in the uroporphyrinogen III synthase (URO-synthase) gene. Three years post-BMT, the recipient had normal hemoglobin, markedly reduced urinary porphyrin excretion, and no cutaneous lesions with unlimited exposure to sunlight. The patient was homoallelic for a novel URO-synthase missense mutation, G188R, that expressed less than 5% of mean normal activity in Escherichia coli, consistent with her transfusion dependency. Because the clinical severity of CEP is highly variable, ranging from nonimmune hydrops fetalis to milder, later onset forms with only cutaneous lesions, the importance of genotyping newly diagnosed infants to select severely affected patients for BMT is emphasized. In addition, the long-term effectiveness of BMT in this patient provides the rationale for future hematopoietic stem cell gene therapy in severely affected patients with CEP.     

Red cell lipid peroxidation and antioxidant system in haemodialysed patients: influence of recombinant human erythropoietin (r-HuEPO) treatment

Oral fluids are convenient alternatives to blood sampling for evaluating significant metabolic components. Two forms of oral fluids, oral mucosal transudates (OMT) and saliva, were collected and compared for content of soluble products of immune activation. The data confirm that OMT and saliva represent distinct body fluids. The concentrations, outputs, and analyte/protein ratios of beta-2-microglobulin (beta2M), soluble tumor necrosis factor alpha receptor II (sTNFalphaRII), and neopterin were measured. Both the OMT and the saliva of most of the individuals in the control healthy populations had measurable levels of all three activation markers. When the immune system is activated, as in human immunodeficiency virus (HIV) infection, the levels of beta2M and sTNFalphaRII are increased in both OMT and saliva compared to those in a healthy control population. OMT levels correlated better with levels in serum than did saliva and appear to reflect systemic immune activation in HIV infection. Because acquisition of oral fluids is noninvasive and easily repeatable, measurement of beta2M and/or sTNFalphaRII content in OMT could be useful in the assessment of disease activity in patients with HIV infection or chronic inflammatory diseases.     

Heat transfer from a high temperature safety rod placed in a perforated guide tube and surrounded by an array of cold tubes

In this paper, a simple natural convection heat-transfer model for a safety rod placed in a perforated guide tube is proposed. The geometry is typical of the Savannah River K reactor. The proposed model for the rod and the perforated guide-tube assembly is benchmarked against prototypical test data obtained by Idaho National Engineering Laboratory. The results showed that the proposed model was in good agreement with the experimental data except at very high temperatures where the model slightly underpredicted the rod and tube temperatures. By evaluating the thermal conductivity of the fluid (air) at the wall temperature, the prediction of the high temperature natural convection data was further improved.     

Induktivitäten bei Gleich-, Wechsel- und Mischstrom

Übersicht Angesichts der entscheidenden Bedeutung der magnetischen Nichtlinearität in der Theorie und Anwendung der Elektrotechnik scheint eine gründlichere Behandlung der Induktivitäten angebracht. Die Arbeit erläutert zuerst die Definitionen, die Änderung und die Anwendung der als Oberbegriff genommenen Grundinduktivitäten bei Gleichstrom. Diese sind die Fluß-, die Differential- und die Energieinduktivität. Dann kommen die drei herkömmlichen Möglichkeiten für die Verwendung der Induktivitäten bei periodischem Strom zur Sprache. Mit der Differentialinduktivität kann man die verhältnismäßig kleinen Änderungen der Variablen Strom und Fluß im ganzen erfassen. Die Schwingungsinduktivitäten sind über die ganze Periode, jedoch nur für eine bestimmte Harmonische gültig. Welche physikalische Definition der Induktivität bei periodischem Strom im nichtlinearen Teil der magnetischen Kennlinie gilt, scheint bisher nicht untersucht zu sein.

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Summary In view of the overwhelming importance of the magnetic non-linearity in the theory and application of electrical engineering, a more thorough-going treatment of inductances seems to be desirable. The paper deals at first with the definitions, the variation and the application of basic inductances at d. c. which are considered as an upper concept. These are the flux, the incremental and the energy inductances. Then the three usual possibilities for using the inductances for periodic current are discussed. The incremental inductance includes in the whole the relatively small variations of the variables current and flux. The inductances for harmonics are valid over the whole period, but only for a definitecouple of harmonics, without being associated with the flux as a whole. Which physical definition of inductance is valid for periodic current for the nonlinear part of the saturation characteristic, seems hitherto not to be investigated.

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Computational challenges of viscous incompressible flows

Over the past 30 years, numerical methods and simulation tools for incompressible flows have been advanced as a subset of the computational fluid dynamics (CFD) discipline. Although incompressible flows are encountered in many areas of engineering, simulation of compressible flow has been the major driver for developing computational algorithms and tools. This is probably due to the rather stringent requirements for predicting aerodynamic performance characteristics of flight vehicles, while flow devices involving low-speed or incompressible flow could be reasonably well designed without resorting to accurate numerical simulations. As flow devices are required to be more sophisticated and highly efficient, CFD tools become increasingly important in fluid engineering for incompressible and low-speed flow. This paper reviews some of the successes made possible by advances in computational technologies during the same period, and discusses some of the current challenges faced in computing incompressible flows.     

Experimental investigations of vegetable based cutting fluids with extreme pressure during turning of AISI 304L

Experimental studies on the performances of both new developed environmental friendly vegetable based cutting fluids (refined sunflower and canola oils) including different percentage of extreme pressure (EP) additive and two commercial cutting fluids (semi-synthetic and mineral cutting fluids) in turning processes were reported in this work. Performances of cutting fluids were compared with respect to surface roughness, cutting and feed forces and tool wear during longitudinal turning of AISI 304L. Experimental results were also compared with dry cutting conditions. The results indicated that 8% of EP included canola based cutting fluid performed better than the rest.     

Recycling of inorganic waste in monolithic and cellular glass‐based materials for structural and functional applications

The stabilization of inorganic waste of various nature and origin, in glasses, has been a key strategy for environmental protection for the last decades. When properly formulated, glasses may retain many inorganic contaminants permanently, but it must be acknowledged that some criticism remains, mainly concerning costs and energy use. As a consequence, the sustainability of vitrification largely relies on the conversion of waste glasses into new, usable and marketable glass‐based materials, in the form of monolithic and cellular glass‐ceramics. The effective conversion in turn depends on the simultaneous control of both starting materials and manufacturing processes. While silica‐rich waste favours the obtainment of glass, iron‐rich wastes affect the functionalities, influencing the porosity in cellular glass‐based materials as well as catalytic, magnetic, optical and electrical properties. Engineered formulations may lead to important reductions of processing times and temperatures, in the transformation of waste‐derived glasses into glass‐ceramics, or even bring interesting shortcuts. Direct sintering of wastes, combined with recycled glasses, as an example, has been proven as a valid low‐cost alternative for glass‐ceramic manufacturing, for wastes with limited hazardousness. The present paper is aimed at providing an up‐to‐date overview of the correlation between formulations, manufacturing technologies and properties of most recent waste‐derived, glass‐based materials. © 2016 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.