水库滑坡位移与水动力耦合预测参数及其评价方法研究

针对库水涨落诱发滑坡致灾机理,在系统分析水库边坡位移与库水位变化规律及其相互作用关系的基础上,运用弹塑性力学基本原理,提出了以库水位下降引起的边坡下滑动力增量作为边坡的加载动力参数,以相应边坡位移变化量作为边坡位移响应参数,以此确定水库边坡库水动力增载位移响应比参数并建立预测模型。运用动力增载位移响应比预测模型对三峡库区典型水库滑坡-黄土坡滑坡关键部位监测点进行了动力增载位移响应比计算,并采用Geostudio软件对该滑坡稳定性进行了数值模拟分析。该滑坡的位移响应特征与稳定性演化规律表明,该滑坡关键变形部位的动力增载位移响应比参数变化规律与其实际位移与稳定性演化规律基本吻合。研究结果表明了动力增载位移响应比参数是水库滑坡有效的位移动力评价参数,可运用该参数及其评价方法对水库滑坡进行稳定性分析与评价。     

A molecular dynamics simulation study on the crystallization of 22,8-polyurethane

By means of the molecular dynamics (MD) simulation, the crystallization mechanism of 22,8-polyurethane which contains hydrogen-bond units is investigated and the results show that the crystallization process at a fixed temperature can be characterized by three stages: (1) The extended chain collapses to a globular random coil; (2) The random coil reorganizes into an ordered lamellar structure; (3) Accompanied with the segments clustering due to the hydrogen-bond formation, the lamellar develops with local defects. Two kinds of hydrogen-bond, which are formed between NH group and CO group (N-H?OC), and between NH group and urethane alkoxy oxygen (N-H?O), respectively, are found to play an important role in the crystallization process of 22,8-polyurethane. Furthermore, the effect of temperature on the crystallization is also studied by selecting three temperatures 200, 300 and 400 K. The lower the crystal temperature is, the slower the crystallization rate is and the stronger the hydrogen-bonding interactions are presented. This is in harmony with the experimental results.     

环氧大豆油的生产技术及其在PVC中的应用

介绍了聚氯乙烯增塑荆环氧大豆油的性质和生产原理，提出了国内环氧大豆油工业生产存在的问题；结合国外先进的环氧化技术提出了相应的改进方法，并介绍了所用的催化剂、工艺条件及稳定荆。同时阐述了环氧大豆油的卫生性及加工性。     

乙炔清净液的循环回用

乙炔清净液循环回用技术解决了乙炔清净液循环回用中硫、磷等杂质的累积问题和排放水中硫、磷含量超标的问题。不仅达到安全生产,而且做到清洁生产和水资源循环利用。     

Preparation and properties of compatibilized PVC/SMA‐g‐PA6 blends

The morphology and mechanical properties of PVC/SMA‐g‐PA6 blends were investigated in this paper. Graft to polymer SMA‐g‐PA6 was prepared via a solution graft reaction between SMA and PA6. FTIR test evidences the occurrence of the graft reaction between SMA and PA6. DSC analysis shows that SMA‐g‐PA6 has a lower melting point of 187°C, which may result in a decrease in crystallinity of PA6 and thus enable efficient blending of SMA‐g‐PA6 and PVC. Compatibilization was evidenced by the dramatic increase in mechanical properties, the smaller particle size and finer dispersion of PA6 in PVC matrix, and, further, a cocontinuous morphology at 16 wt % SMA‐g‐PA6 content. SMA‐g‐PA6 from the solution graft reaction can toughen and reinforce PVC material. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 432–439, 2004     

A high propylene productivity over B2O3/SiO2@honeycomb cordierite catalyst for oxidative dehydrogenation of propane

Boron-based metal-free catalysts for oxidative dehydrogenation of propane (ODHP) have drawn great attention in both academia and industry due to their impressive activity and olefin selectivity. Herein, the SiO₂ and B₂O₃ sequentially coated honeycomb cordierite catalyst is designed by a two-step wash-coat method with different B₂O₃ loadings (0.1%–10%) and calcination temperatures (600, 700, 800 °C). SiO₂ obtained by TEOS hydrolysis acts as a media layer to bridge the cordierite substrate and boron oxide via abundant SiOH groups. The well-developed straight channels of honeycomb cordierite make it possible to carry out the reactor under high gas hourly space velocity (GHSV) and the thin wash-coated B₂O₃ layer can effectively facilitate the pore diffusion on the catalyst. The prepared B₂O₃/SiO₂@HC monolithic catalyst exhibits good catalytic performance at low boron oxide loading and achieves excellent propylene selectivity (86.0%), olefin selectivity (97.6%, propylene and ethylene) and negligible CO₂ (0.1%) at 16.9% propane conversion under high GHSV of 345,600 ml·(g B₂O₃)⁻¹·h⁻¹, leading to a high propylene space time yield of 15.7 g C₃H₆·(g B₂O₃)⁻¹·h⁻¹ by suppressing the overoxidation. The obtained results strongly indicate that the boron-based monolithic catalyst can be properly fabricated to warrant the high activity and high throughput with its high gas/surface ratio and straight channels.     

大掺量粉煤灰高性能混凝土的研究

本文从高分散性表面活性剂显著影响粉煤灰的形态效应而大幅降低混凝土用水量的角度出发,利用复合激发剂激发粉煤灰的火山灰效应,结合粉煤灰自身的微集料效应提高混凝土强度的技术手段,探讨了大掺量粉煤灰在混凝土中的应用,分析了高分散性表面活性剂与复合激发剂的组合对大掺量粉煤灰混凝土的作用机理。     

封端型多异氰酸酯加成物的合成

使用甲乙酮肟、己内酰胺及苯酚等不同的封端剂合成了一系列封端型多异氰酸酯加成物。通过DSC和TGA研究了不同封端剂和不同多元醇对封端型异氰酸酯加成物解封温度的影响。测试并比较了各种封端型异氰酸酯加成物与端羟基聚丁二烯的反应物达到凝胶所需要的时间;并探讨了封端加成物在不同聚合物多元醇中的溶解性能及封端型加成物结构与性能之间的关系。     

丁腈橡胶装置腈水提浓系统的优化改造

通过增加1台立式滗析器,对中国石油兰州石化公司15kt/a丁腈橡胶装置腈水提浓系统进行改造。改造后经提浓的丙烯腈质量分数大于90%,可直接用于聚合反应;单体转化率基本达到73%左右;产品质量提高,生产成本降低。