Assessment of Durability and Long Term Performance of High Density Polyethylene Drainboards in the Gotthard Railway Tunnels

Drainage layers provide permanent relief of hydrostatic water pressure, while the waterproof liner prevents any ingress of water into the tunnel. The durability and aging resistance of drainage membranes are of primary concern. This paper describes advantages and concerns related to the usage of, and the design with, polymeric drainboards in tunnel construction. Common degradation mechanisms associated with HDPE （high density polyethylene） sheets are described. The stringent requirements for the Gotthard Alpine Railway Tunnel through the Swiss Alps, e.g., high ambient temperatures of up to 45 ℃ and an expected service life of up to 100 years require outstanding aging resistance of polymeric drainage materials. The paper describes the methods deployed to investigate the long-term performance of HDPE drainboards, focusing on aging mechanisms. Details associated with the test procedures developed to reflect the specific properties of drainboards, as well as the results obtained, are presented. A summary table shows recommended product specifications needed to confine the aging properties of drainboards and to design a system performing adequately during the entire lifetime of the structure.     

Effects of calcium chloride and calcium lactate applications with osmotic pretreatment on physicochemical aspects and consumer acceptances of dried papaya

This study explored the effects of calcium chloride (CaCl₂) and calcium lactate (Ca‐L) pretreatments prior to osmotic dehydration on physicochemical characteristics and consumer acceptance of dried papaya. Three different calcium concentrations [0.5, 1.5 and 2.5% (w/v)] were applied to samples before they were soaked in a 30 °Brix sucrose solution and subsequently dried at 70 °C. The results showed that the dried samples treated with calcium exhibited significantly lower moisture content, water activity, apparent density and shrinkage, while volume was higher when compared to the control. Calcium applications did not obviously influence sugar content of samples and maintained the quality of dried papaya in terms of colour and textural characteristics. Calcium chloride at 2.5% (w/v) was found to particularly impart undesirable bitterness to the dried papaya. In contrast, using 2.5% (w/v) Ca‐L provided the best acceptance scores. Thus, the use of Ca‐L could be an alternative to CaCl₂ in the pretreatment of fruits prior to drying as it offers improved quality.     

Modeling fixed-bed drying of bark

A model for fixed-bed drying of bark has been developed. The model takes heat and mass transfer between the air and bark into account and the volumetric heat transfer coefficient was used as fitting parameter in the model. The assumption of adiabatic saturation of the air leads to too high drying rates but a model with three size fractions shows good agreement both between experimental laboratory data and data from an industrial dryer. A sensitivity analysis for different air temperatures, air velocities, and bed heights show how the dryer capacity depends on these parameters.     

Optical investigation of laser-produced C2 in premixed sooty ethylene flames

Emission from laser-produced C₂ has been studied at different heights in premixed ethylene---oxygen---nitrogen flames at various fuel-oxidant ratios and laser pulse energies for the wavelengths 266, 355, and 532 nm. At the laser wavelengths 355 and 532 nm, the laser-produced C₂ emission was detected in sooting flames, both in the sootfree reaction zone and in the sooty region, whereas using 266 nm radiation it was observed both in sooting and nonsooting flames. Polyaromatic hydrocarbons were monitored by laser-induced fluorescence and the properties of the soot particles were determined using scattering/extinction measurements.     

Functional impairment of the individual rat stomach ECL cell in response to sustained hypergastrinemia

ECL cells in the oxyntic mucosa secrete histamine and pancreastatin in response to gastrin. The present study examined gastrin-evoked ECL-cell responses over a 10-week time span in terms of individual ECL cells and unit ECL cell volume. Rats were treated with omeprazole (400 micromol/kg per day orally). The concentrations of gastrin and pancreastatin in serum and of histamine and pancreastatin in the oxyntic mucosa were measured as was the activity of the oxyntic mucosal histidine decarboxylase (HDC). The ECL cells were visualized by immunostaining of histamine and examined by electron microscopy. The total ECL cell number and volume, and the mean ECL cell diameter and volume were determined. The HDC, chromogranin A (CGA) and cholecystokinin-B (CCK-B) receptor mRNA concentrations were determined. In terms of individual ECL cells and unit ECL cell volume, the serum pancreastatin concentration, the oxyntic mucosal histamine content, HDC activity, and HDC, CGA and CCK-B receptor mRNA contents increased slowly at first and then leveled off or started to decline after 2 weeks. After 10 weeks all ECL-cell parameters (expressed per unit ECL cell volume) were back to or approaching the starting value. In conclusion, sustained hypergastrinemia first activates each individual ECL cell (with a peak after 1-2 weeks) and then causes gradual functional impairment, the activity returning towards the pre-stimulation level.     

Immunohistochemical and in situ hybridization studies of beta-microseminoprotein in the human gastric mucosa

beta-Microseminoprotein is a 10-kDa disulphide-rich protein with unknown function which is present in the mucus of the airways, gastrointestinal tract and urogenital tract. In this paper, an investigation of the distribution of beta-microseminoprotein in the human stomach is reported. Immunohistochemistry and in situ hybridization were used. beta-Microseminoprotein was found to be localized mainly in the antrum part of the stomach and in two types of cells. Cells of the most abundant type (designated M-cells) were the neutral mucin-containing cells in the bottom part of the gastric glands and the surface epithelium. Virtually all these cells contained both beta-microseminoprotein mRNA and protein product. Cells of the second type (designated E-cells) were found in a zone one-third up from the bottom of the gastric glands, where gastric endocrine cells are located. The E-cells were fewer than the M-cells and usually solitary. They seemed to have a high concentration of protein compared with their low mRNA level. The majority of the E-cells contained chromogranin A and gastrin. The observations made have implications for the understanding of the differentiation of the mucosal cells in the antrum of the stomach and form a basis for future studies of beta-microseminoprotein in gastric disease.     

Porous Silica Matrix Obtained from Pyrex Glass by Hydrothermal Treatment: Characterization and Nature of the Porosity

A novel porous silica matrix has been prepared from Pyrex glass, using hydrothermal treatment under saturated-steam condition. This process makes it possible to obtain, in one step, a silica support formed of a homogeneously distributed and interconnected macropore microstructure. The new matrix contains silanol groups that can be used in reactions of surface modification to provide a hybrid material and a selective macrofiltration membrane, and also it can improve chemical inertness. The porous matrix is noncrystalline as obtained and, after thermal treatment at temperatures higher than 950°C, exhibits an X-ray pattern characteristic of α-cristobalite and low volume contraction. The present samples were characterized by scanning electron microscopy, mercury intrusion porosimetry, nitrogen adsorption-desorption isotherms, infrared spectroscopy, X-ray powder diffractometry, atomic absorption, and high-resolution solid-state nuclear magnetic resonance. The results present a new way of producing a macroporous silica matrix.