全文获取类型
收费全文 | 1084篇 |
免费 | 28篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 61篇 |
综合类 | 3篇 |
化学工业 | 254篇 |
金属工艺 | 32篇 |
机械仪表 | 26篇 |
建筑科学 | 22篇 |
能源动力 | 41篇 |
轻工业 | 72篇 |
水利工程 | 1篇 |
无线电 | 71篇 |
一般工业技术 | 195篇 |
冶金工业 | 172篇 |
原子能技术 | 55篇 |
自动化技术 | 110篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 20篇 |
2020年 | 11篇 |
2019年 | 5篇 |
2018年 | 18篇 |
2017年 | 11篇 |
2016年 | 13篇 |
2015年 | 14篇 |
2014年 | 31篇 |
2013年 | 61篇 |
2012年 | 39篇 |
2011年 | 63篇 |
2010年 | 43篇 |
2009年 | 50篇 |
2008年 | 41篇 |
2007年 | 39篇 |
2006年 | 43篇 |
2005年 | 36篇 |
2004年 | 31篇 |
2003年 | 35篇 |
2002年 | 42篇 |
2001年 | 21篇 |
2000年 | 19篇 |
1999年 | 14篇 |
1998年 | 73篇 |
1997年 | 43篇 |
1996年 | 39篇 |
1995年 | 23篇 |
1994年 | 18篇 |
1993年 | 32篇 |
1992年 | 20篇 |
1991年 | 13篇 |
1990年 | 6篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 8篇 |
1986年 | 5篇 |
1985年 | 18篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 11篇 |
1981年 | 14篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 8篇 |
1976年 | 6篇 |
1975年 | 2篇 |
1973年 | 4篇 |
排序方式: 共有1115条查询结果,搜索用时 15 毫秒
41.
Masatoshi Hasegawa Masahito Horiuchi Kyoko Kumakura Junko Koyama 《Polymer International》2014,63(3):486-500
Alkyl‐substituted cyclobutanetetracarboxylic dianhydrides (CBDAs) were synthesized by photo‐dimerization of alkyl‐substituted maleic anhydrides to obtain novel colorless polyimides (PIs). Dimethyl‐substituted CBDA (DM‐CBDA) showed much higher polymerizability with various diamines than conventional cycloaliphatic tetracarboxylic dianhydrides and led to high molecular weights of PI precursors. Polyaddition of non‐substituted CBDA and trans‐1,4‐cyclohexanediamine (t‐CHDA) was completely inhibited by salt formation in the initial reaction stage. The use of DM‐CBDA allowed the formation of a homogeneous/viscous PI precursor solution by overcoming the salt formation problem. The prominent substituent effect probably reflects how the methyl substituents of DM‐CBDA contributed to increasing the salt solubility. Some of the thermally imidized DM‐CBDA‐based systems simultaneously possessed non‐coloration, low coefficient of thermal expansion (CTE), very high Tg exceeding 300 °C and very low dielectric constant. Copolymerization was very effective for improving the solubility of DM‐CBDA‐based PIs. The copolyimide cast films prepared via chemical imidization displayed a further decreased CTE without sacrificing other target properties, suggesting that the present materials can be useful as plastic substrates in display devices. The mechanism of self‐chain orientation behavior during solution casting is also discussed. A potential application of the copolyimide systems as optical compensation film materials in liquid crystal displays is proposed. © 2013 Society of Chemical Industry . 相似文献
42.
Yutaka Kawahara Atsushi Nakayama Masatoshi Shioya Masaki Tsuji Hideki Yamane Tadahisa Iwata 《Journal of Materials Science》2012,47(4):1887-1892
Structure of poly(dioxanone) (PPDX) fibers produced through a two-step melt-spinning process with an additional short-period
annealing above the melting temperature of PPDX was investigated and the effect of annealing on the degradation behavior was
discussed. The morphological study carried out by etching the fibers using a phosphate or permanganate solution suggested
that the fibers take a skin–core structure, and both the skin layer and the core region consist of a bundle of microfibrils.
The micro-beam X-ray diffraction analysis revealed that the short-period annealing in the production process only slightly
promotes the crystallization in the skin layer but contributes to increasing the packing of amorphous chains near the skin,
which seems to be the controlling factor of the hydrolytic degradation behavior of the fibers. 相似文献
43.
44.
45.
Ahn Seongyool Yu Panlong Watanabe Hiroaki Kurose Ryoichi Tanno Kenji Kitagawa Toshiaki 《Journal of Mechanical Science and Technology》2021,35(5):2209-2218
Journal of Mechanical Science and Technology - A three-dimensional numerical simulation was performed to investigate the physics and combustion characteristics of a two-phase reacting turbulent... 相似文献
46.
Yosuke Yamazaki Yohei Abe Yukio Hioki Mitsuyoshi Nakatani Akikazu Kitagawa Kazuhiro Nakata 《Welding International》2016,30(10):745-754
Narrow gap welding with an oscillation laser beam is one of the effective processes for thick plate welding. To put this welding process into practical manufacturing, a groove-sensing system using image processing for narrow gap welding with an oscillation laser beam is used. This developed system uses still images of the weld zone taken by a coaxial CMOS camera. It can recognize the position of the groove wall by analysing the brightness distribution in the still image. It can then control the oscillation width and the laser-irradiated area by calculating the groove width and the groove centre position. Some narrow gap welding experiments were performed to evaluate the performance of the developed system. The results revealed that the developed system is effective for narrow gap welding with an oscillation laser beam. Using this system, the narrow gap groove can be welded even if the groove width has changed during the welding process. 相似文献
47.
Improvement in impact strength of modified cardanol‐bonded cellulose thermoplastic resin by using olefin resins 下载免费PDF全文
Impact strength of a modified cardanol‐bonded cellulose thermoplastic resin was greatly improved by using a small amount of olefin resins. As we showed, this thermoplastic resin (3‐pentadecylphenoxy acetic acid (PAA)‐bonded cellulose diacetate (CDA): PAA‐bonded CDA) exhibited high practical properties such as bending strength, heat resistance, and water resistance. However, its impact strength was insufficient for use in durable products. We improved the impact strength of PAA‐bonded CDA by adding hydrophobic olefin resins, such as polyethylene or polypropylene, while maintaining good bending strength and breaking strain. Furthermore, the application of olefin resins also increased water resistance and fluidity. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39829. 相似文献
48.
Main‐chain smectic liquid crystalline polymer exhibiting unusually high thermal conductivity in an isotropic composite 下载免费PDF全文
Shusuke Yoshihara Masatoshi Tokita Toshiaki Ezaki Mitsuru Nakamura Masashi Sakaguchi Kazuaki Matsumoto Junji Watanabe 《应用聚合物科学杂志》2014,131(6)
The thermal conductivity (TC) of an isotropic composite comprising of a main‐chain smectic liquid crystalline PB‐10 polyester and 50‐μm‐sized roughly spherical magnesium oxide (MgO) particles is investigated. The increase in the composite TC with higher MgO fractions is steeper than that expected by Bruggeman's theory for the TC of a polydomain PB‐10 polyester (0.52 W m?1 K?1). When the filler content is larger than 30 vol %, the composite TC approaches a value that can be explained only if the polyester functions as a matrix with 1.0 W m?1 K?1, which is five times as high as those of isotropic common polymers (0.2 W m?1 K?1). Such an unusually high TC for a polymer matrix is attributed to some polymer lamellae that lie parallel to the particle surface and are stacked toward neighboring particles, thus creating effective heat paths between the particles and a continuous thermal network in a composite. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2014 , 131, 39896. 相似文献
49.
Improvement in impact strength of modified cardanol‐bonded cellulose thermoplastic resin by adding modified silicones 下载免费PDF全文
The impact strength of cellulose diacetate (CDA) bonded with a modified cardanol (3‐pentadecylphenoxy acetic acid: PAA) was greatly improved up to 9 kJ/m2 by adding a relatively small amount of modified silicones while suppressing a decrease in bending strength. In our recent research, this thermoplastic resin (PAA‐bonded CDA) exhibited high rigidity, glass transition temperature, and water resistance. However, its impact strength was insufficient for use in durable products. Therefore, silicones modified with polyether, amino, and epoxy groups were investigated as possible ways to improve the impact strength. The results show that adding polyether‐modified silicone (polyether silicone) with moderate polarity relative to PAA‐bonded CDA resulted in shearing deformation greatly enhances its impact strength while maintaining other properties, including glass transition temperature (Tg), water resistance, and thermoplasticity. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40366. 相似文献
50.
Masatoshi Hasegawa Mari Fujii Junichi Ishii Shinya Yamaguchi Eiichiro Takezawa Takashi Kagayama Atsushi Ishikawa 《Polymer》2014
A novel cycloaliphatic monomer for polyimides (PI), 1S,2S,4R,5R-cyclohexanetetracarboxylic dianhydride (H′-PMDA) is proposed in this work. H′-PMDA shows high polymerizability with various diamines in contrast to its isomer, i.e., conventional hydrogenated pyromellitic dianhydride (H-PMDA) and leads to highly flexible and colorless PI films with very high Tg's. In particular, the combinations with rigid structures of diamines give rise to PIs with significantly decreased coefficients of thermal expansion (CTE) owing to high extents of in-plane chain orientation induced by thermal imidization, whereas the H-PMDA-based counterparts do not. The decreased CTE reflects structural rigidity/linearity of the H′-PMDA-based diimide units as supported by liquid crystallinity observed in the corresponding model compound. Solution casting of a chemically imidized PI derived from H′-PMDA and 2,2′-bis(trifluoromethyl)benzidine (TFMB) results in a lower CTE than that of the thermally imidized counterpart, suggesting the presence of a self-orientation phenomenon during solvent evaporation. The mechanism is proposed in this work. H′-PMDA/TFMB and its copolymer systems can be useful as plastic substrates in image display devices and/or novel coating-type optical compensation films. 相似文献