全文获取类型
收费全文 | 368篇 |
免费 | 38篇 |
国内免费 | 1篇 |
专业分类
化学工业 | 150篇 |
金属工艺 | 9篇 |
机械仪表 | 7篇 |
建筑科学 | 24篇 |
矿业工程 | 10篇 |
能源动力 | 6篇 |
轻工业 | 93篇 |
水利工程 | 1篇 |
石油天然气 | 1篇 |
无线电 | 6篇 |
一般工业技术 | 43篇 |
冶金工业 | 13篇 |
原子能技术 | 3篇 |
自动化技术 | 41篇 |
出版年
2023年 | 4篇 |
2022年 | 4篇 |
2021年 | 18篇 |
2020年 | 14篇 |
2019年 | 14篇 |
2018年 | 20篇 |
2017年 | 18篇 |
2016年 | 12篇 |
2015年 | 16篇 |
2014年 | 19篇 |
2013年 | 29篇 |
2012年 | 31篇 |
2011年 | 39篇 |
2010年 | 29篇 |
2009年 | 25篇 |
2008年 | 28篇 |
2007年 | 16篇 |
2006年 | 13篇 |
2005年 | 12篇 |
2004年 | 9篇 |
2003年 | 6篇 |
2002年 | 6篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有407条查询结果,搜索用时 124 毫秒
51.
Information on natural concentrations or variability of secondary metabolites in marine organisms may be important both to ecological/evolutionary and applied approaches. A gas chromatographic procedure with an electron capture detector (GC-ECD) was developed to quantify the sesquiterpenoid elatol at the surface and within-thalli of 70 specimens of the red seaweed Laurencia obtusa. The concentration of elatol was highest within-thalli [9.89 mg g−1 of L. obtusa, dry weight (d.w.)], compared to lower values found at the surface [0.006 mg g−1 of L.obtusa (d.w.), or 0.5–10.0 ng cm−2]. This method provides a rapid and inexpensive quantification of small quantities of elatol, and probably may also be used to quantify other halogenated compounds usually found in red seaweeds. 相似文献
52.
Michele Espinosa da Cunha Laiza Canielas Krause Maria Silvana Aranda Moraes Candice Schmitt Faccini Rosângela Assis Jacques Suelen Rodrigues Almeida Maria Regina Alves Rodrigues Elina Bastos Caramão 《Fuel Processing Technology》2009
In the present work, the process of biodiesel production in a pilot plant has been studied using beef tallow as raw materials with methanol and potassium hydroxide as catalyst. The biodiesel quality is regulated by Brazilian specifications (Resolution 42) by the National Agency of Petroleum (ANP). The alkaline transesterification of animal fat with methanol produces a biodiesel with high quality and also with a good conversion rate. The process is possible but the economical viability must be improved by recovering methanol and glycerin. The obtained results have been used for industrial scale up of the process. 相似文献
53.
Walter Luiz Andrade de Oliveira Silvana De Nardin Ana Lúcia H. de Cresce El Debs Mounir Khalil El Debs 《Journal of Constructional Steel Research》2009,65(12):2103-2110
This paper presents an experimental analysis of the confinement effects in steel–concrete composite columns regarding two parameters: concrete compressive strength and column slenderness. Sixteen concrete-filled steel tubular columns with circular cross section were tested under axial loading. The tested columns were filled by concrete with compressive strengths of 30, 60, 80, and 100 MPa, and had length/diameter ratios of 3, 5, 7, and 10. The experimental values of the columns’ ultimate load were compared to the predictions of 4 code provisions: the Brazilian Code NBR 8800:2008, Eurocode 4 (EN 1994-1-1:2004), AINSI/AISC 360:2005, and CAN/CSA S16-01:2001. According to the results, the load capacity of the composite columns increased with increasing concrete strength and decreased with increasing length/diameter ratio. In general, the code provisions were highly accurate in the prediction of column capacity. Among them, the Brazilian Code was the most conservative, while Eurocode 4 presented the values closest to the experimental results. 相似文献
54.
The physical qualities of butter are affected by the physical properties of the cream used to make it. The objective of this study was to evaluate the effect of high-intensity ultrasound (HIU) on the physical properties of cream and butter. High-intensity ultrasound (frequency: 20 kHz, amplitude: 108 µm), often called sonication, was applied for 0, 10, 30, 60, and 90 s using a 1.27-cm-diameter tip to heavy cream (40% fat; 300 g) that was aged at 7.5°C with low agitation (40 rpm) for 90 min. Sonicated cream was churned at 7.5°C until butter grains were formed. The solid fat content (SFC), melting behavior, and average fat droplet size of cream were measured after HIU treatment. Butter was characterized by SFC and melting behavior immediately after production and was tested for SFC, melting behavior, and hardness after storage for 24 h at 5°C. High-intensity ultrasound did not affect the average fat droplet size of cream. Sonicating cream for 30, 60, and 90 s slightly decreased SFC due to the temperature increase (2–6°C) that occurred during HIU application. Two melting peaks were observed at approximately 17 and 33°C in all the cream samples. A significantly lower peak temperature was observed in cream sonicated for 10 s compared with creams sonicated for 30 and 60 s. A relatively shorter churning time of sonicated cream compared with nonsonicated cream was observed, possibly because HIU weakens the fat globule membrane. Two melting peaks were observed in all butter samples at approximately 16 and 33°C. Treatment with HIU for 10 to 60 s significantly increased the hardness of butter. When HIU was applied to cream for 10 s, the hardest butter was obtained, with the lowest onset temperatures and highest enthalpy values for both melting peaks. Treatment with HIU for 10 s promoted crystallization of low-melting-point triacylglycerols (TAG) during churning, which resulted in a harder material. Significantly lower enthalpy values for the high-melting-fraction TAG were observed in butters treated with HIU for 60 and 90 s compared with non-HIU-treated butter, which suggests that a longer duration of HIU promotes melting of high-melting-point TAG. The hardness of butter was correlated with the enthalpy values of the low-melting fraction and with total enthalpy values of fresh butter. However, further crystallization occurred in the butter during 24 h of storage at 5°C, and all differences in enthalpy values disappeared. In conclusion, exposure of cream to HIU can be used to modify the physical properties of butter, and the effects of HIU depend on the length of HIU treatment. 相似文献
55.
Prof. Chiara Brullo Dr. Federica Rapetti Prof. Silvana Alfei Dr. Irena Maric Dr. Francesca Rizzelli Dr. Marina Mapelli Dr. Camillo Rosano Dr. Maurizio Viale Prof. Olga Bruno 《ChemMedChem》2020,15(11):961-969
Even though immunotherapy has radically changed the search for anticancer therapies, there are still many different pathways that are open to intervention with traditional small molecules. To expand our investigation in the anticancer field, we report here a new series of compounds in which our previous pyrazole and imidazopyrazole scaffolds are linked to a differently decorated phenyl ring through an acylhydrazone linker. Preliminary tests on the library were performed at the National Cancer Institute (USA) against the full NCI 60 cell panel. The best compounds among the imidazopyrazole series were then tested by immunofluorescence staining for their inhibition of cell proliferation, apoptosis induction, and their effect on the cell cycle and on microtubules. Two compounds, in particular 4-benzyloxy-3-methoxybenzyliden imidazopyrazole-7-carbohydrazide showed good growth inhibition, with IC50 values in the low-micromolar range, and induced apoptosis. Both compounds altered the cell-cycle phases with the appearance of polyploid cells. Immunofluorescence analysis evidenced microtubules alterations; tubulin polymerization assays and docking studies suggested the tubulin system to be the possible, although not exclusive, target of the new acylhydrazone series reported here. 相似文献
56.
C. Hoflehner S. Ilie J. Six C. Beal C. Sommitsch 《Journal of Materials Engineering and Performance》2018,27(10):5124-5129
The hot ductility of a low alloyed Cr-Mo steel has been investigated to evaluate the surface cracking sensitivity within the straightening or unbending regime during the continuous casting process. Tensile samples were subjected to various thermal treatments, including melting and solidification, and were tested at deforming temperatures ranging between 600 and 1100 °C using a strain rate of 10?3 s?1. Hot ductility was evaluated based on reduction in area measurement and metallographic investigations. The investigated steel exhibits a drop in ductility at around 800 °C due to intergranular cracking. Microstructural examinations and supplementary thermokinetic computer simulations were carried out to describe the evolution of the microstructure during solidification and cooling. 相似文献
57.
Raffaella Balestrini Cecilia Brunetti Maria Cammareri Sofia Caretto Valeria Cavallaro Eleonora Cominelli Monica De Palma Teresa Docimo Giovanna Giovinazzo Silvana Grandillo Franca Locatelli Erica Lumini Dario Paolo Cristina Patan Francesca Sparvoli Marina Tucci Elisa Zampieri 《International journal of molecular sciences》2021,22(6)
Plant specialized metabolites (SMs) play an important role in the interaction with the environment and are part of the plant defense response. These natural products are volatile, semi-volatile and non-volatile compounds produced from common building blocks deriving from primary metabolic pathways and rapidly evolved to allow a better adaptation of plants to environmental cues. Specialized metabolites include terpenes, flavonoids, alkaloids, glucosinolates, tannins, resins, etc. that can be used as phytochemicals, food additives, flavoring agents and pharmaceutical compounds. This review will be focused on Mediterranean crop plants as a source of SMs, with a special attention on the strategies that can be used to modulate their production, including abiotic stresses, interaction with beneficial soil microorganisms and novel genetic approaches. 相似文献
58.
59.
Tobias E. Schmitzhaus Maria R. Ortega Vega Roberto Schroeder Iduvirges L. Muller Silvana Mattedi Célia de Fraga Malfatti 《工业材料与腐蚀》2020,71(11):1885-1902
The aim of the present study is to evaluate the performance of N-methyl-2-hydroxyethylammonium oleate ([m-2HEA][Ol]) as a corrosion inhibitor for mild steel in a 0.1-mol/L hydrochloric acid solution and also investigate the role of chloride in the inhibition mechanism. This protic ionic liquid (PIL) has formerly shown a high efficiency as a corrosion inhibitor in a neutral chloride medium. Electrochemical and weight loss measurements, surface contact angle determination, scanning electron microscopy, and Raman spectroscopy were used to understand the factors that influence the response of the studied inhibitor. Results revealed that [m-2HEA][Ol] behaves as a mixed-type adsorption inhibitor, by blocking cathodic sites and by modifying the activation energy of the anodic reaction, and it can reach up to 94–97% of inhibition efficiency. PIL adsorption was enhanced by the excess of positive charge of the mild steel. The effect of inhibitor molecule has been discussed to propose a mechanism that explains the inhibitory action of the corrosion inhibitor, pointing out the role of chloride in the inhibition mechanism. 相似文献
60.
Felipe R. Boni Filipe V. Ferreira Ivanei F. Pinheiro Silvana A. Rocco Mauricio L. Sforça Liliane M. F. Lona 《应用聚合物科学杂志》2020,137(45):49416
Here, an alternative route to successfully synthesize polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) is reported. Steglich esterification was used as an effective, metal free approach for coupling carboxylic terminated PS and the hydroxyl end-functionalized PMMA chains obtained by nitroxide-mediated polymerization and atom transfer radical polymerization, respectively. α-Functionalization was obtained using 4,4′-azobis(4-cyanovaleric acid) and 2,2,2-tribromoethanol as initiators. The synthesis of PS-b-PMMA was confirmed by gel permeation chromatography and nuclear magnetic resonance (NMR), while the dependence of the diffusion coefficients of the polymers (PS, PMMA, PS/PMMA blend, and PS-b-PMMA) with their corresponding molecular weights was discussed based on the results of atomic force microscopy-based infrared spectroscopy, differential scanning calorimetry, and spectra of diffusion-ordered NMR spectroscopy. Differently from PS-b-PMMA, a partial segregation was observed for the PS/PMMA blend, affecting its thermal behavior and diffusion coefficient. The study here presented provides an easier and efficient strategy for the synthesis of PS-b-PMMA and new insights into the diffusion of polymers. 相似文献