Control of the particle microstructure during the synthesis of bulk-polymerized transparent methacrylate-acrylonitrile-butadiene-styrene resin

A series of methacrylate-acrylonitrile-butadiene-styrene (MABS) resins was prepared using bulk polymerization. The polarity of the continuous phase and the compatibility of two phases were changed by adjusting the methyl methacrylate (MMA) content, choosing values that were close to styrene-butadiene rubber solubility value. The possibility of controlling the microstructure of the MABS resin by changing the polarity of the components and the compatibility of two phases was assessed. The dynamic mechanical analysis shows that the compatibility of two phases varies with the MMA content. The morphological analysis shows that increasing MMA contents results in a gradual decrease in the sub-inclusion structure with a network skeleton of rubber particles, and that all the particles become solid rubber when the MMA content reaches 75%. The sub-inclusion structure reappears but does not have a network skeleton when the MMA content is 90%. The impact strength and morphological analysis indicate that the solid rubber particles and the sub-inclusion structure with a network skeleton provide excellent toughness, while the sub-inclusion structure without a network skeleton does not. In contrast, the transmittance of the ABS resin first increased and then decreased with increasing MMA content.     

钒掺杂二氧化钛光催化活性研究

二氧化钛凭借优异的光催化性能,越来越受到人们的广泛关注和重视。以钛酸四丁酯为原料,利用水解-水热-干燥/煅烧工艺制备得到未掺杂TiO₂光催化剂和掺钒TiO₂光催化剂,利用其对甲基橙溶液的降解率做了比较分析。结果表明,以钛酸四丁酯为原料,采用溶胶-凝胶法制备钒掺杂TiO₂光催化剂是可行的。制备V/TiO₂产品的最佳工艺条件：钒钛质量比为6∶100、水热温度为160 ℃、水热时间为12 h,120 ℃下干燥14 h。紫外光照射条件下,甲基橙光催化降解效率达到99.10%,降解时间小于45 min。     

核电厂立式泵电机多故障耦合振动问题的处理

某核电厂立式水泵配套电机存在两径向方向振动差异大、启机后振动缓慢上升的振动现象，为解决该问题，本文利用频谱分析、固有频率分析、相位分析等方法进行故障诊断，判断出该配套电机存在结构共振、转子热弯曲、动不平衡的耦合问题，并最终通过调整螺栓及现场动平衡方法成功解决了振动问题。      

Sensitivity analysis of Johnson-Cook material parameters on adiabatic shear in different directions

ABSTRACT

This study investigates the effects of strain, strain rates, and forming directions (RD-rolling direction, TD-transverse direction, and ND-normal direction) on adiabatic shear, via dynamic impact compression tests using the Split Hopkinson Pressure Bar (SHPB) apparatus. A modified Johnson-Cook (J-C) constitutive model is proposed, which used to analyse the influence of the constitutive parameters on the sensitivity of adiabatic shear, employing a finite element software. The different sensitivities of adiabatic shear under different directions are explained by combining microscopic analysis and results from mechanical responses. The results show that the sensitivity of adiabatic shear can be related to the time of stress collapse in the following trend: ND?>?TD?>?RD; the sensitivities of these constitutive parameters on adiabatic shear are calculated and compared.     

海工磨细矿渣混凝土的冻渗性与孔结构研究

在天然海水侵蚀和冻融循环作用下,与普通混凝土对比,对掺加磨细矿渣(GGBS)海工混凝土的抗冻性和抗氯离子渗透性的耦合性能(简称冻渗性)以及孔结构的细观性能进行了研究.用R值代表混凝土冻渗性指标进行分析讨论,结果表明:掺加磨细矿渣的混凝土,无论掺加引气剂与否,水胶比增大,R值逐渐减小;不掺引气剂,矿粉掺量增大,R值减小;掺加引气剂,矿粉掺量增大,R值增大;引气剂掺量增大,R值增大,但引气剂掺量超过一定极限,R值增长不明显;抗压强度等级在40～60 MPa范围内,其强度值与R值没有明显的规律性.MIP结果表明:掺加矿粉和引气剂的海工混凝土经过冻渗后,无害孔和少害孔的数量较多;R值与最可几孔径大小有明显的反比关系.     

聚合氯化铝铁的制备、使用及混凝机制研究

以氯化铝和氯化铁为原料制备出一系列不同铝铁物质的量比及碱化度的无机高分子混凝剂——聚合氯化铝铁（PAFC）,并应用于地表水的混凝处理过程。考察PAFC的混凝效能及产生的絮体特性,进而对其使用条件进行优化并分析混凝机制。结果表明,PAFC为多羟基桥连的铝铁聚合物,水解后发生电中和作用使胶粒脱稳,而后通过羟桥和氧桥联接产生架桥和卷扫沉淀作用,混凝效果优异。PAFC的pH适用范围较宽,但铝铁物质的量比对其水解过程影响较大,在铝铁物质的量比为7:1、碱化度为0.5、投加量为10 mg/L时,絮体的粒度及生长速度最大,此时浊度和UV₂₅₄的去除率分别达84.93%和78.52%。此外,正交实验的结果表明水力条件对PAFC的混凝效能影响显著,其最佳使用条件为：快搅时间为20 s、快搅速度为200 r/min、慢搅时间为15 min、慢搅速度为40 r/min。     

郭沫若的翻译理论与思想探析

从探讨郭沫若的生平背景入手,介绍了他的翻译成就,并对郭沫若的翻译理论和翻译思想做出了初步的剖析。郭沫若的翻译实践主要可以从郭沫若译著《英诗译稿》和《浮士德》窥见一斑,而郭沫若的翻译理论则可从罗新璋所著的《翻译论集》和方克平所著的《溯洄从美:从批判理论到文学翻译》中探出精髓。对郭沫若翻译实践和理论的研究可以发现郭沫若的"创作论"的地位固然不可撼动,但其中对于创作的维度却并没有提出很好的标准。     

Combination of heat treatment and chitosan coating to improve postharvest quality of wolfberry (Lycium barbarum)

The synergistic application of hot water dip at 42 °C for 30 min and 1% chitosan coating on differentiation in postharvest quality traits, microstructure as well as microbiological evolution of wolfberry fruits was investigated. Fresh wolfberry fruits were stored at 2 ± 0.5 °C and 90% relative humidity (RH) for 28 days. Results indicated the combination of prestorage heat treatment and chitosan coating maintained higher levels of ascorbic acid, total phenolic contents and antioxidant capacity as well as lower decay, compared with untreated wolfberry fruits. The possible mechanism was that the heat treatment almost sealed open stomata to limit the sites of pathogen penetration into fruits independently, followed by the biofilm formed by chitosan which controlled secondary infections as well as slowed changes in fruit respiration and metabolic activity in wolfberries. The synergistically treated fruit also exhibited a higher acceptability obtained by sensory analysis after cold storage. In this sense, the integrated application of heat treatment and chitosan coating could be regarded as an effective strategy to extend storage life and maintain the postharvest quality of wolfberry fruits.     

某水电厂励磁系统跨接器故障分析

本文对一起机组起励时灭磁电阻严重烧坏并最终导致停机的事故进行分析,查找出灭磁电阻严重烧坏的原因.通过一系列试验,模拟机组起励停机过程,证明此次故障是由于机械跨接器在实际运行中存在缺陷造成的.最后,为防止此类事故再次发生,提出相关技术改造意见,以保证励磁系统安全稳定运行.     

Heat propagation in thermally conductive polymers of PA6 and hexagonal boron nitride

Thermally conductive polymers offer new possibilities for the heat dissipation in electric and electronic components, for example, by a three‐dimensional shaping of the heat sinks. To face safety regulations, improved fire performance of those components is required. In contrast to unfilled polymers, those materials exhibit an entirely different thermal behavior. To investigate the flammability, a phosphorus flame retardant was incorporated into thermally conductive composites of polyamide 6 and hexagonal boron nitride. The flame retardant decreased the thermal conductivity only slightly. However, the burning behavior changed significantly, due to a different heat propagation, which was investigated using a thermographic camera. An optimum content of hexagonal boron nitride for a sufficient thermal conductivity and fire performance was found between 20 and 30 vol%. The improvement of the fire performance was due to a faster heat release out of the pyrolysis zone and an earlier decomposition of the flame retardant. For higher contents of hexagonal boron nitride, the heat was spread faster within the part, promoting an earlier ignition and increasing the decomposition rate of the flame retardant.