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Changwei Dun Guoxi Xi Ye Zhang Tingting Zhao Yumin Liu Xiaoying Heng Lu Yao 《Ceramics International》2018,44(17):20984-20991
In this study, we investigated the effects of substituting Li+ for Co2+ at the B sites of the spinel lattice on the structural, magnetic and magnetostrictive properties of cobalt ferrites. The Li+ substituted cobalt ferrites, Co1-xLixFe2O4, with x varying from 0 to 0.7 in 0.1 increments, were synthesized with a sol-gel auto-combustion method using the cathode materials of spent Li-ion batteries. X-ray diffraction analysis revealed that all the Co1-xLixFe2O4 nanopowders had a single-phase spinel structure and the lattice parameters decreased with increasing Li+ content, which can be proved by slight shifts towards higher diffraction angle values of the (311) peak. Field emission scanning electron microscopy was used to observe the fractured inner surface of the sintered cylindrical rods and the increased porosity resulted in a decreased magnetostriction. The oxidation states of Co and Fe in the cobalt ferrite samples were examined by X-ray photoelectron spectroscopy. High resolution transmission electron microscopy micrographs showed that most particles were roughly spherical and with sizes of 25–35?nm. Li+ substitution had a strong effect on the saturation magnetization and coercivity, which were characterized with a vibrating sample magnetometer. The Curie temperature was reduced due to the decrease in magnetic cations and the weakening of the exchange interactions. The magnetostrictive properties were influenced by the incorporation of Li+ at the B sites of the spinel structure and correlated with the changes in porosity, magnetocrystalline anisotropy and the cation distribution. 相似文献
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Inam Ridha Ali Basiri Sudhakar Godeshala Md Zubair Ebne Rafique Deepanjan Ghosh Jason Williams Nikhilesh Chawla Jung Keun Lee Jacquelyn Kilbourne Yu Yao Kaushal Rege 《Advanced functional materials》2021,31(6):2007811
Poor strength, infection, leakage, long procedure times, and inflammation limit the efficacy of common tissue sealing devices in surgeries and trauma. Light-activated sealing is attractive for tissue sealing and repair, and can be facilitated by the generation of local heat following absorption of nonionizing laser energy by chromophores. Here, the inherent ability of biomaterials is exploited to absorb nonionizing, mid-infrared (midIR) light in order to engender rapid photothermal sealing and repair of soft tissue wounds. In this approach, the biomaterial simultaneously acts as a photothermal convertor as well as a biosealant, which dispenses the need for exogeneous light-absorbing nanoparticles or dyes. Biomechanical recovery, mathematical modeling, histopathology analyses, tissue strain mapping using digital imaging correlation, and visualization of the biosealant-tissue interface using hyperspectral imaging indicate superior performance of midIR sealing in live mice compared to conventional sutures and glue. The midIR-biosealant approach demonstrates rapid sealing of soft tissues, improves cosmesis, lowers potential for scarring, obviates safety concerns because of the nonionizing light used, and allows adoption of a wide diversity of biomaterials. Taken together, the studies demonstrate a novel advance both in biomaterials for surgical sealing along with the use of nonionizing midIR light, with high potential for clinical translation. 相似文献
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Xi Shen Li-Peng Cao Jian-Fa Zhao Wei-Peng Wang Qing-Qing Liu Yuan Yao Jun-Jie Li Chang-Zhi Gu Ming-Wei Chen Chang-Qing Jin Ri-Cheng Yu 《Journal of the American Ceramic Society》2019,102(11):6469-6474
We propose the question of the modulated structures of copper oxide is caused by the [CuO2] in-plane oxygen vacancy or apical oxygen vacancy. Sr2CuO3+δ single-crystal samples were prepared using high-temperature and high-pressure methods. The major phase of Sr2CuO3+δ (δ = 0.4) single-crystal system is found to be constituted by the 5 a modulated structure with the Fmmm space group, which originates from the [CuO2] in-plane oxygen vacancy appearing in octahedral Cu-O. Besides, the presence of the [CuO2] in-plane oxygen vacancy may obliterate the superconductivity of the system. Experimental results deduce that the oxygen vacancy may appear in the apical oxygen sites in high-temperature copper oxide superconductors. 相似文献
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随着社交媒体的发展,用户之间的关系网络对于社交媒体的分析有很大的帮助。因此,该文主要研究用户好友关系检测。以往的关于用户好友关系抽取的研究主要基于社交媒体上的结构化信息,比如其他好友关系,用户的不同属性等。但是,很多时候用户本身并没有大量的好友信息存在,同时也不一定有很多确定的属性。因此,我们希望基于用户发表的文本信息来对用户关系进行预测。不同于以往的潜在好友推荐算法,该文提出了一种基于注意力机制以及长短时记忆网络(long short-term memory,LSTM)的好友关系预测模型,将好友之间的评论分开处理,通过分析用户之间的评论来判断是否具备一定的好友关系。该模型将好友双方信息拼接后的结果作为输入,并将注意力机制应用于LSTM的输出。实验表明,用户之间的评论对于好友关系预测确实有较大的实际意义,该文提出的模型较之于多个基准系统的效果,取得了明显的提升。在不加入任何其它非文本特征的情况下,实验结果的准确率达到了77%。 相似文献
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构建直流微网容错控制对象模型,调节直流微电网的输出回路参数;以输出功率、直流微网的 参考电压、弱电网下系统惯性响应特征等为约束参量,构建直流微网容错控制目标函数,在不同电网强度下 进行直流微网容错控制的参数自整定性调节,采用无功环比例积分控制方法进行直流微网容错寻优分析, 建立模糊 PID控制模型,采用变结构的模糊 PID控制方法进行直流微网容错控制过程中的自适应加权学习 和误差反馈调节,实现直流微网容错控制改进设计。仿真结果表明,采用该方法进行直流微网控制的容错 性能较好,输出稳定性较强,具有较好的直流微网输出增益。 相似文献