金属钝化剂的合成和应用

简要介绍了金属钝化剂的品种和合成方法及在PE、PP、PS等聚合物材料上的应用。     

纳米技术的发展与市场

综述了纳米科技目前世界发展状况、发达国家争夺主导权的激烈竞争以及世界市场状况 ,叙述了纳米技术在电子信息、生物医药等各方面的应用 ,最后 ,概括介绍了纳米材料的制备方法。     

初轧机主传动系统扭转自激振动的稳定性

用变量摄动法对初轧机主传动系统扭转自激振动的稳定性进行了初步研究，讨论了稳定性条件，为初轧机打滑状态的诊断、监测提供了参考依据。     

Overexpression of amyloid precursor protein of Alzheimer's type in brains of intoxicated children

The coincidence of neuronal stress induced by intoxication and an overexpression of amyloid precursor protein (APP) in the brains of children was examined. Brains of ten children accidentally intoxicated by poisonous mushroom were studied by means of immunohistochemical methods using monoclonal antibodies generated against different domains of APP and glial cell markers. Overexpression of APP was found in the brain neurons of all intoxicated children. Neurons were immunopositive with the antibodies generated against the middle (amyloid beta protein) domain of APP. No extracellular deposits were found in the tissue. Our results provided, for the first time, the evidence that overexpression of APP concomitant with the neuronal stress is age-independent phenomenon appearing not only in the brain of adults but in very young individuals as well.     

Direct electrooxidation of methanol on highly dispersed platinum-based catalyst electrodes: temperature effect

The direct electrooxidation of methanol in acid medium was studied on electrodes made of a perfluorinated membrane with small amounts of metal catalysts incorporated by chemical reduction. Platinum is a good electrocatalyst for this reaction, but needs to be modified by other metals in order to obtain oxidation potentials much more compatible with a working anode in a direct methanol fuel cell. Ruthenium and tin appear to give encouraging results, leading to a negative shift of more than 250 mV as compared to the potential obtained with pure platinum. Other parameters were investigated in this work, such as the working temperature, and the manner of introduction of the methanol into the cell. By gaseous supply, it was possible to carry out measurements at higher temperatures than with methanol in solution, and consequently to greatly improve the performance of the catalytic electrode.     

工程变更及其管理

本文以京秦高速公路 (廊坊段 )为例介绍了在机电工程实施中针对工程变更采用的一套严密科学的工程变更管理程序。履约各方在执行程序过程中 ,职责分明 ,有效地保证了整个项目的顺利实施。     

一维河网非恒定流及悬沙数学模型的节点控制方法

本文的一维河网非恒定流及悬沙数学模型，是根据以一维圣维南方程组，悬沙非平衡输运方程及水位、含沙量节点控制法而建立。首先，利用单一河流有限差分方程组转换形式和节点处质量、能量守恒性，写出所有节点的水位控制方程组。求解此不规则稀疏矩阵方程组得到得有节点的水位，再由单一河流非恒定流的求解方法可获得所有单一河流的断面水位和流量。基于水注的节点水位控制法，本文提出了节点悬沙控制法。假设节点处冲刷或淤积较小，所有节点的含沙量控制方程组可通过输沙量守恒方程用矩阵形式写出。求解此不规则稀疏矩阵方程组，得到所有节点处的含沙量。所有单一河流断面处的含沙量通过单一河流悬沙输运的求解方法获得。本文介绍的模型适用于各种河网类型。作为检验，该模型成功地应用于珠江三角洲流域河网水流及悬沙的数值计算。     

ZrO_2与40Cr钢钎焊中的缓冲层

本试验研究了ＺｒＯ２与４０Ｃｒ钢在加入缓冲层前后的钎焊连接，结果表明：插入缓冲层Ｃｕ和Ｔｉ可以提高接头强度。对每一种缓冲层，存在一最佳厚度，对应的钎焊强度最大。此最佳厚度对Ｃｕ为０．４ｍｍ左右，对Ｔｉ为１ｍｍ左右。作者认为这是由缓冲层的力学性能和热膨胀系数对残余应力释放产生的两种相反影响而造成的。钎焊时，缓冲层Ｃｕ和Ｔｉ向钎料中均有程度不同的溶解，但不影响钎料对ＺｒＯ２的浸润和反应结合。ＺｒＯ２－４０Ｃｒ钢连接的所有接头均断在陶瓷的近缝区，其断裂方式有三种。     

溶胶-凝胶法制备(Sr,Pb)TiO3纳米晶粉及表征

采用溶胶－凝胶法成功地合成了（Sr,Pb)TiO3纳米晶粉，并利用FTIR技术对凝胶的形成过程及350℃，1．5h煅烧获得的粉体材料进行了表征。实验以TG－DSC分析作为拟定煅烧温度的依据，以XRD作为煅烧产物的分析手段，最佳煅烧温度为600℃，所合成的（Sr,Pb)TiO3纳米晶粉的平均晶粒尺寸约为21nm，属钙钛矿型立方顺电相结构。     

超声波检测混凝土结构抗冻性的方法研究

依据固体结构动弹模与表面波速度的关系，采用超声波检测混凝土冻融试件的动弹模，并与共振法测出的动弹模进行对比，总结出其内在相关规律，建立起预报混凝土动弹模的回归主程，由测得的波速计算出相应的动弹模，再利用动弹模之比评估出混凝土结构的抗冻性。初步试验和研究表明，此方法研究思路切实可行，符合混凝土冻融特性的基本变化规律，能够实现从度件测试向结构检测的发展，可供混凝土耐久性检测工程参考。