Polyimide/nano-TiO2 hybrid films having benzoxazole pendent groups: In situ sol–gel preparation and evaluation of properties

Polyimide/titania (PI/TiO₂) nanocomposite films have been successfully fabricated through the in situ formation of TiO₂ within a PI matrix via sol–gel method. Poly(amic acid) (PAA), which is the precursor of PI, was successfully synthesized by mixing pyromellitic dianhydride (PMDA), with equimolar amount of a diamine monomer having a pendent benzoxazole unit and two flexible ether linkages in N,N-dimethylformamide (DMF) solvent. Tetraethyl orthotitanate [Ti(OEt)₄] and acetylacetone were then added to the resulted PAA. After imidization at high temperature, PI/TiO₂ hybrid films were formed. The structure and morphology of the hybrid nanocomposites with different titania contents (0 wt%, 5 wt%, 10 wt%, and 15 wt%) were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and transmission electron microscopy. The results indicate that the TiO₂ nanoparticles were homogeneously dispersed in the hybrid films. The thermogravimetric analysis of nanocomposites confirms the improvement in the thermal stability with the increase in the percentage of titania nanoparticle. Transmission electron microscopy showed that the nanoparticles with an average diameter of 25–40 nm were dispersed in the polymer matrix.     

Selective oxidation of glycerol over nitrogen-doped carbon nanotubes supported platinum catalyst in base-free solution

In this communication, N-doped multiwall carbon nanotube (N-MWCNT) supported Pt NPs (1.8 nm) were prepared via a facile routine under microwave irradiation and tested in the selective oxidation of glycerol in an aqueous base-free solution. Characterizations confirmed that N-MWCNTs could improve the dispersion of Pt through strengthened metal-support interactions and donate its electron to metallic Pt. This electron-enriched Pt NPs on the surface of N-MWCNTs is active and stable for the selective oxidation of glycerol.     

Failure analysis of bellows under external pressure

As is the case of a bellows under internal pressure, there also exists a condition for plastic failure when a bellows is loaded under external pressure. In this paper calculating formulae of the critical failure pressure under external pressure are suggested and analyzed by comparing the calculated results and the experimental ones. Close agreement is obtained.     

账面盈利与经营活动现金净流量的相关性研究——基于金属非金属行业上市公司的实证分析

对2004年中国证券市场上的129家金属和非金属行业上市公司的会计账面盈利与现金流量的相关性进行实证研究后,发现两者的相关程度很低,很大一部分上市公司的账面盈利没有形成相应的现金流入,导致两者之间产生“滞脱”的效应.因此,笔者认为在对企业的财务状况进行评价时,不能仅仅局限于使用一些反映企业账面盈利的指标,应该还需要考虑一些反映企业创造现金流量能力的指标.     

Input‐to‐state stability of min‐max MPC scheme for nonlinear time‐varying delay systems

This paper studies the robustness problem of the min–max model predictive control (MPC) scheme for constrained nonlinear time‐varying delay systems subject to bounded disturbances. The notion of the input‐to‐state stability (ISS) of nonlinear time‐delay systems is introduced. Then by using the Lyapunov–Krasovskii method, a delay‐dependent sufficient condition is derived to guarantee input‐to‐state practical stability (ISpS) of the closed‐loop system by way of nonlinear matrix inequalities (NLMI). In order to lessen the online computational demand, the non‐convex min‐max optimization problem is then converted to a minimization problem with linear matrix inequality (LMI) constraints and a suboptimal MPC algorithm is provided. Finally, an example of a truck‐trailer is used to illustrate the effectiveness of the proposed results. Copyright © 2010 John Wiley and Sons Asia Pte Ltd and Chinese Automatic Control Society     

80%莠灭净水分散粒剂的配方

采用了挤压造粒的加工工艺对高含量莠灭净固化新剂型WG(水分散粒剂)进行了研制,尤其对该制剂中的润湿剂、悬浮分散剂、粘结剂和崩解剂的种类及用量进行了筛选,并对该制剂的润湿、崩解、悬浮等性能进行了检测,根据试验结果得到了由2%的烷基萘磺酸钠、4%的马来酸-丙烯酸共聚物钠盐、3%的聚乙烯吡咯烷酮、2.5%的可溶淀粉、83.3%的莠灭净原药(含量为96%)和适量膨润土等组成的较佳配方,该产品的悬浮率在90%以上,崩解时间在1min以内,在(54±2)℃下贮存4周后的分解率小于5%,各项性能指标均符合水分散粒剂的要求。     

免水型生态卫生设施用降解菌的分离筛选

本文对免水型生态卫生设施中的生物填料及施有机肥农田的土壤进行了人类粪便降解菌的分离。筛选得到的各菌种在实验条件下，降解粪便效果较好，除臭除味，COD下降率在30％左右。其中在土壤中分离出来的9号菌，COD下降率达41％，全部菌种复合培养处理的下降率高达59％。结果表明，实验采用的分离筛选方法是比较有效的，筛选得到了具有较好降解效果的菌种，为降解菌的进一步试验打下了基础。     

负载型钴铜双金属氮化物催化氨分解研究

Co and Mo bimetallic nitrides supported on Mg（Al）O, MgO and γ-Al2O3 were prepared in temperatureprogrammed reactions with NH3. The surface morphology, chemical composition and catalytic activity for NH3 decomposition on the supported Co and Mo bimetallic nitrides were studied by X-ray diffractometer （XRD）, NH3 temperature-programmed desorption and mass spectrometer （NH3-TPD-MS）, temperature-programmed desorption and mass spectrometer （TPD-MS）, H2 temperature-programmed surface reaction （H2-TPSR） and activity test. The phases of Co3Mo3N and MoN could be formed on Mg（Al）O, MgO and Al2O3 during the nitridation, and they might be more uniformly dispersed on Mg（Al）O and MgO than on γ-Al2O3. Transition metallic nitrides are generally considered as potential catalysts for hydrogen-involving reactions due to the entrance of hydrogen atoms into subsurface and the lattice of metallic nitrides. The diffusion of nitrogen in the bulk and the structure transformation of Co and Mo nitride compounds occur during NH3-TPD, but the supported Co and Mo bimetallic nitrides are not easily reduced at H2 atmosphere. Co3Mo3N/Mg（Al）O catalyst exhibits the highest activity, while Co3Mo3N/Al2O3 exhibits the lowest activity for NH3 decomposition. Furthermore, the catalytic activity of Co and Mo bimetallic nitrides is not only much higher than that of supported single metallic nitride, but also highly dependent upon the surface acidity and BET surface area of support.     

Modeling for soft sensor systems and parameters updating online

Soft sensor technology is an important means to estimate important process variables in real-time. Modeling for soft sensor system is the core of this technology. Most nonlinear dynamic modeling methods integrate the processes of building the dynamic and static relationships between secondary and primary variables, which limits the estimation accuracy for primary variables. To avoid the problem, a kind of soft sensor model consisting of a dynamic model in cascade with a static one is proposed. The model identification and update online are conducted in substep way. In order to improve the model update efficiency, two improved Gauss–Newton recursive algorithms, which avoid nonsingular covariance matrix, are proposed for time-invariant and time-variant soft sensor systems. The uniform convergence for dynamic model parameter and the existence of estimation deviations for static model parameters are proved for time-invariant soft sensor system. The parameters of time-variant soft sensor system would be boundedly convergent. Case study confirms that, on the basis of the proposed model and recursive algorithms, the dynamic and static characteristics of soft sensor system can be described efficiently, and the primary variables are ensured to be estimated accurately.     

氟两相体系及其在有机合成中的应用

简要介绍了氟化学的发展历史,结合绿色化学和绿色合成技术,介绍了氟化学、全氟溶剂、氟两相体系和氟代催化剂的概念,特性,对氟两相体系在有机合成和催化反应中的应用以及研究进展作了综述。