Preparation,structural and photocatalytic activity of Sn/Fe co-doped TiO2 nanoparticles by sol-gel method

Pure and Sn/Fe co-doped (0.2 at.% Sn and 0.6 at.% Fe, 0.6 at.% Sn and 0.2 at.% Fe, 1.0 at.% Sn and 1.0 at.% Fe) TiO₂ nanoparticles were synthesized via a sol-gel method and subsequently calcined at different temperatures. Furthermore, the particles were analyzed by TG-DSC, XRD, TEM, HRTEM, EDS, SAED and UV–Vis for investigating the influences of dopant and calcination temperature on the thermal effect, composition, morphology, energy band gap (E_g) and the degradation efficiency of methyl orange (MO) under various light irradiations respectively. Results indicated that Sn/Fe co-doping inhibited the crystallization transformation from anatase to rutile phase of TiO₂ and decreased the E_g. The increased calcination temperature and Sn/Fe co-doped effect brought about the abnormal grain growth of TiO₂ nanoparticles. 0.6 at.% Sn/0.2 at.% Fe and 1.0 at.% Sn/1.0 at.% Fe co-doped TiO₂ nanoparticles presented better photocatalytic performance than pure and 0.2 at.% Sn/0.6 at.% Fe co-doped TiO₂ nanoparticles under visible light irradiation mainly due to the decreased E_g. On the contrary, 0.2 at.% Sn and 0.6 at.% Fe co-doped TiO₂ nanoparticles calcined at 650 °C showed the most excellent photocatalytic performance under UV light irradiation, which was about twice as large as that of pure TiO₂ possibly due to the formed hybrid structure of anatase and rutile phase as well as the h⁺-mediated decomposition pathway.     

Hydrothermal synthesis of 3D NixCo1−xS2 particles/graphene composite hydrogels for high performance supercapacitors

In this work, three dimensional (3D) Ni_xCo_1−xS₂/graphene composite hydrogels with different Ni contents (denoted as Ni_xCo_1−xS₂/GH (x = 0, 0.31, 0.56, 0.66, 1)) have been synthesized by a simple one-step hydrothermal method and utilized as the active materials of supercapacitors. The as-prepared samples present a 3D interconnected porous network with the pore sizes in the range of several to tens micrometers. Interestingly, the Ni_xCo_1−xS₂ particles are uniformly located on the graphene network and the particle size is evolved from ∼50 nm to ∼1.5 μm with the increase of Ni content. The electrochemical measurements revealed that the specific capacitance, rate capability and cyclability of different Ni_xCo_1−xS₂/GH electrodes are strongly affected by their different Ni content. Among these, the 3D Ni_0.31Co_0.69S₂/GH composite has the highest specific capacitance of 1166 F/g at a current density of 1 A/g. Furthermore, a specific capacitance of 559 F/g can be still maintained at high current density of 20 A/g. After 1000 charge–discharge cycles at 5 A/g, the specific capacitance remains a high value of 755 F/g.     

基于流媒体的网络视频监控系统研究与实现

介绍了流媒体网络视频监控系统的原理、设计方案和具体实现,给出了用流媒体进行视频数据的采集、显示、传输和控制的方案和实现方法,充分利用了流媒体网络传输特性和Windows多线程机制,详细介绍了如何把DirectShow和WinSock技术相结合,综合使用TCP和UDP多播通信方式,用双缓冲队列进行数据的控制,采用VC 实现了流媒体网络视频监控系统。     

Moving beyond the fourth dimension with an IFC-based single project database

4D CAD has been an active research area for many years. The first generation 4D tools simulated construction schedules and demonstrated the potential benefits in several case studies. Researchers tried to improve the functionality of the first generation 4D tools by adding annotations and highlighting the building elements that have problems. The future generation 4D tools are expected to include more than these. It has been envisioned that 4D models would be part of project databases in order to take decisions related with different project dimensions.This paper presents the development and implementation of a new 4D planning tool which is a part of a product model-based project database. This tool brings the 4D simulation and cost estimation together and aims to contribute to what-if analysis in construction projects. The last part of the paper presents a case study in which the proposed prototype is evaluated.     

重载电力机车制动控制单元的研究

介绍了大功率交流传动货运电力机车微机网络控制系统的结构和特点,对基于WorldFIP现场总线的传输模式作了研究,描述了微机网络各控制单元的功能,并概述了制动控制单元的工作原理,搭建实验通信平台,模拟机车的制动网络控制系统。     

PUF-enhanced offline RFID security and privacy

RFID (Radio Frequency IDentification) based communication solutions have been widely used nowadays for mobile environments such as access control for secure system, ticketing systems for transportation, and sport events. These systems usually depend on readers that are not continuously connected to a secure backend system. Thus, the readers should be able to perform their duties even in offline mode, which generally requires the management by the readers of the susceptible data. The use of RFID may cause several security and privacy issues such as traceability of tag owner, malicious eavesdropping and cloning of tags. Besides, when a reader is compromised by an adversary, the solution to resolve these issues getting worse. In order to handle these issues, several RFID authentication protocols have been recently proposed; but almost none of them provide strong privacy for the tag owner. On the other hand, several frameworks have been proposed to analyze the security and privacy but none of them consider offline RFID system.Motivated by this need, in this paper, we first revisit Vaudenay's model, extend it by considering offline RFID system and introduce the notion of compromise reader attacks. Then, we propose an efficient RFID mutual authentication protocol. Our protocol is based on the use of physically unclonable functions (PUFs) which provide cost-efficient means to the fingerprint chips based on their physical properties. We prove that our protocol provides destructive privacy for tag owner even against reader attacks.     

基于Super-Twisting算法的内燃机车永磁同步发电系统策略研究

为了使内燃机车永磁同步发电系统在内燃机全速范围内和突变性负载条件下均能稳定控制中间直流环节电压且减小电压的脉振,采用Super-Twisting高阶滑模算法对电压外环进行控制得到给定转矩,与传统PI外环控制相比,中间直流环节电压开始的超调减小,且电压跟随性、稳定性得到提升。同时,为了提高发电系统变流器容量利用率,在矢量控制的基础上,提出改进的功率因数控制策略对电机进行控制。仿真试验表明,所提发电系统在内燃机宽转速范围、突变性负载条件下,可以得到平稳且能够快速恢复的中间直流电压。同时,发电系统在切换转矩内无功功率基本能稳定在零附近,超过切换转矩后无功功率依旧保持较低水平,提高了变流器容量利用率。     

方波激励下纳米晶体铁心损耗模型建立与验证

为了实现电力机车小型化轻量化的发展要求,国内外专家考虑通过采用提高变压器的工作频率减小变压器整体的体积和质量。铁心作为高频变压器的关键部件,可以准确计算铁心损耗,对中高频变压器的设计和优化具有重要作用。针对高频变压器铁心通常是工作在方波或脉宽调制(PWM)波等非正弦激励下的特点,对传统Steinmetz损耗计算模型进行了优化改进,给出了考虑磁密的变化率及波形系数对损耗的影响的Steinmetz改进损耗模型。同时,为了提高损耗模型在不同特征频率下的通用性,进一步对损耗模型系数的非线性进行研究,给出了模型系数随频率变化的非线性函数。最后,利用有限元计算结果同实物测量结果进行比较,证明了所提损耗模型在方波激励下对纳米晶体铁心计算的准确性。     

基于改进快速幂次趋近律的永磁同步电机滑模控制

针对永磁同步电机(PMSM)滑模控制指数趋近律中趋近速度与抖振之间的矛盾问题,基于快速幂次趋近律提出一种幂次项系数自适应调节的新型趋近律。所提趋近律将系统状态引入幂次项系数中,实现了系统状态由较远处到滑模面附近的趋近过程中加入幂次项的作用,在保证幂次项特点的前提下,动态响应过程的收敛速度大大提高。负载转矩是滑模速度控制器中的一个扰动项,设计了带有幂次项的滑模观测器,将观测值作为转矩前馈补偿。仿真结果表明,与快速幂次趋近律相比,所提趋近律具有更快的收敛速度,负载观测器能准确跟踪负载变化,提升了系统抗扰性能。     

基于Pro/E的设计与工艺信息共享关键技术研究

阐述了利用Visual C＋＋6．0、Pro／Toolkit和数据库的强大功能从设计信息中提取相关的零部件信息及将工艺信息输出到绘图环境下的具体方法和过程，实现了在Pro／E环境下设计与工艺之间的信息共享、无缝连接，并给出了实例。