Solid–liquid phase equilibria of binary indole mixtures with some aromatic compounds using a solid–liquid–vapor equation-of-state

The separation of useful chemicals, such as indole from coal tar, is an important subject of research in the field of fossil energy, renewable energy, and utilization of byproducts and waste materials. High-pressure crystallization is one of the proposed separation methods. To understand the process requires detailed knowledge of solid–liquid phase behaviors. Solid–liquid phase equilibrium data of various binary mixtures of indole have been reported in the literature. In the present report, we analyze some of the experimental data with our unified solid–liquid–vapor equation-of-state to see whether our model can be useful for the calculation of solid–liquid equilibria in these organic systems. Good correlations of the data and predictions of phase behavior, at very high pressures, are demonstrated.     

Membrane bioreactor with nonwoven fabrics as solid–liquid separation media for wastewater treatment

A nonwoven fabric module was utilized as a solid–liquid separation medium in a membrane bioreactor (MBR) for treating wastewater. The experimental results indicated that nonwoven fabrics had lower filtration resistance than microporous membranes in MBR applications. The optimal aeration intensity was approximately 0.01m³/m² s. The effect of mixed liquor suspended solid concentration on filtration resistance was not significant at an operating flux of under 0.8m³/m² d in the study range. The performance of nonwoven fabrics in a MBR application was further demonstrated in a pilot test. Chemical oxygen demand (COD) and suspended solids (SS) in the effluent were maintained under 60 and 10 mg/L, respectively, whereas influent COD varied from 800 to 1800mg/L. The transmembrane pressure was maintained below 5 kPa at a permeation flux of 0.18m³/m² d. The experimental results demonstrated that nonwoven fabrics maintained stable operation in MBR applications under appropriate operating conditions.     

Long-term and seasonal nitrate trends illustrate potential prevention of large cyanobacterial biomass by sediment oxidation in Hamilton Harbour,Lake Ontario

Several studies have shown that large, experimental additions of nitrate (NO₃) to eutrophic systems can mitigate large populations of nuisance cyanobacteria and that high NO₃ concentrations can oxidize anoxic sediments. These studies are consistent with observations from numerous aquatic systems across a broad trophic range showing development of reduced surficial sediments precedes the formation of large cyanobacteria populations. We use 50+ years of data to explore whether high NO₃ concentrations may have been instrumental both in the absence of large populations of cyanobacteria in eutrophic Hamilton Harbour, Lake Ontario in the 1970s when total phosphorus (TP) and total nitrogen (TN) concentrations were high, and in delaying large populations until August and September in recent decades despite much lower TP and TN. Our results indicate that large cyanobacteria population events do not occur at the central station in July-September when epilimnetic NO₃ > 2.2 mg N L^?1. The results further suggest that remedial improvements to wastewater treatment plant oxidation capacity may have been inadvertently responsible for high NO₃ concentrations > 2.2 mg N L^?1 and thus for mitigating large cyanobacteria populations. This also implies that large cyanobacteria populations may form earlier in the summer if NO₃ concentrations are lowered.     

可见光多相类芬顿降解水中孔雀石绿

为强化多相类芬顿反应的速率,采用可见光辅助树脂载铁(FeIII/R)为催化剂催化过氧化氢降解水中孔雀石绿(MG).结果表明,可见光能强化MG的降解.探讨初始pH值、过氧化氢初始浓度和MG初始浓度及叔丁醇等对反应速率的影响.叔丁醇实验表明羟基自由基和高价态铁在反应中同时存在.催化剂重复使用表明铁在树脂表面负载比较牢固,具有较好的稳定性.     

Design and implementation of a general software library for using NSGA-II with SWAT for multi-objective model calibration

Calibrating watershed-scale hydrologic models remains a critical but challenging step in the modeling process. The Soil and Water Assessment Tool (SWAT) is one example of a widely used watershed-scale hydrologic model that requires calibration. The calibration algorithms currently available to SWAT modelers through freely available and open source software, however, are limited and do not include many multi-objective genetic algorithms (MOGAs). The Non-Dominated Sorting Genetic Algorithm II (NSGA-II) has been shown to be an effective and efficient MOGA calibration algorithm for a wide variety of applications including for SWAT model calibration. Therefore, the objective of this study was to create an open source software library for multi-objective calibration of SWAT models using NSGA-II. The design and implementation of the library are presented, followed by a demonstration of the library through a test case for the Upper Neuse Watershed in North Carolina, USA using six objective functions in the model calibration.     

Identification of relationship between sunspots and natural runoff in the Yellow River based on discrete wavelet analysis

Annual natural runoff is an important index of a river, which may be affected by solar activities. In this study, 304 years of annual natural runoff at the Sanmenxia station located in the Yellow River and the sunspot relative number are decomposed with the application of a Complex Morlet. According to the results of real part, modulus and second power of modulus, the annual runoff series at the Sanmenxia station has an obvious periodic oscillation on 90–100, 50–80, 35–50, 15–35, about 10, and less than 10-year scales. Also, there are obvious periodic variability with 60–90 years, 30–50 years and about 10 years. There are two centers of energy: one is about 1840–1850 on 7–11-year scale and the other is about 1825–1925 on 60–70-year scale. From the wavelet variance, 3, 26, 46, 68 year periods are detected within a 100-year scale, and the 68-year period is the most significant. Similar analyses are conducted for the sunspot relative number within the same period 1700–2003. The sunspot series shows 11- and 60-year period variation, as well as eight energy centers. Then, the correlation analyses for 11- and 60-year serial scales are computed. From a long-term period (1700–2003) view, there is no notable correlation between the natural runoff and the sunspot relative number; however, it is evident that the correlations exist within a short-term period. The results also indicate that the relationships between solar activities and the natural runoff in the Yellow River are complicated.     

Effects of size and autoclavation of fruit and vegetable wastes on biohydrogen production by dark dry anaerobic fermentation under mesophilic condition

Fermentative hydrogen production from fruit and vegetable wastes (FVWs) through Dry Fermentation Technology (DFT) was studied through three independent experiments in order to find out the effect of particle size and autoclaving pretreatment on bio-hydrogen production from FVWs and as follows: (1) autoclaved FVWs with sizes < 5 cm (experiment I); (2) raw FVWs with sizes < 5 cm (experiment II) and (3) autoclaved FVWs with sizes > 5 cm (experiment III). The assay with autoclaved waste yielded a higher percentage of hydrogen in the headspace of the dry fermenter reaching a maximum value of 44% in experiment I. However, the maximum hydrogen production was obtained in experiment III with 14573 NmL at a yield of 23.53 NmL H₂/gVS. Profiling of the microbial communities by denaturing gradient gel electrophoresis (DGGE) indicated that the most prominent species were the genera Clostridium, Bifidobacterium, and Lactobacillus.     

Effect of fine crack width and water cement ratio of SHCC on chloride ingress and rebar corrosion

SHCC (Strain Hardening Cement-based Composite) is a material known for its strain-hardening behavior under tensile and bending stress and its characteristic numerous small cracks. SHCC is expected to show superior durability because of the fineness of the cracks. In this study, chloride ingress through cracks into SHCC and progress of rebar corrosion in three mixtures of SHCC with various water-cement ratios were investigated. Through a chloride solution immersion test, it was confirmed that chloride could penetrate through even very fine cracks. The resistivity of cracked SHCC against chloride ingress is mainly governed by the accumulated crack width and the water cement ratio. Chloride pre-mixed SHCC specimens were left in a high-temperature, high-humidity chamber for 11 months to promote rebar corrosion. While the accumulated crack width and the water cement ratio were both influential to an increase in corrosion area, only the water cement ratio had bearing on corrosion loss.     

供水厂节水优化现状调查与分析

通过对中东部地区的52个常规工艺处理厂自用水消耗情况的调查,分析总结了不同地域城市供水厂工艺单元的类型特点;研究水厂絮凝池、沉淀池的池型及排泥工况对水厂自用水耗水率及排泥水含固率的影响;研究水厂滤池池型及反冲洗工况对自用水耗水率和反冲洗效果的影响;分析了现阶段城市供水厂建有自用水废水回用工艺的比例及工艺特点。