ZnIn2S4/In(OH)3 hollow microspheres fabricated by one-step l-cysteine-mediated hydrothermal growth for enhanced hydrogen production and MB degradation

An intervening barrier for photocatalytic water decomposition and pollutant degradation is the frustratingly quick recombination of e⁻ - h⁺ pairs. Delicate design of heterojunction photocatalysts by coupling the semiconductors at nanoscale with well-matched geometrical and electronic alignments is an effective strategy to ameliorate the charge separation. Here a facile and environment-friendly l-cysteine-assisted hydrothermal process under weakly alkaline conditions is demonstrated for the first time to fabricate ZnIn₂S₄/In(OH)₃ hollow microspheres with intimate contact, which are verified by XRD, SEM, (HR)TEM, XPS, N₂ adsorption-desorption, UV–Vis DRS and photoluminescence spectra. ZnIn₂S₄/In(OH)₃ heterostructure (L-cys/Zn²⁺ = 4, molar ratio) with a band-gap of 2.50 eV, demonstrates the best photocatalytic performance for water reduction and MB degradation under visible light, outperforming its counterparts (In(OH)₃ and ZnIn₂S₄). The excellent activity of ZnIn₂S₄/In(OH)₃ heterostructure arises from the intercrossed band-edge positions as well as the unique hollow structure with large surface area and wide pore-size distribution, which are beneficial for the efficient charge migration from bulk to surface as well as at the interface between ZnIn₂S₄ and In(OH)₃. This work provides an efficient and eco-friendly strategy for one-pot synthesis of heterostructured composites with intimate contact for photocatalytic application.     

物联网在公交车智能监控调度系统中的应用研究

介绍了物联网技术的概念、基本特征、发展现状以及物联网中的关键技术,提出了一种公交车智能监控调度模型,并分析了该系统架构中各个模块的功能,以便在一定程度上促进公交系统的发展,同时也促进物联网的建设与发展。     

基于OPC的焦化厂备煤系统异构网络化控制系统设计

针对焦化厂备煤生产车间内部由于具有多种网络体系或者结构的现场总线及控制系统而造成信息无法共享的问题,提出了一种基于OPC技术的异构网络化控制系统的设计方案,详细介绍了系统的OPC服务器/客户端的设计开发。该系统通过基于工业以太网的TCP/IP体系连接所有子系统,并利用OPC技术为异构数据源提供统一数据接口,使数据管理层能够获取各种数据,解决了异构网络中数据信息转换、集成及存储问题,满足了企业生产过程中信息互操作以及与企业信息系统集成的要求。     

铁矿石境外投资风险评估的模糊神经网络模型

论文将模糊理论与神经网络结合,对铁矿石境外投资所涉及的风险因素分别从资产影响、威胁频度两方面进行分析,建立了铁矿石境外投资的风险层次化结构,并构造了各因素所对应评判集的隶属度矩阵;综合运用模糊推理算法与神经网络仿真技术,对铁矿石境外投资的风险进行评估,进而判定铁矿石境外投资风险等级。最后,通过计算铁矿石境外投资的市场风险说明了算法的应用,并将结果与模糊综合评估得到的风险值进行比较,检测了模型的有效性。     

基于磁记忆检测的桥钢箱梁翼缘损伤状态力磁关系

金属磁记忆检测技术由于其能够快速便捷的对铁磁性构件的损伤进行识别,且被认为具有识别隐性损伤的能力,而被广泛研究。为推进金属磁记忆检测技术在桥钢箱梁损伤检测方面的应用,对桥钢箱梁进行了静力受弯试验,提取其变形最严重的上翼缘磁信号分布,建立了损伤区域力与磁信号和磁信号梯度的关系曲线,并提出用磁场梯度指数来表征钢梁的受力和损伤状态。结果表明:上翼缘磁信号曲线与应力变化形态正好相反,磁信号曲线在进入塑性后发生反转变为负值,且随应力变化的速度增快,可以判断构件进入塑性状态,即将发生损伤;磁场梯度曲线在损伤最严重的区域出现最大值,且随着荷载的增大,磁梯度最大值点不断向钢梁中间移动,由此可以进行破坏状态的预警;磁场梯度与应力关系曲线可将构件整个受力过程明显的区分为初始、屈服、塑性、损伤4个状态;可以用磁场梯度指数来进行构件受力状态与损伤状态的表征。该研究可为金属磁记忆检测技术在桥钢箱梁损伤状态的定量评估和预警方面的应用提供依据和参考。      

碳质金矿中碳质物及其“劫金”机理研究进展

碳质金矿是重要的难处理金矿资源之一,碳质物“劫金”是金浸出率低下的主要原因。碳质物组分复杂,不同组分的碳质物的“劫金”能力和“劫金”行为存在差异,磨矿和浸出环节对碳质物的“劫金”能力也会产生影响,这些因素均能直接影响金的浸出率。通过系统总结碳质金矿中碳质物在组成特征、“劫金”机理及“劫金”能力的影响因素等方面的研究进展,对碳质物“劫金”机理现有研究工作的不足及未来研究方向进行了探讨,为碳质金矿碳质物劫金机理及预处理工艺的研究提供了重要参考。     

Membrane bioreactor with nonwoven fabrics as solid–liquid separation media for wastewater treatment

A nonwoven fabric module was utilized as a solid–liquid separation medium in a membrane bioreactor (MBR) for treating wastewater. The experimental results indicated that nonwoven fabrics had lower filtration resistance than microporous membranes in MBR applications. The optimal aeration intensity was approximately 0.01m³/m² s. The effect of mixed liquor suspended solid concentration on filtration resistance was not significant at an operating flux of under 0.8m³/m² d in the study range. The performance of nonwoven fabrics in a MBR application was further demonstrated in a pilot test. Chemical oxygen demand (COD) and suspended solids (SS) in the effluent were maintained under 60 and 10 mg/L, respectively, whereas influent COD varied from 800 to 1800mg/L. The transmembrane pressure was maintained below 5 kPa at a permeation flux of 0.18m³/m² d. The experimental results demonstrated that nonwoven fabrics maintained stable operation in MBR applications under appropriate operating conditions.     

上拔荷载对斜桩水平承载性状影响的试验研究

斜桩在承受水平荷载的同时,往往会受到上拔荷载的作用。为研究上拔荷载对斜桩水平承载性状的影响,开展了10根直、斜桩的室内模型试验,研究上拔荷载对斜桩桩顶水平位移和水平承载力的影响,对比了直桩与斜桩桩身弯矩和剪力的差异,并分析了上拔荷载对正、负斜桩桩身内力及桩侧摩阻力的影响规律。模型试验结果表明:上拔荷载从直桩水平极限承载力的12.5%增大到75%时,正斜桩水平承载力比增大21%,负斜桩水平承载力比减小25%。上拔荷载的存在会使正、负斜桩桩身轴力均增大,且上拔荷载越大,桩身轴力越大。上拔荷载能减小正斜桩桩身弯矩和剪力,使其抵抗弯矩和剪力的能力得到提高,而增大负斜桩桩身弯矩和剪力,使其抵抗弯矩和剪力的能力被削弱;不论正斜桩还是负斜桩,其上部区段桩身侧表面均出现了方向向上的摩阻力,而下部区段桩身侧表面均为方向向下的摩阻力,随着上拔荷载的增大,斜桩桩身侧摩阻力逐渐增大。     

Evaluation Indicators and Extraction Method for Pitting Corrosion of Structural Steel

A set of evaluation indicators based on corrosion ratio in theory for assessing the extent of pitting corrosion and performance reduction are proposed. In order to quantify the morphology of pitting co...     

TiO2-SnO2 coated bamboo biochar for electrochemical treatment of coking wastewater

A new type of bamboo biochar (BC) loaded TiO₂-SnO₂ particle electrode was prepared and characterized by SEM, FT-IR, BET and XRD for efficient treatment of the coking wastewater in a three-dimensional electrochemical reaction system(3DERs). The results showed that bamboo biochar had a dense microporous space structure, and a significant amount of Ti-Sn oxides existed on the surface and in the interior of the BC. The removal rates of COD and DOC in coking wastewater reached to 73.96% and 66.72% respectively, and UV₂₅₄ reduced from 6.65 cm^-1 to 3.00 cm^-1 by the electrolysis treatment of 150 min at the current density of 30 mA/cm². The three-dimensional fluorescence spectra indicated that the most of the soluble organic compounds and soluble microbial by-products were degraded and transformed. The addition of Ti and Sn enhanced the efficacy of the electrooxidation, electro-adsorption and electrocatalytic behavior of the BC particle electrodes, which improved the treatment effect on coking wastewater in the 3DERs. In addition, this study provides the possibility of basic research for the engineering practice of electrochemical oxidation treatment of coking wastewater.