Effect of particle size on quality of crab meatballs using enzymatically deproteinized crab by-products

The production of crab meatballs generates large amount of crab shell waste, it is therefore necessary to develop a green, economical and environmentally friendly process to vaporize the waste. This study was aimed at investigating the applicability of microwave heating combined with ultrasonic field-assisted alkaline protease (MUSED) (50 ℃, pH = 9.0, 14025.67 U/g, 4.21 h and liquid/material = 14.41:1) for pretreatment of ball-milled crab shells. The ball milling efficiency of the crab shell powder pretreated by MUSED was observed to increase by 50 % compared to the control group, with the final average particle size of D₄ = 4.88 ± 0.20 um. High calcium solubility and low energy consumption of the ball-milled powder increased dietary calcium bioavailability and reduced the potential for high calorie intake. The addition of 6 % (w/w) crab shell powder treated by MUSED improved the texture of the crab meatballs (CM-D₄) and gave the product enhanced crab flavor relative to the control group. Moreover, the lower cooking loss of CM-D₄ resulted in significant retention of nutrients (p < 0.05). The crab shell powder treated by MUSED method was more efficient in ball milling, which improved the quality of crab meatballs while relieving environmental pressure.     

A novel pure red phosphor Ca8MgLu(PO4)7:Eu3+ for near ultraviolet white light-emitting diodes

A novel red-emitting phosphor Ca₈MgLu(PO₄)₇:Eu³⁺ was synthesized by a high-temperature solid-state reaction method. Its crystal structure, photoluminescence emission and excitation spectra, and decay time were investigated in detail. X-ray diffraction (XRD) results indicate that Ca₈MgLu(PO₄)₇ crystallizes in single-phase component with a whitlockite-like structure and the space group R3c of β-Ca₃(PO₄)₂. The emission spectrum shows a dominant peak at 612 nm due to the dipole ⁵D₀→⁷F₂ transition of Eu³⁺, and the luminescence intensity keeps increasing with increasing the content of Eu³⁺ to 100%. The excitation spectrum is coupled well with the emission of near ultraviolet (NUV) LED (380–410 nm). The CIE coordinates of Ca₈MgLu(PO₄)₇:Eu³⁺ phosphor is (0.654, 0.346), being close to the standard value of National Television Standard Committee (NTSC) for red phosphor, (0.670, 0.330). The internal quantum efficiency of the phosphor is 69% under the excitation of 394 nm. The results show that Ca₈MgLu(PO₄)₇:Eu³⁺ is a very appropriate red-emitting phosphor with a high ratio of red and orange for NUV-based white LEDs.     

刍议炸药库安防系统的设置

介绍了炸药的分类及其主要特点,从综合管理平台、入侵报警系统、视频监控系统、出入口控制系统等方面入手,详细阐述了炸药库安防系统的设置要求,指出了目前安防系统设置存在的主要问题,提出了解决问题的对策。     

Methods of choosing the optimal parameters for solid fuel combustion in stoker-fired boilers

Stoker-fired boilers are used for the combustion of coal and solid wastes. The most important disadvantage is their low thermal efficiency. The authors present methods of choosing the optimal rate of travel of the grid and height of the fuel layer basing on both realscale and laboratory measurements. Basing on industrial-scale experiments the authors calculated the optimal thermal efficiency and main energy losses using the least squares adjustment method. The stepwise regression method was used to correlate the main energy losses as functions of grid operating parameters. These correlations were used in the optimization method to estimate the optimal rate of travel of the grid and height of the fuel layer. The minimum retention time of the coal can be also calculated.     

High carrier mobility and remarkable photovoltaic performance of two-dimensional Ruddlesden–Popper organic–inorganic metal halides (PA)2(MA)2M3I10 for perovskite solar cell applications

Two-dimensional Ruddlesden–Popper (2DRP) metal halides have attracted extensive attention in photovoltaic applications due to their high stability, low self-doping levels and long-lived free carriers. Among them, (PA)₂(MA)₂Pb₃I₁₀ presents itself as a superior candidate, demonstrating greater moisture resistance and improved heat and light stability over many other 2DRP metal halides. This study takes on the opportunity to search for lead-free alternatives by investigating the optoelectronic and carrier transport properties, as well as the photovoltaic performance of such (PA)₂(MA)₂M₃I₁₀ type metal halides as the photovoltaic absorber, where M = Pb, Cd, Cr, Cu, Ge, Mn, Ni, Sn, Yb, Zn. Our results indicate that the bandgap of (PA)₂(MA)₂M₃I₁₀ can be tuned to the optimum photovoltaic application range of 0.9–1.6 eV, along with improved optical and enhanced photo-response capacity, when Sn, Cd, Mn, Ge, and Zn are used to replace Pb. In particular, (PA)₂(MA)₂Zn₃I₁₀ possesses the largest Stokes shift and Huang-Rhys factor, while showing the best photoluminescence tendency and broadest emission nature. (PA)₂(MA)₂Ge₃I₁₀ displays the most excellent of carrier transport capacities with high mobilities of 73 cm² V⁻¹ s⁻¹ and 43 cm² V⁻¹ s⁻¹ for electron and hole carriers, respectively, which are even comparable to that of 3D counterparts. Furthermore, (PA)₂(MA)₂Zn₃I₁₀ is predicted to have the highest power conversion efficiency of 23.36% based on an empirical energy loss (0.5 eV), which is quite close to the Shockley–Queisser limit, thereby featuring it as a suitable absorber for photovoltaic applications. These findings shed light on new strategies for designing and developing lead-free 2DRP metal halides targeted at future applications in photovoltaic solar cell devices.     

Origin of the temperature stability of dielectric constant in CaCu3Ti4O12

The temperature and dc bias stability of the dielectric constant and loss tangent of CaCu₃Ti₄O₁₂ samples sintered under different oxygen atmospheres are discussed. The results suggest that the metal-oxygen vacancy related defects not only provide the charge carriers for the conduction (defect doping) but also contribute to the huge permittivity in the way of defect dipoles repositioning under charge carrier hopping. The charge localization in a specific copper-oxygen vacancy defect complex is the reason of the huge and stable permittivity and low dielectric loss in the middle temperature range, 90 K-200 K (20 Hz), while the implementation of the large barrier layer height needs a contribution by the titanium oxygen vacancy related trap charges in the grain boundaries, which also lead to a second permittivity stable range in a higher temperature range 200 K–300 K.     

Lewis acid-oxygen vacancy interfacial synergistic catalysis over SO42−/Ce0.84Zr0.16O2–WO3–ZrO2 for N,N-diethylation of aniline with ethanol

Herein, a new mechanism involving Lewis acid-oxygen vacancy interfacial synergistic catalysis for aniline N,N-diethylation with ethanol was proposed, and the SO₄²⁻/Ce_0.84Zr_0.16O₂–WO₃–ZrO₂ catalyst (SCWZ) with both Lewis acid sites and oxygen vacancies was synthesized by the hydrothermal method, which shows better catalytic activity than the reported solid acidic catalysts. Besides, the SO₄²⁻/ZrO₂ (SZ) and SO₄²⁻/WO₃–ZrO₂ (SWZ) catalysts were also prepared and compared with SCWZ to investigate the synergistic effect of each component. The SO₄²⁻ and WO₃ mainly generate Lewis acid by bonding with ZrO₂, which is beneficial for the fracture of the N–H bond in aniline. The Ce_0.84Zr_0.16O₂ solid solution mainly plays a vital role in generating the oxygen vacancies as the interface active species, which can participate in stripping –OH from ethanol, then the carbocation will also be released, which only needs 1.3805 kcal/mol energy, calculated by density functional theory (DFT), to be input. In comparison, the traditional reaction mechanism needs the Brønsted acidic sites to promote the protonation of ethanol, then dehydration and subsequent formation of carbocation followed, and 108.6846 kcal/mol energy needs to be input, which is far higher than that of the new mechanism. The apparent activation energy (E_a) over SCWZ was measured by experiment to be 34.09 kJ/mol, which is much lower than that of SWZ (47.10 kJ/mol) and SZ (54.37 kJ/mol), illustrating comparatively preferable kinetics for SCWZ than that of SWZ and SZ. Besides, the conversion of aniline and selectivity to N,N-diethylaniline over SCWZ reach almost 100% and 73%, respectively. The SCWZ can be renewed for 4 times without rapid deactivation, and the longevity of SCWZ is longer than that of SWZ and SZ, as the loaded SO₄²⁻ and tetragonal ZrO₂ are stabilized by Ce_0.84Zr_0.16O₂ and WO₃, respectively.     

硅烷偶联剂Si747在全钢载重子午线轮胎胎面胶中的应用

研究硅烷偶联剂Si747在全钢载重子午线轮胎胎面胶中的应用。结果表明:与添加硅烷偶联剂Si69的胶料相比,添加硅烷偶联剂Si747胶料的焦烧时间延长,硫化时间缩短,硫化胶的硬度和定伸应力减小,拉断伸长率增大,其他性能相当;随着硅烷偶联剂Si747用量的增大,硫化胶的耐磨性能总体提高;当硅烷偶联剂Si747用量为2份、硫黄用量为1.2份时,胶料的综合性能最好,成品轮胎的耐久性能提高。     

江苏广电城的预应力节点深化设计和施工

预应力节点深化设计是联系预应力设计和预应力施工的重要纽带,是保证预应力结构施工质量的关键,本文就江苏广电城的工程实例介绍了预应力节点深化设计和施工,为类似工程提供成功的经验。     

钕系顺丁橡胶在绿色轮胎胎面胶中的应用

研究钕系顺丁橡胶(Nd BR)在绿色轮胎胎面胶中的应用。结果表明:与未采用Nd BR的胎面胶相比,采用20份Nd BR的胎面胶门尼粘度较大,门尼焦烧时间较短;强伸性能相当或略差,耐热老化性能和耐磨性能提高,滚动阻力和生热降低。Nd BR有利于提高胎面胶耐磨性能及降低滚动阻力和生热,可作为绿色轮胎用原材料。