Research on the effects of surface modification of ceramic powder on cure performance during digital light processing (DLP)

Digital light processing (DLP) is one of the most important additive manufacture technologies to fabricate ceramic parts with complex geometries. Compared with pure photosensitive resin, the cure performance of ceramic suspensions is obviously different due to the optical property change after the addition of ceramic powders. In this paper, a unique oxidation process was used to modify the optical properties of nitride powders including AlN and Si₃N₄. The properties of oxidized ceramics were investigated and the cure performance of ceramic suspensions was then characterized. The effect of oxidation time on cure performance was evaluated. The results showed that for AlN, oxidation process leads to the smaller cure depth and smaller excess cure width as compared with non-oxidized AlN and for Si₃N₄, oxidation process leads to the larger cure depth and larger excess cure width as compared with non-oxidized Si₃N₄, indicating that both refractive index and light absorbance of ceramic powders have obvious effects on cure behaviors. Additionally, the cure behavior of oxidized ceramic suspension in this study shows that the relationship of cure depth vs. incident energy agrees well with Beer- Lambert model, but the excess cure width vs. incident energy is not consistent with quasi Beer-Lambert model due to the nature of digital micromirror device (DMD).     

调节剂对烷基水杨醛肟萃取铜铁的影响

烷基水杨醛肟虽然是一种高选择性的铜萃取剂，但单独使用时，萃取相易出现沉淀；反萃时，再生有机相出现乳化物，而且两相分离时间较长．将月桂醇、仲辛醇、壬基酚三种调节剂分别加入到萃取剂中，研究其对烷基水杨醛肟萃取及反萃行为的影响．结果表明，三种调节剂均可以解决上述问题，只是使萃取能力略有降低；壬基酚加入到烷基水杨醛肟中有助于提高铜铁分离系数，可达647．     

Differences in electrochemical corrosion behaviours between selective laser melted and wrought Ti6Al4V alloys in acid fluoride-containing artificial saliva

Journal of Applied Electrochemistry - In this work, the electrochemical corrosion behaviours of selective laser melted (SLMed) and wrought Ti6Al4V alloys in acid fluoride-containing artificial...     

高铬铸铁表面缺陷焊补技术

采用手工电弧补焊技术，对高铬铸铁小型磨辊类铸件缺肉缺陷进行修补补焊。选择与铸件同质的高铬铸铁焊条DJ052／D656，焊条直径为4mm．焊接电流为150～160A。焊补后的铸件经表面无损探伤检测无裂纹存在，其宏观硬度与基体材料相当，微观组织显示熔合面为较好的冶金结合。     

离子束增强沉积Si─N膜

用离子束增强沉积方法制备了ＳｉＮ薄膜，其中Ｓｉ由一束Ａｒ离子从Ｓｉ靶上溅射下来，在溅射沉积的同时，以一束Ｎ离子轰击正在沉积的膜层，于是获得了ＳｉＮ膜。采用卢瑟福背散射、红外光谱和透射电镜对膜层的成分和结构进行了分析，结果表明：膜面平整，膜层为非晶或微晶结构，由Ｓｉ和βＳｉ３Ｎ４组成     

中频磁控溅射沉积梯度过渡Cr/CrN/CrNC/CrC膜的附着性能

采用中频磁控溅射结合无灯丝离子源技术沉积梯度Cr/CrN/CrNC/CrC膜层,设计两组正交实验对膜层中界面Cr层及梯度层沉积的工艺参数对附着性能的影响进行研究。利用扫描电镜（SEM）、电子能谱（EDS）对其表面形貌及梯度成分进行表征;用划痕仪、显微硬度计及洛氏硬度计测评其附着性能,并对比两者测评的有效性。所得最优工艺参数为：梯度层沉积偏压100 V,中频功率6.5 kW,真空度0.6 Pa;Cr层的沉积时间、离子源电流及中频功率分别为2 min、4 A和6.5 kW。高中频功率及离子辅助沉积Cr层能有效提高膜层附着力。     

不同喷涂工艺下NiCoCrAlYTa涂层的显微结构和性能

为探索不同喷涂工艺对NiCoCrAlYTa涂层的显微结构和性能的影响规律,确定最优工艺,采用大气等离子、低压等离子、常规超音速火焰和低温超音速火焰4种工艺在镍基单晶高温合金表面制备了NiCoCrAlYTa涂层。采用X射线衍射(XRD)、扫描电镜(SEM)和显微硬度计等分析手段对喷涂态涂层的相组成、显微结构和显微硬度等进行了表征。结果表明,不同喷涂工艺下涂层的相组成均为γ′-Ni_3Al、β-NiAl和γ-Ni固溶体。低压等离子和超音速火焰喷涂的涂层致密且孔隙率低,其中超音速火焰喷涂的涂层孔隙率低于1%。低压等离子和低温超音速火焰喷涂的涂层氧含量很低,控制在0.3%~0.6%的范围。综合来说,低温超音速火焰喷涂工艺制备的涂层结构致密,孔隙率和氧含量很低。该工艺是沉积NiCoCrAlYTa涂层的首选。     

亚热带地区校园建筑空调系统节能技术的应用

在分析校园建筑功能和使用规律以及校园建筑空调系统的性能特点的基础上,以南方某高校新校区校园建筑空调系统为研究案例,研究亚热带地区校园建筑空凋系统中的节能环保技术与方法.结果表明:针对校园建筑的用途和结构规模不同,采用不同的空调机组可有效节能.针对校园建筑使用的时效性特点,采用变频技术合理调节新风量、冷冻水流量或冷凝水流量,可有效降低空调系统耗电量.对于校园建筑中有可能回收的热量都可以通过相关辅助设备进行回收,以达到热量再利用的目的.     

Microstructure and sliding wear behaviour of Tribaloy T-800 coatings deposited by laser cladding

This work has focused on the obtainment of Tribaloy T-800 coatings by laser cladding on plane 18/8 stainless steel specimens (AISI 304). The appropriate selection of cladding parameters allowed defect-free coatings to be obtained with minimal dilution. In order to evaluate their microstructure, cross-sections of the coatings were examined by optical microscopy and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS). The elemental composition of the coatings was determined using an optical emission spectrometer with an excitation source (GDOES) and phase analysis was performed by X-ray diffraction (XRD). Several zones can be distinguished in the microstructure of the clad layer: a planar crystallization region at the interface with the substrate, followed by cellular and dendrite crystallization from the interface to the surface of the laser track and an overlap zone between tracks which is characterised by the coarsening of the structure and the formation of a lamellar eutectic phase. The mechanical properties were evaluated by hardness measurements and sliding wear tests (ball-on-disk and block-on-ring configurations) at room temperature and without lubrication. It was observed the great hardness (close to 850 HV_0.3) achieved for the Tribaloy 800 laser coatings, which presented a wear coefficient (k) between one and two orders of magnitude lower than the substrate. The analysis of the clad worn surfaces showed that there was a transition from an adhesive-oxidational mechanism to a more severe plastic deformation and crack formation wear process with increasing the applied load.     

不同磁控溅射工艺对纳米晶TiN薄膜微观结构与力学性能的影响

对比研究了直流磁控溅射（dcMS）、高功率脉冲磁控溅射（HPPMS）和调制脉冲磁控溅射（MPPMS）所沉积纳米晶TiN薄膜的组织结构与力学性能。结果表明,因dcMS溅射粒子离化率与动能均较低,薄膜表现为存在少量空洞的柱状晶结构,薄膜力学性能差、沉积速率为51 nm/min。HPPMS因具有较高的瞬时离化率和较低的占空比,薄膜结构致密而光滑,性能得到了显著改善,但平均沉积速率较低,仅为25 nm/min。通过MPPMS技术可大范围调节峰值靶功率和占空比,从而得到较高的离化率和平均沉积速率,薄膜结构致密光滑、力学性能优异,沉积速率达45 nm/min,接近dcMS。