Fabrication of 3D structures via direct ink writing of kaolin/graphene oxide composite suspensions at ambient temperature

Kaolin/graphene oxide composite has been widely utilized in aero-space and architectural engineering applications due to its excellent mechanical property. Direct ink writing (DIW) is a freeform rapid prototyping technology that could be used to accurately fabricate the resulting size with complex shapes. In this study, we reported the DIW of kaolin/graphene oxide (GO) composite suspensions (KGCS) to assemble 3D structures at ambient temperature for the first time. The effects of GO on the chemical constitution and microstructure of kaolin suspensions were investigated. Rheology was characterized to ensure printability of KGCS. The addition of GO in kaolin suspensions quickened a flocculation structure, which dramatically changed their rheology properties. The DIW of 3D structures from the optimal KGCS sample maintained their initial shape without spreading. The flexural and compressive strengths of the dried optimal KGCS samples were obviously enhanced due to the improvement and reduction of the micro-defects compared from cured kaolin matrix.     

Polyimide/nano-TiO2 hybrid films having benzoxazole pendent groups: In situ sol–gel preparation and evaluation of properties

Polyimide/titania (PI/TiO₂) nanocomposite films have been successfully fabricated through the in situ formation of TiO₂ within a PI matrix via sol–gel method. Poly(amic acid) (PAA), which is the precursor of PI, was successfully synthesized by mixing pyromellitic dianhydride (PMDA), with equimolar amount of a diamine monomer having a pendent benzoxazole unit and two flexible ether linkages in N,N-dimethylformamide (DMF) solvent. Tetraethyl orthotitanate [Ti(OEt)₄] and acetylacetone were then added to the resulted PAA. After imidization at high temperature, PI/TiO₂ hybrid films were formed. The structure and morphology of the hybrid nanocomposites with different titania contents (0 wt%, 5 wt%, 10 wt%, and 15 wt%) were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and transmission electron microscopy. The results indicate that the TiO₂ nanoparticles were homogeneously dispersed in the hybrid films. The thermogravimetric analysis of nanocomposites confirms the improvement in the thermal stability with the increase in the percentage of titania nanoparticle. Transmission electron microscopy showed that the nanoparticles with an average diameter of 25–40 nm were dispersed in the polymer matrix.     

Insights into biological delignification of rice straw by Trametes hirsuta and Myrothecium roridum and comparison of saccharification yields with dilute acid pretreatment

Rice straw is the most abundant agricultural residue on a global scale and is widely available as feedstock for cellulosic fuel production. However, it is highly recalcitrant to biochemical deconstruction and also generates inhibitors that affect enzymatic saccharification. Rice straw from eastern Arkansas was subjected to dilute acid pretreatment (160 °C, 48 min and 1.0% sulfuric acid) and solid-state fermentation with two lignocellulolytic fungi, Trametes hirsuta and Myrothecium roridum, and their saccharification efficacies were compared. T. hirsuta and M. roridum were tested separately; pretreatment of rice straw with either strain for seven days resulted in 19 and 70% enrichment of its holocellulose content, respectively. However, liquid chromatography analysis of the alkali extracts showed significant differences in cell wall degradation by T. hirsuta and M. roridum. T. hirsuta removed 15% more phenolic compounds and 38% more glucan than M. roridum, while M. roridum removed 77% more xylan than T. hirsuta. Fungal and dilute acid pretreated biomass was then hydrolyzed using Accellerase^® 1500, a saccharification cocktail. Saccharification efficiency of M. roridum was 37% higher than that of dilute acid pretreatment of rice straw, requiring 8% lower enzyme loading and 50% shorter enzymatic hydrolysis duration. Alkali extraction of fungal pretreated biomass also yielded 10–15 g kg⁻¹ of acid precipitable polymeric lignin (APPL), which is a valuable co-product for biorefineries. In comparison to dilute acid pretreatment, fungal pretreatment could be a cost-effective alternative for the degradation of recalcitrant biomass, such as rice straw.     

Synthesis and properties of cinnamic acid series organic UV ray absorbents–interleaved layered double hydroxides

Organic ultraviolet (UV) ray absorbents, cinnamic acid (CA) and p-methoxycinnamic acid (PMOCA) were intercalated into Zn₂Al layered double hydroxides (Zn₂Al-LDHs) by co-precipitation reaction. The organic–inorganic nanocomposites, Zn₂Al-LDH/CA and Zn₂Al-LDH/PMOCA were obtained. The samples showed excellent UV ray absorption ability and their catalytic activity for the air oxidation of castor oil greatly decreased when the organic UV ray absorbents were intercalated in the layers of the Zn₂Al-LDHs. The studies suggested that Zn₂Al-LDH/organic UV absorbent nanocomposites might be used as safe sunscreen materials.     

Forest park landscape pattern system based on FPGA and GIS system

Perceptual scenes and scene swing surveys are the ideas for reminding local and wooded area park executives and scene placement. The maximum precise analysis of panorama visualization, forest park landscapes, planning of essential scenic spots, and visualization and safety of Geographic Information Systems (GIS) cost tools is primarily based on management and historical data. Visual impacts and cultural, historical past adjustments to are expecting visual and natural landscapes. By deciding on points from a panorama attitude, intervention calls for vital signs and symptoms of safety. Among them, studies are being carried out in many towns around the arena. Geographic Information System (GIS) depends simply on noticeable assessment and is remembered for the social legacy plan. The Gate Array (FPGA) and Geographic Information System (GIS) are analyzed based on the panorama in every place within the painting's framework. In these activities, landscape planning is proposed thru the development of scientific Piedmont. Turin is conducting a few research. From a global attitude, the version suggests that these packages reduce the capability use of the era.     

Existence and Exponential Stability of Multiple Periodic Solutions for a Multidirectional Associative Memory Neural Network

The paper proposes several mathematical models of the multidirectional associative memory (MAM) neural network by analyzing its structure. A model of MAM with distributed delays is studied. Under some new assumptions on activation functions, 2^n₀[m/2]{2^{n_0[m/2]}} invariant subsets of MAM are constructed. Then the existence and the exponential stability of 2^n₀[m/2]{2^{n_0[m/2]}} periodic solutions located on invariant subsets are obtained by constructing a suitable Liapunov function and a Poincaré mapping. An estimating method of the exponential convergence rate is given. The obtained results are new to MAM neural networks. An example is given to illustrate the effectiveness of the results.     

基于ARM和嵌入式Linux疲劳检测系统研究

基于视觉的疲劳驾驶检测技术是疲劳检测领域的前沿技术。根据基于视觉的车载驾驶员疲劳检测系统实时、小型化、非接触、可扩展等技术要求,以ARM开发板和嵌入式Linux操作系统为平台,设计了一套基于PERCLOS疲劳驾驶检测方法,与传统的基于PC机的疲劳检测系统相比,具有更好的稳定性、可行性以及更优越的可扩充性。