Mechanical Properties of Single-Layer Diamond Reinforced Poly(vinyl alcohol) Nanocomposites through Atomistic Simulation

Low-dimensional carbon nanostructures are ideal nanofillers to reinforce the mechanical performance of polymer nanocomposites due to their excellent mechanical properties. Through molecular dynamics simulations, the mechanical performance of poly(vinyl alchohol) (PVA) nanocomposites reinforced with a single-layer diamond – diamane is investigated. It is found the PVA/diamane exhibits similar interfacial strengths and pull-out characteristics with the PVA/bilayer-graphene counterpart. Specifically, when the nanofiller is fully embedded in the nanocomposite, it is unable to deform simultaneously with the PVA matrix due to the weak interfacial load transfer efficiency, thus the enhancement effect is not significant. In comparison, diamane can effectively promote the tensile properties of the nanocomposite when it has a laminated structure as it deforms simultaneously with the matrix. With this configuration, the interlayer sp³ bonds endows diamane with a much higher resistance under compression and shear tests, thus the nanocomposite can reach very high compressive and shear stress. Overall, enhancement on the mechanical interlocking at the interface as triggered by surface functionalization is only effective for the fully embedded nanofiller. This work provides a fundamental understanding of the mechanical properties of PVA nanocomposites reinforced by diamane, which can shed lights on the design and preparation of next generation high-performance nanocomposites.     

改进HSR-FCN的服装图像识别分类算法研究

目前网络上的服装图像数量增长迅猛，对于大量服装图像实现智能分类的需求日益增加。将基于区域的全卷积网络（Region-Based Fully Convolutional Networks，R-FCN）引入到服装图像识别中，针对服装图像分类中网络训练时间长、形变服装图像识别率低的问题，提出一种新颖的改进框架HSR-FCN。新框架将R-FCN中的区域建议网络和HyperNet网络相融合，改变图片特征学习方式，使得HSR-FCN可以在更短的训练时间内达到更高的准确率。在模型中引入了空间转换网络，对输入服装图像和特征图进行了空间变换及对齐，加强了对多角度服装和形变服装的特征学习。实验结果表明，改进后的HSR-FCN模型有效地加强了对形变服装图像的学习，且在训练时间更短的情况下，比原来的网络模型R-FCN平均准确率提高了大约3个百分点，达到96.69%。     

Effect of steel slag on 3D concrete printing of geopolymer with quaternary binders

A new type of 3D-printable ‘one-part’ geopolymer was synthesized with fly ash (FA), granulated blast furnace slag (GBFS), steel slag (SS) and flue gas desulfurization gypsum (FGD). The effects of SS content (0–40%) on the rheological properties, 3D-printability, mechanical anisotropy and reaction kinetics of geopolymer were investigated. The yield stress and plastic viscosity monotonically decreased with the increasing SS content. Contrarily, the geopolymer with 10% of SS presented better extrudability, buildability and mechanical strength than those with 0, 20%, 30% and 40% of SS. This was mainly attributed to the conflicting influence of SS on geopolymerization, of which the OH^? produced by hydration of SS raised the alkalinity of the reaction system and accelerated the dissolution of SiO₄^4? and AlO₄^5?, while the low reactivity prohibited the following polymerization process. Furthermore, the 3D-printed geopolymer presented more compact microstructure and less mechanical anisotropy thanks to the crosslinking of morphologically complementary products, including N(C)-A-S-H, C–S–H, AFt and CH, formed via synergistic reaction of FA-GBFS-SS-FGD system.     

气瓶内部淬火过程的流动换热特性

 大直径厚壁气瓶内部淬火时的流动换热过程极其复杂，受到多种因素的影响，而研究气瓶内部压强和温度的变化规律对改善流动换热效果、提高产品组织性能具有重要的理论指导意义。以914 mm厚壁气瓶和瓶内流体为研究对象，建立了二维等效流 固耦合模型；采用多喷嘴系统对气瓶内外进行喷水淬火，研究了气瓶总长、喷水流速及淬火时间对瓶内压强及内壁温度的影响，通过间歇淬火试验验证了数学模型的正确性。结果发现，气瓶长度对瓶内压强和瓶壁温度的影响显著，喷水流速次之，当喷水流速大于8 m/s后，水量对瓶壁的冷却效果大大降低；气瓶内壁长度方向的温度梯度分别随气瓶总长的增加和淬火时间的延长而减小，但基本不受喷水量的影响。     

Reply to the discussion by Q. Zeng and S.L. Xu of the paper “Numerical simulation of moisture transport in concrete based on a pore size distribution model”

This paper presents a reply to the discussion of the paper “Numerical simulation of moisture transport in concrete based on a pore size distribution model” by Q. Zeng and S.L. Xu.     

不同润湿表面液体沸腾的分子动力学模拟

采用分子动力学方法研究纳米尺度下液氩在过热基板上的沸腾过程。通过调节固液间相互作用的方式改变壁面润湿性，模拟并分析了壁面润湿性对沸腾过程中能量传递和液体运动情况的影响。结果表明：不同润湿性表面均会发生固液分离的现象，但是固体表面附近吸附的氩原子数密度随润湿性增强而增大；润湿性较强时，液体的能量上升快，热通量高，液体内部温度梯度大，发生固液分离时间早，系统中氩的温度和能量低，上升过程中液氩密度、厚度变化小；润湿性较弱时，液体的能量上升慢，热通量小，液体内部温度梯度小，发生固液分离时间延后，系统中氩的温度、能量更高，上升过程中液氩密度、厚度变化较大。下部气体压力整体上大于上部气体压力，发生固液分离时润湿性越强的表面上液体上下压差越大，首次上升过程能达到的高度越高，所需时间越短。     

Effects of sintering in a high magnetic field on properties of vitrified bond and vitrified CBN composites

Vitrified bond CBN grinding wheels are being widely used due to their superior performance. Also, advantages of vitrified grinding wheels are high elastic modulus, stable chemical property, and low thermal expansion coefficient. Brittleness and low strength are key factors restricting the development of vitrified bond CBN grinding wheels. In this paper, the sintering in a high magnetic field was innovatively introduced into the manufacturing of vitrified bond CBN grinding wheels, and the effects of sintering in a high magnetic field on properties on vitrified bond and vitrified CBN composites were systematically investigated. Vitrified bond was characterized using three-point bending, scanning electron microscopy, X-ray diffraction. It was observed that microstructure of vitrified bond could be changed, grain orientation could be controlled and average grain size could be decreased in a high magnetic field, while vitrified bond strength could be simultaneously improved. High quality vitrified bond could be obtained by appropriately adjusting the strength and direction of high magnetic field. Results demonstrated that vitrified bond properties were improved when the magnetic field strength was 6?T. In order to highlight the high magnetic field effect on the vitrified CBN composites, the ordinary CBN abrasives and nickel plated CBN abrasives were used respectively. Microstructures, bending strengths of vitrified CBN composites were compared in different high magnetic fields. When the magnetic field strength was appropriate (less than 6?T), the binding characteristic of vitrified bond CBN composites with nickel plated CBN abrasives was greatly improved. The highest bending strength value of vitrified CBN composites was 79.5?MPa in 6?T high magnetic field.     

8位模型计算机自动测试系统的设计与实现

描述基于MCS-51的自动测试系统的设计,实现对8位模型计算机的自动测试过程。对8位模型计算机的测试流程进行详细分析,绘出模型机的存储器模块、运算器模块和控制器模块的测试流程图,编写各模块的C语言测试程序。通过大量实验。完成时8位模型计算机的自动测试,整机测试执行时间不超过10秒钟。     

基于SOPC的网络视频监控系统的设计

提出一种以Nios Ⅱ软核处理器为核心,利用SOPC技术构建硬件平台,采用H.263协议压缩视频数据的网络视频监控系统设计方案;详细分析了系统的功能需求,确定了系统设计的总体方案;按照模块化的思想,设计了各个功能模块,并给出了网络芯片DM9000A电路的具体实现,利用μClinux中的TCP/IP协议栈进行数据通信,分析H.263视频编码协议基本原理,提出在硬件上实现H.263协议的设计方法;实验结果显示系统的网络视频传输速率达到25～30fps,满足实时性的要求.本设计方法灵活、成本较低、易扩展,具有一定的实用价值.     

HZSM5分子筛膜复合二氧化锡对甲烷的气敏性能研究

采用液相氧化法制备二氧化锡纳米颗粒,并利用浸渍法制备Pd负载二氧化锡纳米材料,通过丝网印刷得到气敏传感膜并在其表面印刷分子筛层。基于动态气敏测试系统探究传感器对甲烷气体的灵敏度及其在CO和乙醇干扰气体下的选择性。研究结果表明,在Pd-SnO₂敏感层表面印刷Pd-HZSM5层后,传感器对甲烷的响应能力显著提高,并且在体积分数为5×10^-4的CO存在时,对甲烷的选择性也得到明显的提升。同样,在质量分数为2×10^-5乙醇的存在下,传感器对甲烷的响应也没有受到干扰。通过对分子筛进行表征和催化分析,发现Pd-HZSM5对CO的催化效率可达100%,使得CO在扩散过程中被催化氧化,这可能是印刷Pd-HZSM5分子筛膜从而提高传感器选择性的主要原因。同时研究还表明,在敏感层表面印刷分子筛层并不会影响传感器的响应和恢复速率。