Fabrication of 3D structures via direct ink writing of kaolin/graphene oxide composite suspensions at ambient temperature

Kaolin/graphene oxide composite has been widely utilized in aero-space and architectural engineering applications due to its excellent mechanical property. Direct ink writing (DIW) is a freeform rapid prototyping technology that could be used to accurately fabricate the resulting size with complex shapes. In this study, we reported the DIW of kaolin/graphene oxide (GO) composite suspensions (KGCS) to assemble 3D structures at ambient temperature for the first time. The effects of GO on the chemical constitution and microstructure of kaolin suspensions were investigated. Rheology was characterized to ensure printability of KGCS. The addition of GO in kaolin suspensions quickened a flocculation structure, which dramatically changed their rheology properties. The DIW of 3D structures from the optimal KGCS sample maintained their initial shape without spreading. The flexural and compressive strengths of the dried optimal KGCS samples were obviously enhanced due to the improvement and reduction of the micro-defects compared from cured kaolin matrix.     

Nickel foam-supported Fe,Ni-Polyporphyrin microparticles: Efficient bifunctional catalysts for overall water splitting in alkaline media

Developing highly active, stable and sustainable electrocatalysts for overall water splitting is of great importance to generate renewable H₂ for fuel cells. Herein, we report the synthesis of electrocatalytically active, nickel foam-supported, spherical core-shell Fe-poly(tetraphenylporphyrin)/Ni-poly(tetraphenylporphyrin) microparticles (FeTPP@NiTPP/NF). We also show that FeTPP@NiTPP/NF exhibits efficient bifunctional electrocatalytic properties toward both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). Electrochemical tests in KOH solution (1 M) reveal that FeTPP@NiTPP/NF electrocatalyzes the OER with 100 mA cm⁻² at an overpotential of 302 mV and the HER with 10 mA cm⁻² at an overpotential of 170 mV. Notably also, its catalytic performance for OER is better than that of RuO₂, the benchmark OER catalyst. Although its catalytic activity for HER is slightly lower than that of Pt/C (the benchmark HER electrocatalyst), it shows greater stability than the latter during the reaction. The material also exhibits electrocatalytic activity for overall water splitting reaction at a current density of 10 mA cm⁻² with a cell voltage of 1.58 V, along with a good recovery property. Additionally, the work demonstrates a new synthetic strategy to an efficient, noble metal-free-coordinated covalent organic framework (COF)-based, bifunctional electrocatalyst for water splitting.     

11B and 15N solid state NMR investigation of a boron nitride preceramic polymer prepared by ammonolysis of borazine

A poly(aminoborazine), precursor for hexagonal boron nitride (h-BN) obtained by reaction of borazine B₃N₃H₆ with ammonia, and its pyrolysis derivatives have been extensively characterised by ¹⁵N and ¹¹B MAS NMR. The various B and N sites have been identified according to their first neighbouring atoms, as well as to the second ones in the case of ¹⁵N, and have also been quantified. This study demonstrates that a suitable choice of NMR techniques together with the use of isotopic enrichment can lead to a large improvement in spectral resolution, which allows a better understanding of such complex BN preceramic polymer structures and permits to follow the polymer-to-ceramic transformation.     

CALCULATION ON TWO-PHASE FLOW TRANSIENTS AND THEIR EXPERIMENTAL RESEARCH

From basic equations of gas-liquid, solid-liquid, solid-gas two-phase flow, the calculating method on flow transients of two-phase flow is developed by means of characteristic method. As one example, a gas-liquid flow transient is calculated and it agrees well with the experimental result. It is shown that the method is satisfactory for engineering demand.     

Stability of foams and froths in the presence of ionic and non-ionic surfactants

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analyzed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was found also that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K₂₃₂) estimated from the film thinning experiments were used to predict the disjoining pressure isotherms using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (H_e) of the foam films stabilized by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, H_e increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is maximum in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.     

Building a research network to better understand climate governance in the Great Lakes

Climate-driven disturbances threaten the sustainability of coastal communities in the Great Lakes Basin. Because such disturbances are unpredictable, their magnitude, number and intensity are changing, and they occur at varying temporal and spatial scales. Consequently, communities struggle to respond in effective ways. The expected intensification of climate-driven disturbances will require that community capacity and governance structures match the spatial and temporal scales of these disturbances, as the most sustainable social and economic systems will be those that can respond at similar frequencies to key natural system drivers. The Climate Governance Variability in the Great Lakes Research Coordination Network (CGVG-RCN) was recently established to address questions about the relationship between climate-driven disturbances and community response. The objective of this short communication is to introduce the ideas behind the CGVG-RCN, outline its goals, and facilitate engagements and collaboration with social and natural scientists interested in social-ecological systems in the Great Lakes Basin.     

Importance of nonindigenous harpacticoids (Crustacea: Copepoda) decrease with depth in Lake Ontario

Harpacticoid copepods can be a substantial component of the meiobenthic community in lakes and serve an ecological role as detritivores. Here we present the first species-level lake-wide quantitative assessment of the harpacticoid assemblage of Lake Ontario with emphasis on the status of nonindigenous species. Additionally, we provide COI-5P sequences of harpacticoid taxa through Barcode of Life Data System (BOLD). Harpacticoids were collected at depths from 0.1 to 184 m and from a range of substrates from August to September 2018 as part of the Cooperative Science and Monitoring Initiative (CSMI) offshore benthic survey. Twenty-six meiobenthic samples were analyzed using microscopy for community composition analysis of harpacticoids. We found thirteen indigenous and three nonindigenous species of harpacticoid, with the introduced species dominating at shallow depths. The community transitioned from nonindigenous to indigenous species dominance as depth increased. Nonindigenous species accounted for 79% of the community (by abundance) at depths <20 m, 55% from 20 to 40 m, and only 24% at depths >40 m. The nonindigenous species encountered included the first detections of Schizopera borutzkyi (Monchenko, 1967) and Heteropsyllus nunni (Coull, 1975) from Lake Ontario. S. borutzkyi was the most abundant harpacticoid species in the lake, approaching a maximum density of 50,000/m² and a lake-wide average density of 7,900/m². Numerically important indigenous species included Bryocamptus nivalis (Willey, 1925), Canthocamptus robertcokeri (Wilson, 1958), Canthocamptus staphylinoides (Pearse, 1905), and Moraria cristata (Chappuis, 1929). The prevalence of nonindigenous harpacticoids in the meiobenthos of Lake Ontario suggests further investigations of Great Lakes meiofauna communities are warranted.     

A song of ice and vessels: Seasonal trends in the soundscape of the western arm of Lake Superior

The soundscapes of marine systems have been studied for decades to determine spatial and temporal patterns of biological, geological, and anthropogenic activity. However, comparatively little is known about freshwater soundscapes. Lake Superior is the world’s largest freshwater lake by surface area and home to a variety of aquatic animals. The Twin Ports of Duluth and Superior, located in the western arm of Lake Superior, are annually closed because of ice cover, providing a unique opportunity to explore sound levels in the absence of vessel traffic. Passive acoustic monitoring was conducted over 15 months between November 2018 and March 2020 to investigate seasonal patterns. Sound pressure levels were significantly lower (8 dB) at low frequencies (<100 Hz) during the winter and spring months (when ice cover increased). Quieter ambient sound pressure levels may provide an acoustic refuge to soniferous animals, especially those that vocalise during winter spawning. During the ice-free months, commercial shipping introduces a near continuous source of sound, increasing sound levels by up to 25 dB (at frequencies < 1,000 Hz). Climate change is expected to further reduce ice cover and thickness allowing the shipping season into the Twin Ports to be extended, thus warranting concern about the effect of noise from vessel activity on aquatic life. This study provides a baseline of the soundscape in the western arm of Lake Superior, against which scientists and environmental managers can assess future changes to this important habitat.