PTFE/GF(glass fiber) composites are widely applied in high-frequency printed circuit board (PCB) substrate materials due to the excellent dielectric properties of PTFE and the low thermal expansion coefficient of GF. However, the poor interface compatibility between PTFE and GF affects the performance of the composite substrates. In this study, tetraethyl orthosilicate (TEOS) was used as the silicon source, and polydimethylsiloxane (PDMS) was the organic precursor to modify the surface of GF through the sol–gel method to promote the interface compatibility of GF and PTFE. The modified GF noted T-GF was filled in PTFE to prepare PTFE/T-GF composites. SEM, FTIR, XPS, and contact angle confirmed that organic–inorganic hybrids were successfully loaded on GF's surface. Moreover, compared with PTFE/GF and the conventional coupling agent modified GF filled PTFE composites, the PTFE/T-GF exhibited improved dielectric constant (2.305), decreased dielectric loss (9.08E?4), higher bending strength (21.45 MPa) and bending modulus (522 MPa), better thermal conductivity (0.268 W/m*K) and lower CTE (70 ppm/°C), making it has promising application as the substrate materials for high frequency PCB.
The present investigation reports an eco-friendly biotechnology applying Paenibacilllus mucilaginosus (P.m), a silicate solubilizing bacteria, to activate pozzolanic activity of CFA. The results show SiO2 and Al2O3 dissolution rate of CFA treated by P.m and its Ca2+ absorption capacity in saturated Ca(OH)2 solutions are increased compared to raw CFA indicating that pozzolanic reactivity of CFA is improved by P.m. One reason is destruction of the anhydrite coating layer of CFA particles surface through P.m erosion. Another reason is promotion of SiO2 dissolution caused by deformation and destruction of Si-O-Si (Al) bonds by P.m. Carbonic anhydrase activity of P.m is one of the main factors involved in dissolution of SiO2, which also induces CaCO3 mineralization. The hardening characteristics and hydration products of CFA-15% lime system with different content of P.m further confirm the effects of P.m on pozzolanic activity of CFA. 40% P.m incorporation is conducive to promote CFA hydration, ettringite earlier formation and bio-mineralization, thereby improving the mechanical properties of hardened mortar. Incorporation of 40% P.m in cement blended with CFA results in that CFA content is increased by 5–20% and the 28d strength improved by 11.5–23.9 MPa. This is the first report of microbial activation of CFA pozzolanic activity. 相似文献
针对最大信息系数(maximal information coefficient, MIC)算法计算时间复杂度较高的问题,提出一种基于动态均分的最大信息系数(dynamic equpartition of maximal information coefficient, DE-MIC)改进算法,利用动态均分对两变量在网格中的散点图进行不断迭代寻优,通过对获得的互信息进行正则化得到最优的DE-MIC值,同时利用标准的可移植操作系统接口(portable operating system interface of UNIX, POSIX)对数据集进行多线程计算,使算法在大规模数据集上的计算效率更高。经过在多个数据集上与快速最大信息系数算法(rapid computation of the maximal information coefficient, RapidMIC)比较, DE-MIC算法在保持原有最大信息系数算法普适性和均匀性的前提下,计算速度更快且效率更佳。 相似文献