Spray coating process variable and property analysis of UV-curable polyurethane acrylate coating on polycarbonate substrate

A series of spray coating experiments were conducted on an UV-curable, polyurethane-modified, acrylate-based coating formulation with the aim to control defects, coating thickness, and thickness variation. Statistical approaches including design of experiment, residual examination, analysis of variance, and t-test were used in designing the experiments and analyzing data. Viscosity of formulation, atomizing pressure, liquid feeding pressure, distance between nozzle and substrate, and travel speed of substrate were the process variables studied. The ranges of process variables that gave defect-free coating were identified and used in the subsequent experiments to determine process variables and interactions that had significant contribution to the changes in coating thickness and thickness variation. All process variables studied were found to have contribution to the change in coating thickness, but they showed no significant contribution to the variation of coating thickness. No interaction displayed significant contribution. Confirmation tests performed on extra samples prepared with varying coating thicknesses indicated a good agreement with the experimental results. Additional samples were tested for total transmittance, transmission haze, adhesion, surface roughness, hardness, scratch hardness, abrasion resistance, and durability to attack of car wash chemicals. Spray coated samples showed slight improvement in the total transmittance over the uncoated samples, while maintaining the transmission haze and exhibiting rougher surfaces. Only samples with thin coatings were found to possess sufficient adhesion to the substrate. These thin coatings gave improved hardness, scratch hardness, and durability to car wash attack to the level comparable to commercial coated polycarbonate headlamp lenses, whilst giving better abrasion resistance.     

Influence of the ZrB2 content on the anti-oxidation ability of ZrB2-SiC coatings in aerobic environments with broad temperature range

ZrB₂-SiC coatings with different ZrB₂ contents were prepared by liquid phase sintering. The oxidation processes of coatings were explained according to TG results of ZrB₂-SiC coatings and powders tested from 298 K to 1773 K. Results show that, increasing ZrB₂ content made the weight of the samples changed from weight-loss of 10.04% to weight-gain of 0.14%, while the fastest weight-loss regions were narrowed, whose inflection points reduced from 1310℃ to 1050℃. Increasing ZrB₂ content made the relative oxygen permeability of the ZrB₂-SiC/SiC coatings reduced from 40%–60% to -10%-5%. Increasing ZrB₂ content enhanced high-temperature stability of coatings, making final weight of samples changed from weight-loss of 0.16% to weight-gain of 0.11% after oxidation at 1773 K for 200 h. The peeling and dispersion of Zr-oxides formed Zr-B-Si-O compound glass layer, presenting enhanced stability, dispersion strengthening and pinning effect of Zr-oxides, which were responsible for the excellent anti-oxidation protective effect of coatings in a broad temperature region.     

Electrochemical characteristics of heme proteins in hydroxyethylcellulose film

A stable film made from hydroxyethylcellulose (HEC) on pyrolytic graphite (PG) electrode was employed for incorporating hemoglobin (Hb), myoglobin (Mb) and horseradish peroxidase (HRP), and the electrochemical characteristics of the proteins were studied correspondingly. Experimental results revealed that HEC film could greatly accelerate electron transfer between the proteins and electrode, and the proteins showed a thin layer electrochemical behavior in the film. Moreover, all the proteins in the film exhibited good catalytic activity towards the reduction of hydrogen peroxide (H₂O₂) in the low H₂O₂ concentration range. In the high concentration range, H₂O₂ would exhibit toxicity effect on the proteins. The electrochemical properties and electrocatalytic abilities of the three heme proteins in HEC film have been compared, and the optimal conditions for H₂O₂ biosensor fabrication have been obtained.     

基于时间加权的重叠社区检测算法研究

随着网络结构的不断扩大和日益复杂, 重叠社区发现技术对挖掘复杂网络深层潜在结构具有重要意义. 本文提出一种基于时间加权的重叠社区检测算法. 该方法考虑了用户兴趣的时间因素, 构建带有时间加权链接的用户-用户图. 接着, 基于网络节点的影响力计算用户全局相似度, 在此基础上通过计算节点的中心度作为度量节点对社区结构影响力的重要性指标, 从而提出一种社区中心点的选取方法. 最后, 通过效用函数的迭代计算实现重叠社区检测. 利用人工网络和真实网络对提出的算法进行验证, 实验结果表明: 相对于传统的社区发现方法, 该算法在社区发现质量和计算效率方面都优于许多已有重叠社区发现算法.     

磷酸二苯酯催化的2-吲哚甲烷胺衍生物的合成

以磷酸二苯酯为催化剂,3-甲基吲哚类化合物与亚胺通过Friedel-Crafts加成反应一步合成了具有广泛药理活性的2-吲哚基甲烷胺类化合物,对反应条件进行优化。结果表明,当n(3-甲基吲哚类)∶n(亚胺)∶n(磷酸二苯酯)=1.0∶2.0∶0.1,其中,磷酸二苯酯0.0025 mmol,1 mL无水二氯甲烷作溶剂,室温下反应0.5 h时,即可得到高收率2-吲哚基甲烷胺类衍生物（85%~90%）。产物经 1HNMR、13CNMR 和 HRMS 进行了结构确定。     

舰船防护结构穿甲后爆炸的数值仿真分析

为了研究冲击爆炸作用下舰船防护结构的破坏情况,将该结构简化为多层板架结构,借助于有限元程序LS-DYNA中的ALE算法,同时考虑穿甲和爆炸的作用,对其在穿甲后爆炸荷载作用下的非线性动态响应过程进行仿真分析,描述了钢板的破口形状、破口半径及板上单元等效应力随时间变化的情况,并与舷外接触爆炸对结构的破坏情况进行比较.结果表明穿甲后爆炸能对舰体内部造成破坏,因此它是一种比较理想的反舰攻击方式.     

基于粒计算的多粒度数据分析方法综述

多粒度数据是一种特殊的、有用的数据类型,它通过对论域（研究对象的集合）采用不同的粒化方式使得数据能够在多个粒度空间中进行呈现,在此基础上可以开展数据的多层次知识发现研究。商空间理论、序贯三支决策、多粒度粗糙集、多尺度数据分析模型和多粒度形式概念分析是几种常见的、有效的多粒度数据分析方法,已受到人们的广泛关注。本文对基于粒计算的多粒度数据分析研究工作进行综述,给出每一类多粒度数据分析方法的理论框架、基本概念以及主要研究思想,并指出多粒度数据分析研究中存在的若干问题,为该领域的后续研究提供理论参考。     

An Integrated Modelling Approach for Flood Simulation in the Urbanized Qinhuai River Basin,China

Water Resources Management - The accurate simulation and prediction of flood response in urbanized basins remains a great challenge due to the spatial and temporal heterogeneities in land surface...