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1.
Theoretical investigation of solvent effects on the selective hydrogenation of furfural over Pt(111)
Jian Wang Cun-Qin Lv Jian-Hong Liu Rong-Rong Ren Gui-Chang Wang 《International Journal of Hydrogen Energy》2021,46(2):1592-1604
It was well known that solvent effect plays a very important role in the catalytic reaction. There are many theoretical studies on the solvent effect in homogeneous catalysis while there are few theoretical studies on the solvent effect in the heterogeneous catalytic reaction and there has been no work to investigate the solvent effect on furfural transformation in heterogeneous catalysis. In the present work, both the density functional calculations and the microkinetic analysis were performed to study the selective hydrogenation of furfural over Pt(111) in the presence of methanol as well as toluene and compared with that in the gas condition. The present results indicated that the methanol can enhance the adsorption strength of furfural and other oxygen-containing reaction species due to its relatively strong polarity properties and this can be a main reason for solvent-induced high activity and selectivity. Another reason is that reaction paths study showed that the presence of methanol solvent makes the dehydrogenation of furfural less thermochemical due to the fact that furfural is more stabilized than that of dehydrogenation species, and methanol also has an inhibition effect on the dehydrogenation of furfural in the kinetic aspect, and further energetic span theory proves highest activity and selectivity for hydrogenation in methanol solvent of vapor, methanol and toluene. Moreover, microkinetic model simulation demonstrated that the activity and selectivity of hydrogenation in methanol is both higher than that in vapor and toluene. The much higher activity in methanol is due to the stabilized adsorbed reactants in the surface, which leads to a higher surface coverage of furfural. It might be proposed based on the present work that a solvent with relatively strong polarity may be favorable for the high selective hydrogenation of furfural. 相似文献
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The morphology of the photoactive layer critically affects the performance of the bulk heterojunction polymer solar cells (PSCs). To control the morphology, we introduced a hydrophobic fluoropolymer polyvinylidene fluoride (PVDF) as nonvolatile additive into the P3HT:PCBM active layer. The effect of PVDF on the surface and the bulk morphology were investigated by atomic force microscope and transmission electron microscopy, respectively. Through the repulsive interactions between the hydrophilic PCBM and the hydrophobic PVDF, much more uniform phase separation with good P3HT crystallinity is formed within the active layer, resulting enhanced light harvesting and improved photovoltaic performance in conventional devices. The PCE of the conventional device can improve from 2.40% to 3.07% with PVDF additive. The PVDF distribution within the active layer was investigated by secondary ion mass spectroscopy, confirming a bottom distribution of PVDF. Therefore, inverted device structure was designed, and the PCE can improve from 2.81% to 3.45% with PVDF additive. Our findings suggest that PVDF is a promising nonvolatile processing additive for high performance polymer solar cells. 相似文献
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Aiming to environment protection, green solvents are crucial for commercialization of solution-processed optoelectronic devices. In this work, d-limonene, a natural product, was introduced as the non-aromatic and non-chlorinated solvent for processing of polymer light-emitting diodes (PLEDs) and organic field effect transistors (OFETs). It was found that d-limonene could be a good solvent for a blue-emitting polyfluorene-based random copolymer for PLEDs and an alternating copolymer FBT-Th4(1,4) with high hole mobility (μh) for OFETs. In comparisons to routine solvent-casted films of the two conjugated polymers, the resulting d-limonene-deposited films could show comparable film qualities, based on UV–vis absorption spectra and observations by atomic force microscopy (AFM). With d-limonene as the processing solvent, efficient blue PLEDs with CIE coordinates of (0.16, 0.16), maximum external quantum efficiency of 3.57%, and luminous efficiency of 3.66 cd/A, and OFETs with outstanding μh of 1.06 cm2 (V s)−1 were demonstrated. Our results suggest that d-limonene would be a promising non-aromatic and non-chlorinated solvent for solution processing of conjugated polymers and molecules for optoelectronic device applications. 相似文献
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数据结构是计算机专业的核心课程,对计算机学科起到承前启后的作用,而数据结构的抽象性,使学生掌握其课程内容感到困难,为了激发学生的学习兴趣,更好地掌握课程的理论知识,提高算法的设计能力和分析能力,本文针对数据结构课程教学现状和对存在的问题,就教学内容、教学方法和手段提出几点改革。 相似文献
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运用Legget—Williams锥上的不动点定理,讨论时间模上的二阶非线性方程三一点边值问题至少有三个正解的存在性. 相似文献
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根据人脑的核磁共振影像(MRI)以及人脑组织数据,采用多物理量有限元模拟的方法进行建模,计算了人脑在手机近场辐射情况下的比吸收率(SAR)和局部温升的特性,并就辐射对人脑的影响问题进行了探讨。模拟结果符合相关国际标准规定,模拟数据合理。 相似文献
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针对目前基于评论文本的推荐算法存在文本特征和隐含信息提取能力不足的问题, 提出一种基于注意力机制的深度学习推荐算法. 通过分别构建用户和项目的评论文本表示, 利用双向门控循环单元提取文本的上下文依赖关系以获得文本特征表示, 引入注意力机制, 更准确的获取用户兴趣偏好和项目属性特征. 将生成的用户和项目评论数据的两组隐含特征分别输入全连接层处理, 再合并到同一个向量空间进行评分预测, 得到推荐结果. 在Yelp和Amazon两个公开数据集中进行实验, 结果表明所提出的算法与其他算法相比, 具有更好的推荐性能. 相似文献
10.
针对传统攻击检测方法检测稳定性低以及检测精准度差的问题,提出一种基于动态无线传感网的抗合谋Sybil攻击检测方法。根据动态无线传感网络组成结构得出对应检测原理,同时计算获取出攻击检测目标函数;在空间约束条件基础上引入无线网络攻击检测法,分类处理Sybil攻击,获取出网络被攻击节点位置;根据角度-衰减度检测法计算得出网络攻击两点基本原则,通过锚节点定位攻击节点,完成抗合谋Sybil攻击检测。仿真结果表明,所提方法能够有效解决传统方法带来的问题,且在计算过程中具有较高实用性以及广泛适用性。 相似文献