Designing amino-based ionic liquids for improved carbon capture: One amine binds two CO2

Generally, amine group captures CO₂ according to 2:1 or 1:1 stoichiometry. Here, we report a kind of improved carbon capture using amino-functionalized ionic liquids (ILs) through 1:2 stoichiometry. A serial of amino-functionalized ILs various with basicity and steric hindrance of anion were designed, prepared, and applied in CO₂ capture. Through a combination of absorption experiment, quantum chemical calculation, spectroscopic investigation and calorimetric method, the results indicated that one amine group could bind two CO₂ through proton transfer (PT) process and intramolecular hydrogen bond formation, which leading to enhanced capacity that breaks through equimolar. The basicity and steric hindrance of anion play a significant role in promoting amine group to capture two CO₂. [P₆₆₆₁₄]₂[Asp] with dual anion was further designed and synthesized to promote PT process, which showed high capacity of 1.96 mol/mol IL at 30°C and 1 atm as well as excellent reversibility. © 2018 American Institute of Chemical Engineers AIChE J, 65: 230–238, 2019     

Anchor plate bearing capacity in flexible mesh facings

This work addresses the problem of the loading capacity of an anchor plate coupled with a steel wire mesh in soil retaining applications. The interaction mechanism between the flexible mesh facing, the underlying soil layer and the plate is studied starting from the results of several laboratory punch tests involving both the plate and the mesh only, and the whole soil-mesh-plate system. The experimental tests have been reproduced by adopting a 3D discrete element model where also the wire mesh is discretized as an assembly of interconnected nodal particles. The interaction between these particles is ruled by elasto-plastic tensile force–displacement laws in which a distortion is introduced in a stochastic manner to account for the wires’ geometrical irregularities. The mesh model is then validated with reference to a set of punch tests in which the shape and size of the punching element as well as the nominal wire diameter were varied. Subsequently, the model is extended to a punch against soil test configuration permitting an insight into the nontrivial local mechanism between the mesh facing and the underlying granular layer. The good agreement between the numerical predictions and the experimental observations at the laboratory scale allowed us to extend the model towards more realistic field conditions for which the role of the mesh panel boundary conditions, the mesh mechanical properties, the soil mechanical properties and the anchor plate geometry is investigated.     

Consolidation considering increasing soil column radius for dredged slurries improved by vacuum preloading method

Soil column is often investigated in the improvement of dredged slurries. Different from the smear zone, the soil column forms gradually and has extremely low permeability. This study presents an analytical solution for soil consolidation considering the increasing radius of the soil column and time-dependent discharge capacity. Based on the solution, the influence of the radius' increase on the consolidation behavior is found significant when the soil column has low permeability and large final radius, and the increase of formation time can lead to the increase of consolidation speed and final consolidation degree.     

鑫汇公司350t/d选矿厂工艺优化改造

基于对低能耗及设备高效利用的要求,鑫汇公司350 t/d选矿厂原工艺流程已无法满足现场的生产需求,对其进行了工艺优化改造。通过调整破碎机安装位置、振动筛安装方向、药剂制度以及更换细碎设备、筛网尺寸等措施,达到了节能降耗的目的,不仅增加了选矿厂的生产能力,而且提高了金的回收率,由89.08%提高到92.58%,年增创收益达1 494.41万元,经济效益和社会效益显著。     

Influence of drying conditions on colour,betacyanin content and antioxidant capacities in dried red-fleshed dragon fruit (Hylocereus polyrhizus)

In this study, drying of red-fleshed dragon fruit at different temperatures (40, 50, 60, 70 and 80 °C) and air velocities (1.0 and 1.5 m s⁻¹) was conducted under the specific humidity of 25 g H₂O kg⁻¹ dry air. The results showed that drying at higher temperatures resulted in shorter drying times. However, temperature and air velocity did not significantly affect the total betacyanin contents and antioxidant capacities in dried products. Seven betacyanins identified by LC-MS were betanin, isobetanin, phyllocactin, isophyllocactin, betanidin 5 –O-(6′O-3-hydroxybutyryl)-β-glucoside, isobetanidin 5 –O-(6′O-3-hydroxybutyryl)-β-glucoside and decarboxylated phyllocactin. In addition, the temperature increased the isomerisation of betacyanins. The most preferable condition for preserving the colour and betacyanin contents of red-fleshed dragon fruit was the drying at a temperature of 80 °C and air velocity of 1.5 m s⁻¹ since it could shorten the drying time and give a bright red colour to the dried product as well as it had no significant impact on the betacyanins.     

Amino acid profile,protein digestibility,thermal and functional properties of Conophor nut (Tetracarpidium conophorum) defatted flour,protein concentrate and isolates

Functional properties, amino acid compositions, in vitro protein digestibility, electrophoretic and thermal characteristics of conophor defatted flour (CDF), conophor protein concentrate (CPC), isoelectric protein isolate (CII) and neutral protein isolate (CNI) were evaluated. The isolates (CII and CNI) showed significantly lower (P < 0.05) water and oil absorption capacities, emulsifying and gelling capacities, but higher emulsion stability and foaming capacity. In vitro protein digestibility, enthalpy and denaturation temperature varied between 52.28% and 73.4%, 1.62–4.04 J g^?1 protein and 79.7–89.3 °C, respectively. The native proteins were comprised of subunits with molecular weights ranging between 15.3 and 129.3 kDa. The major amino acids in all the samples were aspartic acid, glutamic acid and arginine, whereas the percentages of essential amino acids in CDF, CPC, CII and CNI were 39.35%, 40.46%, 44.54% and 46.04%, respectively. Conophor protein products could be used as functional ingredients in food formulations and for enriching low quality protein diets.     

Hot-Water Extraction Optimization of Sugar Maple (Acer saccharum Marsh.) and Red Maple (Acer rubrum L.) Bark Applying Principal Component Analysis

In the forest industry, bark is an abundant residue, predominantly converted into calorific energy. As the antioxidant potential of phenolic compounds from sugar maple (Acer saccharum Marsh.) and red maple (Acer rubrum L.) bark has previously been established, the present study focused on the hot-water extraction optimization of these barks. Several process parameters (maple species, temperature, duration, ratio bark/water, particle size) were thus studied and large disparities were found between the two species. Extraction yield, phenolic content, and antioxidant capacity of red maple extracts were several times higher than those of sugar maple extracts. Principal component analysis, applied to the selected best extraction conditions, identified 3–4 clusters depending on the maple species. These groups were sorted from the highest extraction yield and energy consumption combined with the lowest phenolic content and antioxidant capacity, to moderate extraction yield and energy consumption with the highest phenolic content and antioxidant capacity.     

重载铁路牵引主变压器过负荷能力浅析

对铁路牵引主变压器过负荷情况进行了分析,针对不同情况提出了相应措施,充分发挥牵引变压器的过负荷能力,做到既节约增容改造资金,又保证不间断供电。     

Scale effect on the behaviour of geogrid-reinforced soil under repeated loads

One of the most useful geosynthetics in soil reinforcement is geogrid due to its high tensile strength, having a great influence on soil skeleton reinforcement and eventually, increasing bearing capacity of the foundation. In this research, a series of 36 repeated plate load tests have been carried out to investigate the scale effect on geogrid-reinforced soil, tending to further understanding of the behaviour of geogrid-reinforced soil system. Four different soil grains sizes, two different geogrid's aperture sizes (with roughly the same tensile strength) and three different loading plate sizes are the variables considered. During the tests, the applied loading and soil surface settlements were recorded to evaluate the systems' response. As it was expected, the reinforced soil exhibited higher bearing capacity than the unreinforced status, up to 635%. The results show that increasing loading plate size and soils' particle size fortify the response of foundation, especially in reinforced status, against the loading plate penetration. The results further focused on the important role of scale effect on the response of reinforced foundation. It was understood that the optimum nominal aperture size of geogrids should be about 4 times of medium grain size of soil. Also, it was found out that in order to acquisition of highest reinforcement benefits, the footing's width should be in the range 13–25 (20 in average) times of medium grain size of the backfill. Finally, to achieve the best results, it is recommended that the aperture size of geogrids should be selected roughly 0.2 times of footing width.     

矿用永磁耦合联轴器过载保护实验研究

 摘要：本文利用Ansoft maxwell有限元模拟分析及实验，研究应用于煤矿井下的磁力耦合联轴器的过载保护问题，并通过实验数据绘制出机械特性曲线。从机械特性曲线可以看出：输出扭矩值在达到磁力耦合器的最大转矩后，随着转差增大，输出转矩、转速降低，电动机的输入功率小于电动机在最大转矩时的功率，说明此磁力耦合联轴器具备过载保护性能。