双醛羧甲基纤维素改性胶原气凝胶复合相变材料的制备及性能

以制革固体废弃物中提取的胶原为原料、双醛羧甲基纤维素（DCMC）为大分子交联剂，通过冷冻干燥技术制备了DCMC改性胶原气凝胶，利用FTIR和SEM对其结构和形貌进行了表征。结果表明，DCMC的引入不会改变胶原三股螺旋结构，且制得的DCMC改性胶原气凝胶具有丰富的多孔结构、低密度（8.83~10.38mg/cm3）、高孔隙率（94.99~97.65%）和良好隔热性能。当DCMC含量小于15%时，DCMC改性胶原气凝胶的压缩应力随DCMC含量的增加而变大。此外，为进一步提升DCMC改性胶原气凝胶的隔热性能和耐久性，通过真空浸渍法填充相变材料和浸涂法疏水处理，制备出DCMC改性胶原气凝胶复合相变材料。隔热实验、泄露实验和防污实验等实验结果表明，气凝胶复合相变材料相比于气凝胶具有更加优异的隔热效果，拓展了其实际应用范围。     

氧空位对氧化锆相结构稳定性及相变过程的影响

从晶体学和配位学的角度，结合电化学技术，讨论了氧空位对氧化锆相结构结构稳定性的影响及氧化锆四方相单斜相转变过程中的作用。结果表明：氧空位的存在与变化不仅影响着氧化锆相结构的稳定性，而且影响着氧化锆的低温相变过程。对于含有一定担氧空位的亚稳四方相氧化锆，氧空位浓度的增加与减少都会进一步降低其结构稳定性，使之更加容晚地向单斜相转变     

改进教与学优化算法的LQR控制器优化设计

为了快速有效地确定线性二次最优控制(linear quadratic regulator,LQR)问题中的加权矩阵Q和R,针对主动悬架LQR控制器权系数设计问题,提出一种改进的教与学优化算法进行LQR优化设计。算法对基本教与学优化算法中的"教"与"学"阶段进行了进一步的改进,同时提出一种"自我学习"策略。通过仿真实验表明,和基本教与学算法、粒子群算法、遗传算法相比,本文算法在对主动悬架LQR控制器优化时,具有收敛速度快,求解精度高和稳定性强等优势。     

基于循环维纳滤波的振动信号去噪算法研究

振动信号的去噪需要在滤除噪声的同时尽可能避免相位失真。传统的锐截止低通滤波器或FIR滤波器无法在去噪效果和线性相位之间取得平衡,难以满足振动信号的去噪需求。针对这一问题,将线性相位的维纳滤波算法引入到振动信号的去噪中,并结合振动信号的循环平稳特性,形成了振动信号的循环维纳滤波算法。文中以直接维纳滤波为基础对循环维纳滤波算法的原理进行了深入分析和仿真实现,并基于实测汽轮机振动信号对算法的去噪性能进行了讨论。理论分析及算法仿真表明,循环维纳滤波算法在保证线性相位的前提下有较好的去噪效果,能够解决传统去噪算法所存在的去噪效果与线性相位难以均衡的问题。     

Human control model in teleoperation rendezvous

This paper proposes a human control model in teleoperation rendezvous on the basis of human information processing （perception, judgment, inference, decision and response）. A predictive display model is introduced to provide the human operator with predictive information of relative motion. By use of this information, the longitudinal and lateral control models for the operator are presented based on phase plane control method and fuzzy control method, and human handling qualities are analyzed. The integration of these two models represents the human control model. Such a model can be used to simulate the control process of the human operator, which teleoperates the rendezvous with the aid of predictive display. Experiments with human in the loop are carried out based on the semi-Physical simulation system to verify this human control model. The results show that this human control model can emulate human operators＇ performance effectively, and provides an excellent way for the analysis, evaluation and design of the teleoperation rendezvous system.     

Measurement of intrinsic rates for homogeneous gas‐phase reactions at high temperatures

A coiled quartz tubular reactor has been designed to measure the intrinsic reaction kinetics for homogeneous reactions at high temperatures up to 1100°C. Actual gas residence times were less than 100 ms. A simple and well‐studied test reaction (i.e., the decomposition of nitrous oxide, N₂O), with published intrinsic kinetics, was used to verify the operation of the experimental reactor. For this system, Peclet numbers (Pe = uL/DL) computed from experimental conversion data were greater than 1000, indicating that the plug flow assumption could be used with this reactor system to determine intrinsic rate expressions with errors of less than 5% for the conditions studied.     

水平矩形管内气液两相流界面波特性

<正>气液两相流中界面波的存在对传热、传质、阻力特性及稳定性都有很大影响。前人有关界面波的研究大多偏重于两相流中界面波的类型及其转变,而对其特征参数变化规律(如振幅、波长、频率和速度等)的研究则很少。但界面波对气液两相流流动阻力和流动结构影响机理的深入研究必须以了解界面波的各特性参数为前提,同时界面波有关特性参数的深入研究也可为气液两相流的数学理论化提供实验基础。 本文以气、水为工质,系统研究了水平矩形管内气液两相流的界面波特性。根据界面波在时域、幅域内的不同特征区别出了各种类型的波并给出了相应的波形和流型图。着重研究了界面波各特征量随气液两相流量变化的变化规律。     

基于超级电容的电梯能量再生系统

针对电梯采用制动电阻消耗回馈能量造成的极大浪费,介绍基于超级电容的电梯能量再生系统及其控制逻辑的设计。     

用新型碳分子筛分析永久气体

本文介绍一种新型气相色谱固定相——碳分子筛(KMS),其最大的优点是在常温下,单柱即可同时分离分析H_2、O_2、N_2、CO、CH_4、CO_2六种混合气体,柱子的保留值重现性好,峰形对称,柱效高。本文求得了在H_2和Ar作载气时KMS对上述六种气体的定性定量特性,配气的定量结果总的平均相对误差为3.67％。同时这种碳分子筛原料易得,制作简单,成本便宜。     

Porous poly(vinylidene fluoride) membrane with highly hydrophobic surface

The preparation of very hydrophobic poly(vinylidene fluoride) (PVDF) membranes was explored by using two methods. The first one was the modified phase inversion method using a water/N,N‐dimethylacetamide (DMAc) mixture instead of pure water as a soft precipitation bath. The second method was a precipitation‐bath free method, that is, the PVDF/DMAc casting solution underwent gelation in the open air instead of being immersed into a precipitation bath. The morphology of the surface and cross section of the membranes was investigated by using scanning electron microscopy (SEM). It was found that the membranes exhibited certain micro‐ and nanoscale hierarchical roughness on the surface, which brought about an enhanced hydrophobicity of the membrane. The contact angle (CA) of the samples obtained by the second method was as high as 150° with water. The conventional phase inversion method preparing PVDF porous membrane using pure water as precipitation bath usually results in an asymmetric membrane with a dense skin layer having a CA close to that of a smooth PVDF surface. The modified approach avoided the formation of a skin‐layer and resulted in a porous and highly hydrophobic surface of PVDF. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1358–1363, 2005