PETROLEUM POTENTIAL, THERMAL MATURITY AND THE OIL WINDOW OF OIL SHALES AND COALS IN CENOZOIC RIFT BASINS, CENTRAL AND NORTHERN THAILAND

Oil shales and coals occur in Cenozoic rift basins in central and northern Thailand. Thermally immature outcrops of these rocks may constitute analogues for source rocks which have generated oil in several of these rift basins. A total of 56 oil shale and coal samples were collected from eight different basins and analysed in detail in this study. The samples were analysed for their content of total organic carbon (TOC) and elemental composition. Source rock quality was determined by Rock‐Eval pyrolysis. Reflected light microscopy was used to analyse the organic matter (maceral) composition of the rocks, and the thermal maturity was determined by vitrinite reflectance (VR) measurements. In addition to the 56 samples, VR measurements were carried out in three wells from two oil‐producing basins and VR gradients were constructed. Rock‐Eval screening data from one of the wells is also presented. The oil shales were deposited in freshwater (to brackish) lakes with a high preservation potential (TOC contents up to 44.18 wt%). They contain abundant lamalginite and principally algal‐derived fluorescing amorphous organic matter followed by liptodetrinite and telalginite (Botryococcus‐type). Huminite may be present in subordinate amounts. The coals are completely dominated by huminite and were formed in freshwater mires. VR values from 0.38 to 0.47%R_o show that the exposed coals are thermally immature. VR values from the associated oil shales are suppressed by 0.11 to 0.28%R_o. The oil shales have H/C ratios >1.43, and Hydrogen Index (HI) values are generally >400 mg HC/g TOC and may reach 704 mg HC/ gTOC. In general, the coals have H/C ratios between about 0.80 and 0.90, and the HI values vary considerably from approximately 50 to 300 mg HC/gTOC. The HI_max of the coals, which represent the true source rock potential, range from ～160 to 310 mg HC/g TOC indicating a potential for oil/gas and oil generation. The steep VR curves from the oil‐producing basins reflect high geothermal gradients of ～62°C/km and ～92°C/km. The depth to the top oil window for the oil shales at a VR of ～0.70%R_o is determined to be between ～1100 m and 1800 m depending on the geothermal gradient. The kerogen composition of the oil shales and the high geothermal gradients result in narrow oil windows, possibly spanning only ～300 to 400 m in the warmest basins. The effective oil window of the coals is estimated to start from ～0.82 to 0.98%R_o and burial depths of ～1300 to 1400 m (～92°C/km) and ～2100 to 2300 m (～62°C/km) are necessary for efficient oil expulsion to occur.     

埋地管道在冻土带的热力变形分析

埋地油气管道通过永冻土地带时,由于管内介质与周围的冻土发生了热力作用,使冰土解冻,在管道周围形成融化圈。文章分析了永冻土的特点,建立了永冻土地带土壤传热数学模型:融化圈内外传热方程、管道向土壤和土壤表面向大气所放热量的守恒关系、融化圈界面处土壤温度、相变界面处固相变为液相的传热条件。还建立了埋地管道模型,并以穿过永冻土地带土壤的输油管道为例,分析并计算了各种应力的最大值所在的位置和大小,提出了在永冻土地带减小管道热力变形的措施。     

甲烷水合物热稳定性的研究

研究了在阴离子表面活性剂十二烷基硫酸钠(SDS)体系中甲烷水合物在冰点以下的常压分解规律。研究结果表明,静态下生成的甲烷水合物较动态下的分解速度低;在262·15~268·15K在之间,甲烷水合物的分解速度随着温度的降低而升高;在此范围以外,甲烷水合物的分解速度随着温度的降低而降低;在262·15~272·15K之间存在最低分解速度,其中在268·15K,甲烷水合物的分解速度最低。利用外推法计算268·15K时甲烷水合物完全分解需要25d,说明水合物的自我保存性质对气体水合物储运技术具有重要意义。     

Microstructures and Phase Transition Points of As-Cast Mg-Zn-Y System Alloys

As-east mierostruetures and their distribution of Mg-Zn-Y ternary alloy with high magnesium, low zinc and yttrium were examined using Nikon Epiphot optical microscopy （OM）, RigakuD/max-3C X- ray diffraetion （XRD）, and JEOL JSM-6700F scanning electron microscopy （SEM） equipped with an energydispersive X-ray spectroscopy （EDS）. In the as-east mierostructures, Yttrium and zinc tend to segregate at grain boundaries,     

铌和钨对γ-TiAl基合金热稳定性的影响

采用光学显微镜(OM)，扫描电镜(SEM)，X射线衍射研究了TiAl—5Nb，TiAl—14．3Nb，TiAl—8Nb—1W，TiAl—12．3Nb-2W四种合金片层组织在1000℃的热稳定性。结果表明，TiAl—12．3Nb-2W合金热稳定性最好，但合金元素对TiAl基合金热稳定性的影响机理还有待进一步的研究。     

ca油田稠油油藏系统保护油气层研究

针对ca油田多层状砂泥薄互层稠油油藏的特点,开展了热采和非热采条件下储层变化特征研究、钻井和固井过程入井液的研究、采油工艺技术等系统保护油气层研究,了解各种变化的作用过程和原因,有效地预防现场施工中可能发生的储层伤害,从而达到储层保护、提高采收率的目的。     

聚焦平台光束大气传输光束扩展的定标参数分析

建议采用63.2%环围能量半径及其内平均功率密度描述激光器大气传输光斑扩展特性.通过利用数值模拟及实验观测相结合的方法,对聚焦平台光束大气传输线性效应及湍流热晕相互作用引起的光束扩展进行了大量的数值模拟及部分实验研究,建立了描述聚焦平台光束大气传输光束扩展与大气传输特征物理参量的定标关系,从而为激光工程应用的可行性及系统参量的优化设计提供依据.     

纵向泵浦Cr∶ Nd∶GSGG激光棒的热透镜效应研究

对纵向泵浦Cr∶Nd∶GSGG激光棒的热透镜效应进行了详细的理论分析。对温度分布的函数表达式 ,进行了讨论 ;分析了热引起的应力 ,得到了激光棒破裂的临界功率公式 ;最后对光学畸变进行了分析与讨论 ,推导了光程差计算公式     

Nd3+:Y0.5Gd0.5VO4晶体生长和基本特性

Nd^3 :Y0.5Gd0.5VO4晶体作为一种新的激光材料，可以用中频感应加热提拉法生长。X射线粉末衍射分析表明它的结构与Nd^3 :YVO4晶体结构相同，它的晶格常数介于YVO4和NdVO4晶格常数之间。用ICP光谱法测定晶体中Nd^3 含量为0．8at％，分凝系数为0．8，与Nd^3 :GdVO4晶体中Nd^3 的分凝系数0．78相当；用称重法测定其密度为5．00g／cm^3；用稳态纵向热流法测出其室温热导率为12．5W／mK。实验表明Nd^3 :Y0.5Gd0.5VO4晶体有希望作为高功率ID泵浦激光晶体材料。     

一种用热像仪获得烟幕透过率的方法

提出了一种用热像仪测试烟幕透过率的方法。经详细分析烟幕遮蔽前后热像仪探测器接收到的红外辐射情况，并经理论推导得出：不考虑烟幕释放对环境辐射和大气辐射的影响时，只需用热像仪对同一场景拍摄其烟幕释放前后的图像，利用这两幅图像的灰度信息即可获得烟幕的透过率，并且，只要场景选择合适，应用该方法可以测得烟幕的透过率分布。论文最后讨论了减小透过率计算误差的方法和获得烟幕透过率分布的技术途径。