压水堆硼稀释事故的计算

一、概述核电厂压水堆的初始过剩反应性是通过控制捧、固体可燃毒物和溶解在主回路冷却剂中的硼酸等三种方式联合控制的。随着反应堆的燃耗和裂变毒物的积累,堆的过剩反应性不断减少,需要通过化容系统,控制硼酸的浓度来进行补偿。如果化容系统发生故障或操作员误操作,就会给回路注入无硼或低于规定浓度的补给水,给反应堆引入正反应性,造成硼稀释事故。按核安全法规的要求,应对换料、冷停堆、热停堆和启动等工况进行计算,并要求在这些     

Transient operation of a catalytic liquid-liquid plug flow reactor for kinetics measurements

A centrifugal partition chromatograph (CPC) was used as a liquid-liquid catalytic reactor for the isomerisation of hexen-3-ol into ethylpropylketone with a water soluble rhodium catalyst. Global mass transfer coefficients were measured and shown to depend on both the nature of the solute and the flow rate. Liquid-liquid partition isotherms were also determined with the CPC using elution chromatography. Finally, a reactor model was derived to account for the experimental results obtained both under stationary and transient (pulse) conditions. A parameter sensitivity evaluation is also presented.     

动态不确定多输入多输出系统的变结构鲁棒控制

本文仅利用输入输出数据给出了一种动态不确定多输入多输出系统的变结构控制器设计机制，控制系统的设计中引入了一个严格正实的模型．应用适当逻辑切换的状态变量滤波器实现变结构控制．证明了所提方案能保证全局输出有界稳定并能实现滑模控制和渐近跟踪参考模型的输出．该设计方案对结构不确定性具有一定的鲁棒性．仿真结果表明了所提方案的有效性．     

电离气体选择性激发产生变色发光的研究

本文综述我们对电脑气体选择性激发产生变色发光的理论研究和实验研究，并探讨这种类型变色发光的实际应用。     

神经网络离散变结构控制的算法及其应用

本文首次将自适应线性神经元（Ａｄａｌｉｎｅ）用于离散变结构控制。以滑模面Ｓ（ｋ）＝０作为Ａｄａｌｉｎｅ元的希望输出，作为Ａｄａｌｉｎｅ元的实际输出，通过ＬＭＳ算法在线调整权值可保证滑态可达条件的满足。应用所提出的控制策略对泵控马达速度伺服系统进行控制，仿真表明控制效果是令人满意的。     

注塑成型计算机模拟

塑料制品的几何形状各异，模腔内的流动复杂，导致价格昂贵的模具开发费用。通过流变学方法对充模过程进行定量模拟，可以为模具统计与注塑工艺优化提供定量依据。对注塑成型有关的数学模型作了讨论，给出了充模，保压和冷却３个阶段的数学模型，讨论了流道流动和三维薄壁模腔流动，还对反应注射成型计算机模拟作了讨论。     

数字式速度比例同步电脑控制系统

数字式速度比例同步控制系统，是把先进的交流变频调速技术，微电子技术和节能效果显著的永磁同步电机融为一体组成的性能优良的调速控制系统。该系统具有调速精度高调整范围大、稳定性好、抗干扰能力强、调整方便、节电效果显著等一系列优点。本文详细介绍了该系统的工作原理，并通过应用实例和分析对比，阐述该系统的优越性。     

Selective partial oxidation of light paraffins with hydrogen peroxide on thin-layer supported Nafion-H catalysts

Thin-layer carbon supported Nafion-H catalysts were found to be active and highly selective (S>98%) for the partial oxidation of C₁-C₃ alkanes, in a three phase catalytic membrane reactor (3PCMR), under mild conditions and in the presence of H₂O₂. The influences of the catalyst teflon loading and H₂O₂ concentration on the reaction rate have been evaluated. A reaction pathway, based on the electrophilic hydroxylation of the C-H bond of alkanes with protonated hydrogen peroxide (H₃O ₂ ⁺ ), is discussed.     

Control of the quality of polymer products in continuous reactors: comparison of performance of state estimators with and without updating of parameters

In the paper the control of the product quality in polymerization reactors is analysed in the presence of persistent perturbations (unmodeled disturbances, modeling errors), as met in industrial reactors. The free radical polymerization of methyl-methacrylate in a continuous stirred tank reactor is studied. It is shown that state estimators (Extended Kalman Filters) with constant parameters cannot give offset free performance. Criteria for the selection of a set of parameters to be updated as additional states in the filter and to evaluate their effectiveness in opposing the action of realistic perturbations are given by an analysis of the linearized model of the system. Performance of different types of estimators, including one and two-time scale filters, with and without updating of parameters, is analysed by simulation on the full order process and the predictions made by previous analysis are confirmed. In the most common case of presence of perturbations affecting the energy balance and the concentration of initiator in the reactor, offset free control of the molecular weight of the product can be achieved by means of a filter which is based only on measurements of temperature and conversion and makes an update of two parameters. In the case that also the kinetic model of the polymerization reaction is affected by errors, a two-time scale filter, which makes use also of Molecular Weight values and updates three parameters, becomes necessary to obtain offset free performance.     

采用先进技术提高装置运行水平

介绍了中国石油化工股份有限公司高桥分公司 1.4Mt/a同轴式重油催化裂化装置的特点和生产情况。为了满足市场需求 ,提高经济效益 ,几年来在该装置上又采用了一些新技术 ,使装置的运转水平进一步提高。如应用降烯烃催化剂GOR Q ,与使用MLC 5 0 0催化剂相比 ,汽油烯烃体积含量约 30 % ,下降 8～ 10个百分点 ;汽油辛烷值基本不变 ;产品分布改善 ;液体收率增加 ;柴油性质变化不大。又如最大量烷烃异构化 (MIP)新型提升管反应系统的应用 ,与常规催化裂化相比 ,产品分布相当 ,汽油的烯烃体积含量下降至 30 %～ 35 % ,MON增加 0 .5～ 0 .8个单位 ,RON下降幅度不大于 0 .5个单位