温度应力、自收缩对高性能混凝土早期开裂的影响

根据高性混凝土的水化特性、物理力学特性及自收缩特性，分析了高性能混凝土早期开裂机理和影响早期开裂的主要因素．并结合工程实例，借助混凝土温度和应力有限元仿真计算方法分析研究了表面适度保温和水管冷却技术在高性能混凝土温控防裂中的应用效果．研究结果表明，表面适度保温与水管冷却相结合能有效降低混凝土的内外温差，减小混凝土早期表面拉应力与后期内部拉应力，防裂效果明显，对类似的工程具有借鉴作用．     

重油催化裂化装置的环保对策

对重油催化裂化过程中的环境影响因素、硫分布状况及硫平衡等进行了分析，指出了重油催化裂化过程中的环境污染问题；从对装置污染源的分析出发，提出了相关的治理措施。     

催化裂化沉降器多臂式旋流快分系统封闭罩内的流场

用智能型五孔探针对催化裂化沉降器内多臂式旋流分离系统封闭罩内的气体流场进行了测试。测试结果表明，罩内流场为轴对称的三维湍流场，在旋流头喷出口处径向速度较大，呈短路流现象。根据流场测试结果，建立了三维气流速度分布的无因次计算式，可供工程设计参考。     

沸石孔结构对1-己烯异构化性能的影响

采用1-己烯为原料,对硅铝比相近、不同孔结构的沸石在脉冲微反装置上进行了评价试验,考察了FCC条件下沸石孔结构对烯烃异构化性能的影响。结果表明,大孔径的Y型沸石具有良好的异构化性能,异构化能力由强到弱的排列顺序为Y>β>ZRP>丝光沸石>镁碱沸石。     

Fracture toughness of thermoset composites reinforced by perfectly bonded impenetrable short fibers

The fracture toughness of brittle thermoset resins could be improved significantly by perfectly bonded tough, short fibers through both crack trapping and bridging effects. In this paper, the crack trapping effect was studied through the analysis of the change of strain energy associated with the crack propagation across a regular array of fibers, and the bridging effect was discussed based on the Andersson–Bergkvist model. The fracture resistance increases with the fiber volume fraction, and is independent of the elastic properties of the matrix, the crack length, and the cross-sectional diameter of the fibers.     

街面水电站混凝土面板堆石坝主要技术问题探讨

街面水电站拦河坝为混凝土面板堆石坝,在面板止水结构型式、面板防裂措施、上游面的施工方法、趾板开挖处理及趾板灌浆等方面,根据工程实际情况,结合国内外的新技术新工艺进行了探讨。     

钛制设备在焦化行业中的应用

介绍焦化行业钛设备的应用,剖析了分块式钛泡罩塔盘的结构特点,并对其经济性作了分析。     

催化裂化汽油脱硫助剂TS-01的工业试验

中国石油化工股份有限公司九江分公司在I套催化裂化装置进行了TS—0l催化裂化汽油脱硫双功能助剂的工业应用。结果表明：TS—0l剂对催化裂化汽油有较好的脱硫效果。当TS—0l剂注入原料中的量为70μg／g时，对催化裂化汽油的硫脱除率约为20％；注入量为120μg／g时，硫脱除率可达到25％-30％。汽油中脱除的硫主要以硫化氢形态转移至于气、液化气中。TS—01剂对产品分布及产品其它质量无明显影响，该剂亦有良好的金属钝化效果。     

吸附精制提高催化裂化柴油的安定性

用卸出的催化裂化平衡催化剂对催化裂化柴油进行吸附精制，取得了很好的效果。精制油收率99％以上，其安定性达到了优级轻柴油的标准（沉渣＜2．0mg／100mL，色号≤16）。精制后柴油的胶质下降约1个百分点，对吸附物的组成分析表明，其氮含量是柴油的17倍以上。对精制油的分析表明，吸附精制可明显降低柴油的酸度和碱性氮化物的含量。     

Study of direct and indirect naphtha recycling to a resid FCC unit for maximum propylene production

To satisfy the increasing propylene demand, direct and indirect naphtha recycling schemes around an existing resid fluid catalytic cracking (FCC) unit were investigated. To this aim, light cracked naphtha (LCN), heavy cracked naphtha (HCN) and a PolyNaphtha (PN) oligomerisation product were cracked under a wide range of operating conditions over a commercial Y zeolite based equilibrium catalyst. Experimental data were acquired in three different units: a fixed bed bench scale unit, a fixed fluidised bed unit and an adiabatic circulating fluidised bed pilot plant. It was shown that FCC naphthas require high operating severities to crack, and that even then their conversion remains relatively moderate. Hence, direct recycling to the main riser does not seem a viable pathway to increase propylene product. Feeding FCC naphthas to a second reaction zone operating at high severity allows to increase the propylene yield in a significant manner. Increasing conversion, however, not only leads to higher LPG and propylene yields, but also results in very high dry gas yields. An alternative scheme was proposed, in which the olefinic C₄ and C₅ fractions are converted into a naphtha fraction through oligomerisation in a dedicated unit before being recracked in the secondary riser. As the highly olefinic oligomerised effluent mainly consist of dimerised and trimerised butenes and pentenes, this feed is more easily cracked and high conversions can be achieved. This indirect interconversion of butenes and pentenes into propylene therefore effectively allows to convert these butenes and pentenes into propylene, resulting in a significant increase in propylene yield. Each of the three main naphtha recycle options (directly to the main riser, directly to a secondary riser or indirectly via a light olefin oligomerisation unit) have been analysed and compared to a base case. In the evaluation of each of these schemes, all heat balance effects, both on the riser and the regenerator side, have been accounted for. The proposed process scheme with an indirect recycle via an oligomerisation unit enhances the already inherent flexibility of the FCC unit. The naphtha recycle can be turned on or off, the second reaction zone can be used to crack naphtha or to crack resid feed to maximise throughput, while the effluent of the oligomerisation unit can be recycled to the FCC unit for propylene production or hydrogenated and sent to gasoline and kerosene pool.