磁通门传感器探头温度特性研究

磁通门传感器主要由磁探头与电路部分组成,其输出不仅随磁场变化,而且易受温度的影响。为了确定磁通门传感器磁探头在宽温度范围下的温度漂移情况,通过试验将探头置于-40℃~150℃的温度环境下,记录得到探头在宽温度范围下,其温度特性曲线近似为正比线性关系。分析认为,磁芯磁滞回线受热偏移与线圈漆包线随温度热胀冷缩是磁探头温漂的主要原因。本文提出选用低磁导率磁芯和高温漆包线绕制探头,并优选一致性较好的探头,采用最小二乘法对温度漂移结果进行拟合补偿,有效地消除了温度对磁探头的影响,提高了磁通门传感器的温度稳定性与应用的广泛性。     

集成于无源UHF RFID标签的宽温测范围CMOS温度传感器

针对无源UHF RFID标签温度测量范围小、功耗等问题,本文提出了一种集成于无源UHF RFID标签的宽温测范围CMOS温度传感器。本文设计采用UMC 0.18μm 1P6M CMOS工艺进行设计,提出一种新温度脉冲转换电路结构产生随温度变化的脉冲,从而实现了宽温度测量。仿真结果表明:当温度范围在-75℃~125℃时,温度脉冲宽度变化近220μs,标签芯片供电电压为1.5V时,室温时新增的温度传感器模块功耗仅为200 nW,温度传感器精度为0.45℃/LSB。测试结果:在-5℃~45℃范围内进行测试,温度传感器精度为0.48℃/LSB,其中在室温25℃左右振荡器频率2.087 MHz,脉冲宽度大约110μs,异步计数器显示为011011000。     

Exothermic effect in the process of electron‐beam curing of epoxy resins

Temperature measurements have been performed in the process of electron‐beam curing of EB‐I and EB‐II epoxy resin systems. The influence of initiator content, resin type, and dose rate on the temperature of the systems was studied. Transverse and longitudinal temperatures of samples in the glass vessel were also analyzed. The nature of temperature curves varied with the different epoxy resin systems in the steel mold, but did not change with different contents of the initiator. At the same time, the heat had no effect on the gel fraction of epoxy resin systems. The temperature curve was greatly affected by the dose rate, and its peak value, peak width, and plateau value also increased with it. The transverse temperature of EB‐II glass vessel samples increased as the radiation dose increased and, in the same sample, the temperature reduced as the distance between the radiation center and the test point increased. The longitudinal temperature of EB‐I and EB‐II resin systems in a glass vessel decreased as the radiation depth increased. As the radiation dose increased, the temperature of the EB‐I resin system increased simultaneously, while that of the EB‐II resin system initially increased and then kept constant when the dose reached a certain value. The temperatures of these two resin systems decreased rapidly when the radiation process stopped. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2217–2222, 2004     

电子陶瓷和器件的低温共烧技术

较系统地介绍了电子器件用低温共烧陶瓷(low temperature cofired ceramics,LTCCs)材料,探讨了其工艺中的若干问题。电子器件用低温共烧陶瓷材料包括:玻璃/陶瓷复合材料、结晶化玻璃、晶化玻璃/陶瓷复合材料以及液相烧结陶瓷,其中典型的和最为常用的LTCCs为玻璃/陶瓷(特别是氧化铝)复合材料。正在研究的一些陶瓷介质材料中,Bi基介质材料引起了人们的关注。玻璃/陶瓷复合材料的制备工艺中,应当着重关注和加深了解玻璃的流动性和结晶性、玻璃的起泡、玻璃和陶瓷颗粒间的反应、共烧材料的匹配等问题,从优选材料配方和优化工艺着手,从而获得优质可靠的材质和器件。     

Lifetime assessment of epoxies by the kinetics of thermal degradation

The kinetics of thermal degradation of 4,4′‐diaminodiphenylsulfone (DDS)‐cured glycidylethers (DGBA) and glycidylamines (TGDDM) have been studied by isothermal annealing. Thermal degradation proceeds via first‐order kinetics with activation energies of 138 (DGBA/DDS) and 95 kJ/mol (TGDDM/DDS). From these data the temperature‐dependent lifetime can be calculated. Based on the heat distortion temperature and 20 years' service as criteria, the upper service temperature is found to be around 115–120°C. In spite of the different activation energies and bond stabilities, only marginal differences in the upper allowed service temperatures between these resins were found. Only slight improvements can be expected by optimizing the cure conditions. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1881–1886, 2004     

安钢二炼焦加热集散控制系统

安钢二炼焦焦炉加热控制系统根据蓄热室温度，建立了可靠的数学模型，通过控制加热煤气的压力和烟道废气吸力实现加热的自动控制，并实现参数无纸记录，日报表的自动生成，设备巡检的记录等功能。     

苯酐固化邻甲酚醛环氧的热性能与热分解动力学

研究了邻甲酚醛环氧树脂(o CFER)与邻苯二甲酸酐固化物的热分解动力学,用动态力学谱仪测定了玻璃化温度(Tg)。讨论了固化剂用量、固化时间等因素对玻璃化转变温度(Tg)的影响。结果表明,固化体系的玻璃化温度随反应程度的增加而升高,当达到一定程度后,趋于一定值。利用热重分析仪(TGA)研究了完全固化产物的热分解动力学,说明热分解反应分2步进行。     

料温对RIM交联型聚氨酯脲结构与性能的影响

采用便携式微型反应注射成型机制备了一组料温分别为３０，４０，５０，６０℃的交联型聚氨酯脲。用ＤＳＣ和力学性能对试样进行表征的结果表明：料温提高有利于软、硬微相的混合，而硬链段微区的有序性变差。反映在宏观力学性能上则表现为：试样的拉伸强度提高，伸长率在５０℃料温时出现极大值，弯曲强度和弯曲模量则出现最小值。料温为３０℃时，物料混合不充分，随着料温升高，混合逐渐均匀，试样透明度提高。     

玄武岩连续纤维的制备

利用坩埚法制备玄武岩连续纤维。研究了玄武岩纤维的熔融过程和拉丝工艺以及玄武岩纤维的基本特性。结果表明:选择陕西略阳辉绿岩矿作为玄武岩连续纤维的原矿,采用分体式氧化铝氧化铬坩埚,高度为13 mm,孔径为4 mm,台阶式漏嘴纺制玄武岩连续纤维,最长能成形15 m,纤维直径为12．2μm。     

An economic and sensitive method for extracting chromium speciation in airborne inhalable dust,using a green sample treatment coupled with electrothermal atomic absorption

ABSTRACT

A new approach of cloud point extraction CPE procedure is optimized for hexavalent chromium determination in airborne dusts. Triton X-114 is used as a surfactant and 1-(2-pyridylazo)-2-naphthol as a specific complexing agent for the trivalent chromium’s removal from the aqueous phase to isolate hexavalent chromium compounds. The parameters influencing the extraction protocol (pH, surfactant concentration, and temperature are optimized. The obtained detection and quantification limits are 0.1 and 0.4 μg/L, respectively. The linearity is verified, with a regression coefficient close to 0.999 and the extraction recovery exceeds 99%. The method was successfully applied to analyze airborne samples collected from workplaces.