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81.
二元复合驱采出液矿场处理试验 总被引:1,自引:0,他引:1
利用研制的二元复合驱采出液矿场处理装置,对辽河油田兴28块兴191井采出液进行了矿场处理试验。结果表明,采用适宜的破乳剂及处理工艺技术,可以使矿场采出液处理达到净化油含水≤0.5%的指标。 相似文献
82.
83.
84.
研究了HIPS/PC共混物的相容性及HIPS-MA对HIPS(30)/PC(70)共混物的相容性、形态和拉伸性能的影响。DSC研究结果表明,HIPS/PC共混物中PS的玻璃化转变温度(Tg)不随组成而变化,而PC的Tg随其质量分数的降低逐渐向低温移动,说明HIPS/PC是部分相容体系。通过DSC、扫描电镜形态观察和拉伸性能测试结果发现,当HIPS-g-MA的含量低于7.5%时,共混物的相容性改善不明显,当其含量达到7.5%时,对共混物有明显的乳化作用,说明饱和的界面浓度在7.5%左右。HIPS-g-MA接枝共聚物在HIPS(30)/PC(70)共混物中的增容作用可能是酯交换反应原位生成的嵌段共聚物所致。 相似文献
85.
90年代以来,国外钻井液和完井液用聚合物添加剂的发展取得长足进步。本文介绍了国外目前用于钻井液和完井液的聚合物添加剂的类型及作用。 相似文献
86.
A general and complete methodology is presented to facilitate systematic modeling and design of polymer processes during the early development period. To capture and handle the subjective type of uncertainty, embedded in the preliminary process development, fuzzy theories are used as a basis to model and design the process in the presence of ambiguity and vagueness. Physical membership functions are developed for mapping the relation between process variables and the associated fuzzy uncertainties. Based on the qualitative results generated using our previously proposed “linguistic based preliminary design method,” the process modeling can be followed even in the absence of any process governing equations. The modeling is carried out by establishing an appropriate fuzzy reasoning system which provides a specific functional mapping that relates input process variables to one (or more than one) output performance parameter(s). A reduced yet feasible domain is generated by our qualitative design scheme to constrain the process variables. Now, any optimization routine can then be employed to search for a proper process design. We demonstrate the effectiveness of the proposed methodology by its application to a typical compression molding process. 相似文献
87.
氮化硅的性能及其聚合物材料 总被引:1,自引:0,他引:1
陈继兰 《高分子材料科学与工程》1996,12(6):144-147
叙述了氮化硅(Si3N4)的性能并制备了含Si3N4的聚合物材料,这种材料在医学上具有重要价值,对改变医学方面的概念、和对促进人类健康长寿具有重要意义。 相似文献
88.
Shiro Matsuoka 《Journal of research of the National Institute of Standards and Technology》1997,102(2):213-228
The high frequency end of the relaxation spectrum for polymer molecules involves the rotation of the segmental bonds. This fast relaxation process, however, cannot take place easily in the condensed state crowded by the densely packed conformers, necessitating the slower cooperatively synchronous relaxation. As the temperature is lowered, the domain of cooperativity grows towards the infinite size at the Kauzmann zero entropy temperature, though actually the system deviates from the equilibrium as the glass transition intervenes typically at 50 K above that temperature. The excess enthalpy and entropy drop faster than predicted by the rotational isomeric states which would reach zero only at 0 K. The real ΔCP is greater than that of the RIS value. The actual volume in excess of the crystalline lattice volume, however, points towards zero at 0 K. Thus, a polymer with higher Tg typically exhibits a lower density and modulus in the glassy state. Since the configurational entropy associated with the free volume is proportional to the logarithm of the latter, the Kauzmann temperature can be scaled by ln M, where M is the algebraic average of the conformer molecular weight. The temperature dependence of the most dominant, i.e., the largest equilibrium domain size will result in the Adam-Gibbs and Vogel equations for the characteristic relaxation time. The cooperative domain distribution leads to the relaxation spectrum that follows a power law. The relationship between the characteristic relaxation time and the rate of physical aging is derived. 相似文献
89.
The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002 相似文献
90.
为了不使用任何还原剂而获得聚合物固载高分散零价双金属加氢催化剂,利用金属蒸气法制备了3种不同Pd/Cu质量比的聚合物固载双金属原子簇。透射电镜(TEM)和X衍射(XRD)测定表明,Pd-Cu原子簇粒度很小,平均直径小于3.0nm。X射线光电子能谱(XPS)表明,Pd和Cu均为零价态。Pd-Cu原子簇在异丙叉加氢反应中具有很高的活性和选择性。这些结果提供了令人信服的证据,即金属蒸气法可用于在聚合物孔穴内直接而温和地置入小的零价金属原子簇,而且这样制备的聚合物固载金属原子簇很适合于催化应用。 相似文献