MB2镁合金变形组织性能研究

为了探讨镁合金铸造组织在较低温度下变形时对组织性能的影响,采用现代冶金分析和测试方法,研究了MB2镁合金铸棒在不同变形温度和变形程度下组织演变过程和再结晶行为,并对各变形条件下试样进行拉伸实验.结果表明,通过挤压变形及动态再结晶,可以显著细化铸造MB2合金的晶粒,其尺寸可由铸态的约100 μm减少到5μm;随变形温度的升高,MB2合金的抗拉强度下降,达到一定温度后,趋于稳定;在相同的变形程度下,随着变形温度的升高,晶粒有长大的趋势.     

电场对Al-Mn-Mg合金的微结构和织构形成的影响

利用透射电子显微镜观察(TEM)和X射线衍射技术(ODFs分析),研究了电场对Al-Mn-Mg合金的回复和再结晶组织演变、再结晶织构的形成和发展的影响.结果表明,电场对再结晶的影响其强度有一个门槛值(3～4 kV/cm),低于此值电场对该合金的再结晶没有明显的影响.强度为4 kV/cm的电场对再结晶形核的影响较大,可抑制Al-Mn-Mg合金的回复和再结晶,促进再结晶立方织构的形成.其主要原因是电场降低了各取向的形变储能,推迟了再结晶进程,抑制储存能小的取向晶核的形成和长大,促进储存能大的S取向晶粒向立方织构择优生长.     

Microstructures and mechanical properties of Mg-Ce-Zn-Zr wrought alloy

Microstructures and mechanical properties of Mg-2.0 ?-0.7 % Zn-0.7% Zr alloy were studied. The results of scanning electron microscopy show that Mg12 Ce phase mainly distributes at the grain boundaries. The fine Mg12 Ce phase can apparently elevate recrystallization temperature by preventing the grain boundary migration. No dynamic recrystallization occurs during the hot-extrusion. The mechanical properties of as extruded specimens are σb=278.5MPa, δ=12.0%, while those of the specimens annealed at 250℃ for 100 h are σb=272.6 MPa, δ=11.3%, which indicate that the alloy has good mechanical properties at room temperature.     

Flow,Thermal and Microstructural Analysis during Cast Rolling of Steel in In‐line Strip Production Process

A mathematical model was developed to describe the in‐line hot rolling deformation and recrystallization behaviour of austenite after the solidification on a thin slab casting plant. The most significant features of the cast rolling process were taken into consideration: through‐thickness thermal gradients, inhomogeneous stress and strain, temperature discontinuity between the strip and the rolls. A HSLA (High Strength Low Alloy) steel has been chosen to perform the experiments of cast rolling. The characteristic constants ruling the microstructural evolution of that steel were computed and integrated into the computational module which manages the structural stress‐strain and strain rate computation. The developed approach is based on the Navier‐Stokes’ equations which were used to compute the speed field in the strip during the deformation. Then a model providing a proper constitutive equation was structured on the basis of the Yada's model based on evolution of the dislocation populations. The use of the Navier‐Stokes’ formalism allows to reach the resolution of the structural problem from the data measured easily during the industrial practice (i.e. speed of the rolled product at the entry and at the exit of a stand, the temperature of the rolled material). The validation of this computational approach was obtained by a comparison between the prior austenite grain size of the strip in different positions of the hot rolling process, as well as by a comparison between the computed deformation power and the measured one provided by the engines moving the rolls.     

6000系铝合金组织性能的研究进展

介绍了6000系铝合金组织性能的研究进展，尤其是时效析出过程及其合金元素的影响、提高合金烘烤硬化性的途径以及合金固溶处理再结晶织构与成形性的研究。对目前铝合金车身板在应用中存在的问题，提出了今后的研究方向。     

3104铝合金的流变应力行为与动态再结晶

对3104铝合金在350-500℃以0．005-0．1s^-1的形变速率进行压缩，真应变为50％，随后立即水冷。采用真应力一真应变曲线和TEM研究其高温压缩变形中的流变应力行为和它的动态再结晶过程。结果表明：3104铝合金为正应变速率敏感材料，具有稳态流变的特征。流变应力随着变形速率的增加而增加，随着变形温度的升高而降低。在低形变温度(350℃)和低形变速率(0．035s^-1)下，该合金发生动态再结晶。     

Production of very fine grained AISI 304 steel with high special grain boundary density by grain boundary engineering

Abstract

AISI 304 stainless steel was subjected to grain boundary engineering by applying cycles of calibre rolling and subsequent heat treatment. After three cycles the grain size started to decrease, and after the fourth cycle a very fine grained material having high fraction of special grain boundaries was produced. Due to the short heat treatment at 850°C, only partial recrystallization occurred after the first three cycles, which was proven by the large amount of low angle boundaries. The stored elastic strain energy helped the grain boundary movement and the formation of annealing twins in the fourth cycle, which caused the formation of very fine grained structure with a large amount of special grain boundaries.     

Evolution of microstructure and properties of internal nitride dispersion strengthened alloy before nitriding

Internal nitride dispersion strengthened superalloy is a new type of high performance superalloy for combustion chamber. The background and development of this alloy were firstly introduced. And then the microstructure and properties of NS163 which is a typical internal nitride dispersion strengthened alloy were investigated. The results show that the microstructure of NS163 is simple in the temperature range of 900??1250??, which is composed of austenite matrix and MC carbide. The recrystallization behavior of the cold- rolled sheet under the test condition was studied systematically. It is found that the solid solution temperature of the finished product should be 1200??, and after solid solution at 1200??, the sheet has 5 grade average grain size, excellent cold workability and low tensile strength at high temperature. The above results can help to optimize the microstructure of NS163 alloy sheet before nitriding and provide a basis for the evaluation of the strengthening effect of the alloy after internal nitriding.     

Preparation and Characterization of Taxifolin Form II by Antisolvent Recrystallization

To improve the aqueous solubility and dissolution rate of taxifolin, taxifolin form II was successfully prepared through antisolvent recrystallization, in which 1‐butyl‐3‐methylimidazolium tetrafluoroborate and dichloromethane were used as solvent and antisolvent, respectively. The properties of taxifolin form II were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X‐ray diffraction, differential scanning calorimetry, solid‐state NMR spectroscopy, the dissolving capability test, and the bioavailability test. The chemical structure of taxifolin form II was not changed, but its morphology and crystalline structure changed during the recrystallization process. Moreover, taxifolin form II showed higher solubility, faster dissolution rate, and better bioavailability than taxifolin form I.