乙基纤维素微胶囊红磷的制备及改性

目前微胶囊红磷大多采用原位聚合法制备,工艺较为复杂,且囊壳原料可能对环境造成危害.为解决这一问题,以可降解材料乙基纤维素(EC)为囊壳,采用相分离法在常温、中性条件下制备微胶囊红磷(MRP);为进一步增强MRP使用性能,添加正硅酸乙酯(TEOS)作为改性材料,在碱性条件下制备SiO_2凝胶/EC复合囊壳微胶囊红磷(SiMRP).对所得样品进行FTIR、形态及XPS分析,观察样品形态并计算包覆率;对样品进行热稳定性分析、吸湿率测定及安定性测试.实验结果表明:采用相分离法可对红磷实现有效包覆,囊壳包覆率为88.2%;EC囊壳提高了红磷的热稳定性,着火点温度较RP提升50℃; MRP 10日后吸湿率降至6.8%,摩擦感度降至34%;添加1 mL TEOS改性后的SiMPR样品包覆率达94.1%,热稳定性较MRP进一步增强,着火点温度较MRP提升90℃;SiMRP 10日后吸湿率降至4.5%,摩擦感度降至20%.     

九头狮子草红色素基膜的制备及动态响应特征

目的 制备了一种九头狮子草红色素基膜,即九头狮子草红色素结合马蹄淀粉的新型比色指示膜。同时利用紫外–可见吸收光谱和灰度平均值探究其动态响应特征。方法 从植物九头狮子草中提取九头狮子草红色素(HPJH),采用共混法将HPJH、马蹄淀粉、丙三醇共混制备比色指示膜。结果 引入九头狮子草红色素后,可以改变马蹄淀粉膜的抗氧化性。适量的九头狮子草红色素促进膜结构的均匀性,当添加质量分数为8%的九头狮子草红色素时,成膜效果最好,DPPH自由基清除率达到88.70%,膜颜色稳定性实验结束时ΔE值为1.649 7。以灰度平均值直观呈现比色指示膜在不同湿度条件下对三乙胺的响应情况,更具有说服力。结论 从植物九头狮子草中提取的HPJH可提高马蹄淀粉膜的指示效果,比色指示膜具有较强的抗氧化性,并对三乙胺具有颜色变化的响应性,在猪肉、鱼肉和莴笋新鲜度监测中具有动态响应特征。     

基于空间培养的植物图像处理方法

光照环境偏暗偏红,光照不均匀等会影响彩色图像的视觉效果。在比较几种现有的处理方法的基础上,提出了一种新的方法,该方法首先减小RGB彩色图像中偏红部分的红色分量值,然后转换到HSV色彩模型中,对亮度分量进行直方图均衡和Retinex 算法处理,最后转换回RGB颜色空间并进行Garmma校正。实验表明：该方法不仅能够减弱红色光源对图像质量的影响而且能够提高图像的亮度,同时也能较好地保留图像的细节。     

工业赤磷除铁工艺研究

采用双级逆流串联反应流程,对工业赤磷除铁工艺进行研究,讨论了影响除铁效果的主要因素,选最佳除工艺条件为：反应温度８８－９０℃,单级反应时间４．５－５．５ｈ,助剂Ｍ与工业赤磷的比例１：１２０,在此条件下,铁的去除率达到９８％以上,赤磷中含铁量降至０．００８％以下。     

南方红壤区不同类型植物篱治理崩岗效益研究

针对南方红壤区(粤东山区)崩岗侵蚀的特点,在工程治理的基础上,配置不同类型的植物篱进行崩岗快速整治。近3 a的试验结果表明,植物篱辅助治理崩岗,土壤渗透速率最大可提高5.1%,径流量最大可减少17%,土壤侵蚀模数最大可减少53.5%,并在改善土壤理化性状、提高植被覆盖度和增加生物多样性等方面均有良好的效果。     

南方红壤区马尾松林下水土流失与降雨量关系研究

为了更好地研究马尾松林水土流失规律,从水土流失主要控制因子——降雨因子出发,通过对红壤侵蚀区不同林下配置模式马尾松林径流试验小区2009—2011年的产流、产沙与降雨量的关系研究。得到如下结论：①各小区的产流量和产沙量均与降雨量呈显著性相关,回归模型主要以一元二次回归最优,个别小区以幂函数和对数函数最优,其中以马尾松地表裸露小区模拟方程可决系数最大;②各雨型在同一郁闭度条件下,除去郁闭度为0％的小区外,各小区基本满足乔＋地表裸露〉乔＋百喜草〉乔＋胡枝子,伴随着降雨量的增加,各小区的径流系数总体上呈增加的趋势,尤其在暴雨和大暴雨以上的雨型更加明显;③产沙方面,各雨型条件下,除去郁闭度为O％的小区和个别郁闭度为24％的小区外,基本上满足乔＋地表裸露〉乔＋胡枝子〉乔＋百喜草。     

MRT letter: Human bloodstains on antique aboriginal weapons: a guiding low-vacuum SEM study of erythrocytes in experimental samples on ethnographically documented biological raw materials

The aboriginal use of reed and bone as raw materials for knives and daggers, respectively, has been well-documented ethnographically in some geographical areas of Melanesia. Because of the significant role that these weapons played in inter- and intra-ethnic aggression, they can potentially have retained smears from the contact with human blood. To carry out a guiding low-vacuum scanning electron microscopy (SEM) study of specific interest to ethnography, the outsides of a fragment of stalk of giant cane (Arundo donax) and tibial diaphysis of domestic sheep (Ovis aries) were smeared with peripheral human blood. No biological specimen preparation was applied to the samples. After just over 1 month, bloodstain boundaries and their neighboring inner areas were examined via secondary electrons by a variable-pressure SEM (VP-SEM) working in low-vacuum mode. On both substrates, bloodstains exhibited micro-scales. No janocyte (erythrocyte negative replica) was observed in the examined areas. However, erythrocytes were seen crowded together as grain-shaped corpuscles in the smear on reed, and several hecatocytes (moon-like shaped erythrocytes) were evidenced in the smear on bone. The results of this study suggest that a VP-SEM working in low-vacuum mode can be used fruitfully to detect blood remains in medium-sized reed and bone antique aboriginal artifacts. This procedure can prospectively help to ethnographic museum curators and aboriginal-art surveyors as an easy guiding test in the valuation of antique traditional weapons prior to acquisition, when the real use of a piece has been claimed by the supplier.     

赣南红壤坡面不同措施径流泥沙及氮磷污染输出试验研究

选择赣南于都县左马小流域的典型红壤坡面,通过在研究区布设标准径流小区,进行了不同措施径流泥沙及氮磷污染输出的试验研究。通过径流小区的试验观测分析表明:水保林+水平竹节沟式综合水保措施实施初期,平均减流和减沙效果达到近73%,以植被增加地表覆盖度,以水平竹节沟坡面水保工程截短坡长,分段拦蓄径流泥沙,可实现保水保土目的;经果林+坡面工程或绿篱是坡地经济果业开发保持水土的重要措施,工程措施在初期发挥作用较绿篱更大;氮磷等面源污染随水土流失从坡面输出,试验区不同措施氮素输出多以径流携带为主,磷素输出均以泥沙携带为主;经果林+工程措施对径流携带氮磷拦截率较高,水保林+工程措施对泥沙携带氮磷的拦截率较高,都在75%以上。     

赤泥堆场固结排水方案的数值分析

流塑状赤泥含水率高、强度低,通过排水固结处理,可以增大其密度和强度,增强其堆场的稳定性,并减小堆场渗漏污染的可能性.采用固结有限元计算,对比分析分层堆载干赤泥、塑料排水板和真空预压3种方案的固结排水效果.由于流塑状赤泥渗透性低,堆载产生的超孔隙水压力难以消散.分析表明,堆载+塑料排水板联合方案下,赤泥堆场能够及时完成固结,有利于扩大库容.     

Properties and mechanism of red mud in preparation of ultra-lightweight sludge-red mud ceramics

New ultra-lightweight sludge-red mud ceramics (ULS-RMC) were prepared by red mud (RM), clay and dried sewage sludge (DSS). The properties and mechanism of RM in the preparation of ULS-RMC were discussed. The chemical components, thermal properties and mineral phases of RM were determined by energy dispersive X-ray (EDX), differential scanning calorimetry/thermal gravimetric analysis (DSC/TGA) and X-ray diffraction (XRD), respectively. Constant dosage of DSS to clay and different amounts of RM were utilized in the preparation of ULS-RMC. Physical properties test (bulk density, grain density, water absorption and expansion ratio), XRD and scanning electron microscopy (SEM) were employed to characterize the ULS-RMC. The results show that RM exhibits high hydroscopic property and good water-retention property, and bloating property and fluxing property of RM are caused by abound of gaseous components and flux, respectively. The two chemical properties are utilized to discuss the mineral phases and microstructures differences between ULSC and ULS-RMC.