水性氯化物介质中对甲基苯烷基硫醚萃取钯的研究

p-Methylphenylalkylsulfide of various alkyl chain length as extractant were synthesized and the extraction of palladium was examined in terms of equilibrium and kinetics. Distribution ratio of Pd was independent of alkyl chain length. For aqueous chloride media, there was a significant difference in distribution ratios for the solution of NaC1 and HC1. The results of loading test and the slope analysis suggest that the extractant and Pd (Ⅱ) form 2:1 complex. Furthermore, the extraction rate based on the volume of aqueous phase was obtained in a stirred vessel, and the rate equation was presented. Unfortunately, it was difficult to construct surfactant liquid membrane system by use of the present extractant.     

Recovery of gallium from phosphorus industry flue

The flue dust generated during electric furnace production of elemental phosphorus was investigated for the recovery of gallium. Then the flue dust was slurried with water and blended with concentrated sulfuric acid, followed by ageing. The gallium in the dust was thereby converted to soluble sulfate. The factors affecting the dust curing were investigated to understand the process chemistry of the pretreatment. The optimal curing conditions are determined as follows: the mass ratio of dust to water and acid is 1 : 1 : 1, ageing temperature and time are 200℃ and 2h, respectively. Almost all the gallium available to acid dissolution in the dust, about 90% gallium, can be extracted by leaching the cured dust at 80℃ for 1h.     

萃取法比色测定镀镍液中的铁杂质

1 方法要点 欲测定镀镍液中铁杂质的含量,传统的做法是以硝酸氧化铁为三价,在大量铵盐存在的条件下,加氨水使Fe3 沉淀为氢氧化铁,然后过滤,以盐酸溶解沉淀,用硫氰酸钠发色后比色测定铁[1].该法采用沉淀分离,操作繁琐、费时,准确度稍差.     

含酚废水处理技术的研究现状及发展趋势

本文综述了含酚废水处理技术的现状及其发展。介绍了溶剂萃取法、高级氧化技术、生化处理技术、膜分离技术在含酚废水处理中的研究及应用，分析各种技术的特点和存在的问题及应用前景。并探讨了含酚废水处理技术的发展趋势。     

钽、铌资源现状及其分离方法研究进展

概述了铌钽资源的分布状况、基本特征,对钽、铌的几种分离方法进行了介绍,重点介绍了萃取法的研究情况.     

N,N-二甲基-3-氧杂-戊酰胺酸与Np(Ⅳ),Pu(Ⅳ)配合物稳定常数的测定

应用溶剂萃取法研究了N，N-二甲基-3-氧杂-戊酰胺酸(DOGA)与Np(Ⅳ)，Pu(Ⅳ)的配位行为。研究结果表明，DOGA与Np(Ⅳ)，Pu(Ⅳ)在25℃可以形成比较稳定的配合物，配合物的逐级累积稳定常数分别为：Pu(DOGA)3^ ：1gβ1=6．52，1gβ2=9．14，1gβ3=15．77；Np(DOGA)3^ ：1gβ1=6．95，1gβ2=10．435，1gβ3=14．93。     

当归中藁本内酯的提取、分离与结构鉴定

运用超临界流体萃取法、水蒸气蒸馏法和有机溶剂提取法提取当归挥发油，运用硅胶柱分离纯化其主要成分藁本内酯并通过核磁共振进行结构鉴定、结果表明，超临界萃取法可以更好地提取当归挥发油，通过硅胶柱分离最终可得到纯度大于97％的藁本内酯，且为Z-ligustilide。     

黄酮提取工艺研究进展

黄酮类化合物是一类活性物质，并具有特殊的保健及疗效功能。本文阐述了黄酮的提取方法，包括热水提取法、碱液提取法、丙酮提取法、乙醇浸提法、微波萃取法、超声波法、酶解法、大孔树脂吸附法、超滤法等方法，从而为黄酮类化合物在各行业的应用开辟了一条可靠的途径。     

从废合金棒中回收钴镍的研究

为了从废合金棒中回收钴、镍,确定了最佳的工艺条件及工艺流程,探讨了钴镍回收与分离的方法,采用溶剂萃取法将钴镍分离,收到好的效果。     

萃取法分离柠檬酸的研究进展

柠檬酸是世界上产量最大发酵产品之一,是一种重要的有机酸。本文较全面地总结了近年来液-液萃取法和液膜萃取法分离纯化柠檬酸的原理和优缺点,详细讨论了这两种体系的发展现状况以及亟待解决的问题,这两种方法均具有污染小、萃取率高、成本低等优点,但是由于发酵液中含有蛋白质、多糖等乳化剂,使得这两种均有易乳化的缺点,并且液膜萃取法操作复杂。基于这两种方法的不足之处,提出了将离子液体运用到柠檬酸的萃取体系中,具有很大的发展空间,既保证了萃取法本身的优势,又克服了易乳化的缺点,同时离子液体可以循环使用,能源效率高,分离成本低。