Synthesis,characterization and properties of functionalized styrene–maleimide copolymers

New functionalized styrene–maleimide copolymers were prepared by free radical copolymerization of styrene (St) and N‐4‐carboxybutylmaleimide (NBMI) in chloroform, using 2,2′‐azobisisobutyronitrile (AIBN) as initiator. Monomer and copolymer characterization was carried out by ¹H‐ and ¹³C‐NMR. Copolymer composition was determined by elemental analysis and Fourier‐transform infrared (FTIR) spectroscopy. The glass transition temperature (from DSC) and the thermogravimetric analysis (TGA) of the copolymers were consistent with the thermal behavior and stability observed for alternating St–maleimide copolymers. St–NBMI copolymers crosslinked with divinylbenzene (DVB) were also synthesized and their cation exchange properties evaluated in order to assess the capacity of the new copolymers to bind metallic ions. Copyright © 2005 Society of Chemical Industry     

时滞系统控制问题块脉冲算子解的收敛性

本文给出了一种基于块脉冲算子的离散逼近格式.应用这种逼近格式,可以获得时滞非 线性最优控制问题的块脉冲级数解.本文证明了这种块脉冲级数解将收敛于这类问题的精 确解,并具有一阶收敛速度.     

火烧油层技术在庙5块低渗透稠油油藏中的应用

方法在物理模拟的基础上，利用数值模拟及油藏工程方法，对影响火烧油层的技术参数进行了优选研究，并对影响火驱成败的油藏地质参数、注气参数进行了分析。目的寻找适合庙５块低渗透稠油油藏的开采方法。结果提出了庙５块火驱的最佳开采方式、点火参数及注气参数；庙５块火驱生产后，平均单井日产液由０１ｔ上升到５６ｔ，平均单井日产油由０１ｔ上升到３５ｔ，生产２６ｄ后由于压风机供风不足被迫停止火驱注气；从数模结果看：火驱最终采收率可达３９８％。结论火烧油层是一种潜力很大的稠油开采方法，但其物理、化学反应机理复杂，火烧前缘难以控制；庙５块火驱初期虽然见到了一定的生产效果，但没有取得经济效益     

NUMERICAL MODEL FOR DYNAMIC SIMULATION OF TRAFFIC FLOW

ＮＵＭＥＲＩＣＡＬＭＯＤＥＬＦＯＲＤＹＮＡＭＩＣＳＩＭＵＬＡＴＩＯＮＯＦＴＲＡＦＦＩＣＦＬＯＷＷｕＺｈｅｎｇ；ＺｅｎｇＬｉ－ｎｏｎｇ（ＤｅｐａｒｔｍｅｎｔＡｐｐｌｉｅｄＭｅｃｈａｎｉｃｓ，ＦｕｄａｎＵｎｉｖｅｒｓｉｔｙ，Ｓｈａｇｈａｉ２００４３３，Ｐ...     

The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

胜利油区厚层底水断块油藏水平井经济技术政策界限

厚层底水断块油藏高含水期水平井开发效果既受剩余油富集区大小、油层厚度、水平井水平段长度、水平井在平面上和纵向上位置以及生产压差的影响，更受油价的制约。因此，通过胜利油区实际资料统计分析、数值模拟和解析法以及经济评价综合研究，提出了在当前油价和技术条件下，这类油藏水平井地质设计和生产控制的经济技术政策界限，即水平井平面位置应避开老井水锥半径20m以上；水平段垂向位置应为距油水界面0．7倍的油层厚度；水平段长度一般为200～250m；油层厚度应大于或等于8m；初期生产压差一般控制为0．6～1．OMPa；对于埋藏深度为1500m的油藏，油价从35美元／bb1升到40美元美元／bb1时，单井经济极限采油量从7101t降到6105t。     

Reconfiguration Aspects and a Reconfigurable Outer Block Interleaver for 3G Applications

Reconfiguration concept represents reconfigurable functionalities of the radio interface for mobile radio systems. Particularly for the physical layer, some possible reconfigurable architectures can be identified. We focus on outer interleaving for turbo codes, which can improve their performance in flat Rayleigh fading environment. The larger the number of columns in the outer interleaver, the better is the performance, but with the penalty of more complexity and delay. Furthermore, an incorrect choice of the number of columns can increase the bit and frame error rates. Therefore, it would be advantageous to reconfigure the outer interleaver in different operating environments with the optimum number of columns. Using two different data frame lengths, in this contribution simulation results are presented for the four possible outer block interleaver configurations specified for the 3GPP mobile standard in the case of flat Rayleigh fading channel. It is shown that different operating environments require an optimum number of columns in terms of bit error rate and frame error rate performance. Finally, frame fade duration is considered and the effect of the product of the Doppler frequency with the frame duration on the performance for the four different 3GPP outer block interleaver configurations is discussed. Costas Chaikalis was born in Athens, Greece, on March 7, 1973. He received the B.Sc. degree in electrical engineering in 1995 from Technological Educational Institute of Lamia, Greece. He also received the M.Sc. and Ph.D. degrees from Department of Electronics and Telecommunications, University of Bradford, Bradford, UK in 1999 and 2003, respectively. During his doctoral studies he worked as a Research Assistant for Mobile Virtual Center of Excellence (Mobile VCE), Terminals Group, UK. Since 2003, he is a lecturer in the Department of Electrical Engineering, Technological Educational Institute of Lamia, Greece. His research interests are in all areas of mobile communications but especially in forward error correction coding, reconfigurable (software radio) architectures, cross layer architectures and DSP applications.     

Water-soluble copolymers: 22. Copolymers of acrylamide with 2-acrylamido-2-methylpropanedimethylammonium chloride: Aqueous solution properties of a polycation

The viscometric, turbidimetric and potentiometric properties of copolymers of acrylamide (AM) with 2-acrylamido-2-methylpropanedimethylammonium chloride (AMPDAC) were studied in aqueous solutions. The AMPDAC polymers exhibit poor salt tolerance and large, negative viscosity/temperature coefficients. Furthermore, the polymers were found to be sensitive to changes in pH. The AMPDAC polymers undergo phase separation in the presence of dianions as a function of temperature and AMPDAC composition.     

阳极炭块压降测试的方法与分析

本文通过阐述新的阳极炭块测试方法，提出了降低阳极炭块Fe-C压降的思路，并分析了降低阳极炭块压降对我公司经济效益的影响，可供同行参考。