基于积分宽度法测量发光二极管结温方法的研究

本文提出了一种基于光谱积分宽度法来测量发光二极管(light emitting diode, LED)结温的新方法,并进行了理论分析和实验研究。本方法主要分为光谱数据采集、定标函数的测定和结温测量三个过程。首先,为了测量成本的降低和精度的提高而采用在正常工作电流下采集LED光谱数据,并通过采用不同温度下的光谱积分宽度与选定的某一基准状态下的值逐差可得到线性度达0.99以上的定标函数,并通过此定标函数可实时测定任意状态下的结温。其次,为了比较本方法测量结温的精确性,分别对单色和白光LED采用本方法和业界主流的正向电压法,通过自行设计的基于积分宽度法结温测量系统和美国Mentor Graphics公司的T3Ster型仪器的测量结果进行比较,两种方法测出的结温最大偏差为2.1℃,在可接受的误差范围内。实验结果表明积分宽度法测结温具有高效便捷且低成本的的特点,具有一定的应用前景。     

风电调频补偿水锤效应的频率特性分析

水轮机在云南电网中占比很大,为了解决水轮机的水锤效应带来的功率反调现象,提出了一种考虑风电调频特性补偿水锤效应的分析方法。首先,建立了含风、水、网、荷的简单系统数学模型。其次,使用直流潮流法得到水轮机及其调频策略、风机及其调频策略所对应的代数微分方程和系统网络方程。并在此基础上进行线性化处理,推导出负荷扰动时水轮机和风机并网节点频率响应的频域解析式。根据解析式分析调频控制参数等对系统频率的影响。最后,通过以双机系统及实际电网的仿真分析对风机补偿水轮机水锤效应的有效性和可行性进行了验证。     

In Situ Topochemical Transformation of ZnIn2S4 for Efficient Photocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran

Photocatalytic selective oxidation of 5-hydroxymethylfurfural (HMF) coupled H₂ production offers a promising approach to producing valuable chemicals. Herein, an efficient in situ topological transformation tactic is developed for producing porous O-doped ZnIn₂S₄ nanosheets for HMF oxidation cooperative with H₂ evolution. Aberration-corrected high-angle annular dark-field scanning TEM images show that the hierarchical porous O-ZIS-120 possesses abundant atomic scale edge steps and lattice defects, which is beneficial for electron accumulation and molecule adsorption. The optimal catalyst (O-ZIS-120) exhibits remarkable performance with 2,5-diformylfuran (DFF) yields of 1624 µmol h⁻¹ g⁻¹ and the selectivity of >97%, simultaneously with the H₂ evolution rate of 1522 µmol h⁻¹ g⁻¹. Mechanistic investigations through theoretical calculations show that O in the O-ZIS-120 lattice can reduce the oxidation energy barrier of hydroxyl groups of HMF. In situ attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) results reveal that DFF^* (C₄H₂(CHO)₂O^*) intermediate has a weak interaction with O-ZIS-120 and desorb as the final product. This study elucidates the topotactic structural transitions of 2D materials simultaneously with electronic structure modulation for efficient photocatalytic DFF production.     

An Efficient One-Arrow-Two-Hawks Strategy Achieves High Efficiency and Stable Batch Variance for Benzodifuran-based Polymer Solar Cells

With the development of organic solar cells (OSCs), the high-performance and stable batch variance are becoming a new challenge for designing polymer donors. To obtain high photovoltaic performance, adopting polymers with high molecular weight as donors is an ordinary strategy. However, the high molecular weight need to subtly control the reaction time and state, inevitably caused batch-to-batch variations. Herein, a strategy of steric effect is applied to benzodifuran (BDF)-based polymer by introducing different positions of Cl atom, producing two polymers PBDFCl-1 and PBDFCl-2. The more twisted side chains conformation not only achieve the control of moderate molecular weight for PBDFCl-2, but also easily form molecular stacking through adopting BDF unit and maintain sufficient polymeric crystallinity. Due to the optimized stacking mode and good blend miscibility, PBDFCl-2-based device exhibitsa more elegant power conversion efficiency (PCE) of 17.00% compared to PBDFCl-1-based device. This is the highest efficiency record for BDF-based binary OSCs. Meanwhile, the PCE device variation of the different molecular weights for PBDFCl-2 is little, indicating the reduction of the batch variation. Therefore, smartly using steric effect of Cl atom in strong crystalline BDF unit can form efficient molecular stacking regulations and realize the coordination of high-performance and stable batch variance.     

Proximity-Induced Fully Ferromagnetic Order with Eightfold Magnetic Anisotropy in Heavy Transition Metal Oxide CaRuO3

Ferromagnetic materials with a strong spin-orbit coupling (SOC) have attracted much attention in recent years because of their exotic properties and potential applications in energy-efficient spintronics. However, such materials are scarce in nature. Here, a proximity-induced paramagnetic to ferromagnetic transition for the heavy transition metal oxide CaRuO₃ in (001)-(LaMnO₃/CaRuO₃) superlattices is reported. Anomalous Hall effect is observed in the temperature range up to 180 K. Maximal anomalous Hall conductivity and anomalous Hall angle are as large as ∼15 Ω⁻¹ cm⁻¹ and ∼0.93%, respectively, by one to two orders of magnitude larger than those of the typical 3d ferromagnetic oxides such as La_0.67Sr_0.33MnO₃. Density functional theory calculations indicate the existence of avoid band crossings in the electronic band structure of the ferromagnetic CRO layer, which enhances Berry curvature thus strong anomalous Hall effects. Further evidences from polarized neutron reflectometry show that the CaRuO₃ layers are in a fully ferromagnetic state (∼0.8 μ_B/Ru), in sharp contrast to the proximity-induced canted antiferromagnetic state in 5d oxides SrIrO₃ and CaIrO₃ (∼0.1 μ_B/Ir). More than that, the magnetic anisotropy of the (001)-(LaMnO₃/CaRuO₃) superlattices is eightfold symmetric, showing potential applications in the technology of multistate data storage.     

考虑负效应的垃圾回收两级选址-路径模型与算法

针对生活垃圾中转站和焚烧站的选址-路径问题（LRP）,考虑经济目标和垃圾设施的负面影响,设计了与风向和距离有关的负效应分段函数,构建了两级多目标选址-路径（2E-MOLRP）模型,并提出了鲸鱼优化算法（WOA）和模拟退火（SA）算法结合的非支配算法WOA-SA。首先,结合随机方法与Clarke和Wright(CW)节约算法优化初始种群;其次,采用非线性动态惯性权重系数调整收敛速度;然后,设计WOA-SA的并行结构来增强全局搜索能力;最后,使用非支配排序法得到帕累托解集。对Prins和Barreto等35个基准案例以及天津市模拟案例进行分析。结果表明,WOA-SA可以找到20个基准案例的已知最优解（BKS）,且对Prins和Barreto案例的求解结果与BSK差距的平均值分别为0.37%和0.08%,具有很好的收敛性和稳定性。将所提模型和算法应用于实例,给决策者提供了三种不同方案的负效应值及经济成本的方案,以支持不同偏好决策者选择,从而减少垃圾回收物流成本和设施对环境的负面影响。     

Simulation and analysis of edge ghosting for microcapsule e-paper based on particle dynamics and light scattering model

Electronic paper (e-paper) is a reflective display technology with unique advantages, such as bistability, low-power consumption, and high ambient contrast ratio. These features make e-paper a promising candidate for future Internet of Things applications. Among different technologies of e-paper, electrophoretic display (EPD) is the most successful one for commercialization. However, the edge ghosting (also known as the fringing effect) still limits the performance of EPD. Herein, we established a model of particle dynamics of electrophoresis, simulated the edge ghosting of microcapsule EPD, analyzed the edge ghosting effect, and revealed the relationship between thicknesses, dielectric constants of the back binder layer, and the edge ghosting. Two EPD panels with different thicknesses of back binder layer were demonstrated, which verifies the accuracy of this simulation model. With the proposed model, many device mechanisms and product issues can be analyzed and illustrated, which is supposed to guide the researchers in optimizing the device structure design of EPD.     

Novel,liquid crystal formula to overcome LTPS LCD image sticking without adjustment of gamma code,optical, VHR and IS evaluation

In this article, novel n-FFS liquid crystal material from Slichem was used in order to elevate the anti-backlight long aging effect; a trace amount of free radical trap HALS-like additive was added, the principle of which can be expressed via Denisov cycle, confirmed by measuring the temporal VHR changes in test cells; three different resolution (FHD ~ QHD) models paired with N19 and N21 were selected for testing by comparing the actual panel. It is verified that the optimized material greatly improves the image sticking performance of the panel and keeping optical performance.     

基于反投影注意力网络的遥感影像超分辨率重建

近年来, 在诸如环境监测等一系列工作中, 遥感影像得到了广泛应用. 然而, 目前卫星传感器观测到的影像往往分辨率较低, 很难满足深入研究的需要. 超分辨率(SR)目的是提高图像分辨率, 同时提供更精细的空间细节, 完美地弥补了卫星图像的弱点. 因此, 本文提出了一种反投影注意力网络(back-projection attention network, BPAN)用于遥感图像的超分辨率重建, 该网络由反投影网络和初始残差注意块两部分组成. 在反投影网络中, 通过迭代误差反馈机制计算上下投影误差指导图像重建; 在初始残差注意块中, 引入初始模块融合局部多级特征为重建详细的纹理提供更丰富的信息, 以注意模块自适应地学习不同空间区域的重要性, 促进高频信息的恢复. 为了评价该方法的有效性, 在AID数据集上进行了大量的实验, 结果表明, 本文的网络模型提升了传统深度网络的重建性能, 且在视觉效果和客观指标方面有明显提升.     

Exploring the tidal effect of urban business district with large-scale human mobility data

Business districts are urban areas that have various functions for gathering people, such as work, consumption, leisure and entertainment. Due to the dynamic nature of business activities, there exists significant tidal effect on the boundary and functionality of business districts. Indeed, effectively analyzing the tidal patterns of business districts can benefit the economic and social development of a city. However, with the implicit and complex nature of business district evolution, it is non-trivial for existing works to support the fine-grained and timely analysis on the tidal effect of business districts. To this end, we propose a data-driven and multi-dimensional framework for dynamic business district analysis. Specifically, we use the large-scale human trajectory data in urban areas to dynamically detect and forecast the boundary changes of business districts in different time periods. Then, we detect and forecast the functional changes in business districts. Experimental results on real-world trajectory data clearly demonstrate the effectiveness of our framework on detecting and predicting the boundary and functionality change of business districts. Moreover, the analysis on practical business districts shows that our method can discover meaningful patterns and provide interesting insights into the dynamics of business districts. For example, the major functions of business districts will significantly change in different time periods in a day and the rate and magnitude of boundaries varies with the functional distribution of business districts.