复合高稳定性固态二氧化氯释放剂的研究

目前中国市场上固态二氧化氯释放剂技术不成熟，产品多为二元包装或伪一元包装，给使用和储存带来很多不便。为解决这个问题，采取亚氯酸钠为释放剂主成分，辅以复合无机盐活化剂，借助小丸包衣技术，制备了一元化、高纯、高稳定性固态二氧化氯释放剂。     

基于小波变换的鼓泡塔内气液两相湍流多尺度结构分析

在φ476 mm的鼓泡塔内,以0.1～1 m·s-1的高气速,利用Pavlov管测量塔内不同位置液相轴向速度,通过能谱分析发现,在空间区域上采用该方法测得的速度时间序列可分为含能尺度区和惯性子区,再借助7尺度Daubechie2小波分析的方法实现湍流量化指标如局部间歇性测度、间歇指数、尺度能量、涡旋尺寸等的评估.实验结果表明,高频和低频尺度下LIM峰分布表明湍流相干结构和大涡旋与小涡旋串级结构的存在.各小波尺度能量的比较说明,气速增大,高频和低频尺度的能量均增大,其中,含能尺度区间的能量占总能量的97%以上.不同尺度涡旋尺寸的计算证实了接近于塔内径最大涡旋的存在.进一步分析表明,塔壁处的涡旋尺寸约为塔中心处的2倍,含能尺度区间的涡旋尺寸为0.03～0.35 m,气速对涡旋尺寸的影响可以忽略.湍流量化指标的分析有助于揭示湍流中的隐含结构以及高气速下鼓泡塔内湍流流动规律.     

尿素包合法分离橡胶籽油中的多价不饱和脂肪酸

用尿素包合法从橡胶籽油混合脂肪酸中分离多价不饱和脂肪酸 ,用正交设计实验法对分离工艺进行研究 ,其最佳分离条件是 :原料配比为m(混合脂肪酸 )∶m(尿素 )∶m(乙醇 ) =1 0 0∶1 5∶1 8,回流时间 12 0min。经一次尿素包合法分离即可得到多价不饱和脂肪酸质量分数大于90 %的产品 ,实验收率大于 35 %     

一种耐超高温、耐酸聚合物的制备及性能测试

摘要：为解决常规聚合物无法满足超高温深井酸化压裂的技术要求，本文分别以丙烯酰胺（AM） 甲基丙烯酰氧乙基三甲基氯化铵（DMC）、AM DMC SMA（十八烷基甲基丙烯酸酯）为原料，通过自由基聚合制备出两种耐酸聚合物SY-1和SY-2，并对其结构进行表征及性能测试。结果表明：SY-2红外谱图中720 cm-1为—(CH2)n—的弯曲振动吸收峰，单体成功接枝到聚丙烯酰胺分子链上；热重分析表明，SY-1升温至600℃失重比为98%，SY-2失重比86%，热稳定性得到改善；质量分数为20%盐酸中，SY-2质量分数0.8%：180℃，170s-1流变性能测试，SY-2剪切终点黏度56mPa?s，90℃、120℃、150℃剪切1h，黏度为83.6mPa?s、43.5mPa?s、27.8mPa?s，剪切稳定性分别为85.66%、74.45%、52.01%； 180℃、3MPa条件下，静态酸岩反应速率为8.94?10-5(g/cm2?s)，较常规SY-1反应速率1.69?10-4(g/cm2?s)减小一个量级。且与缓蚀剂、铁离子稳定剂配伍性良好，克服高温酸化压裂技术的应用瓶颈。     

Photoelastic Studies on Rubber-to-Rubber Joints

Photoelasticity is a method which yields information on the principal stress difference and orientation in a composite structure. Various problems associated with this technique, especially those concerning the fundamental relationship between the fringe order and the stress, have yet to be investigated. A few studies of this relationship in a universal stress state have been presented, particularly in the field of rubber-to-metal and rubber-to-fabric composites, but no evaluations have so far been made in the field of rubber-to-rubber joints. Applying the photoelastic method, we report our observations on the stress distribution in a natural rubber to natural rubber joint subjected to uniaxial tension. A comparison between the results of experimental photoelastic studies and the corresponding computer modelling has been illustrated. The theoretical displacement pattern of the angular joints of bi-rubber part has also been highlighted.     

超高分子相对质量部分水解聚丙烯酰胺合成研究

选择AM均聚后水解工艺路线,采用新型复配引发体系,合成作为油田驱油剂的超高相对分子质量聚丙烯酰胺(简称PAM).在所选高效的引发体系下,考察了主要聚合反应因素对产品平均分子相对质量的影响,确定了聚合工艺条件溶液的pH值为11～11.5,W(单体)为45%,W(引发剂)为70×10-6,W(链转移剂)为1.3×10-6.在优化的聚合条件下,合成了相对分子质量高达25×106,水解度在20%～30%可调,过滤比小于1.3的聚丙烯酰胺.     

高气速下鼓泡塔中气含率分布的测定

在内径476 mm的鼓泡塔内用压差法测定全塔平均气含率与表观气速的关系,进一步利用响应特性良好的双电导探针,考察了不同气速下局部气含率的分布规律。实验结果表明,利用探针法计算得到的全塔平均气含率值与压差法测定值平均误差仅为4.5%,表明探针法测量局部气含率的可靠性良好。实验还表明在高气速下,除分布板影响区外,局部气含率均类似抛物线型分布;随着气速增加,气含率分布趋于陡峭。以实验为依据,拟合了不同气速下(0.05~1.0 m/s)鼓泡塔中局部气含率的关联式,认为塔内局部气含率与径向位置、表观气速和塔径等因素有关。     

Studies on high-performance blended/multiblended cements and their durability characteristics

Number of blends were prepared by intergrinding clinker, gypsum, fly ash, calcined clay, microsilica and limestone in laboratory ball mill in varying percentages, and their physical properties such as fineness, consistency, setting time and compressive strength have been determined. The durability tests on selected compositions were also conducted by exposing the mortar cubes separately in 5% Na₂SO₄ and 5% NaCl solutions till the age of 90 and 180 days. The performance was observed by compressive strength development criteria after various length of exposure. Results have been discussed and found that the durability of blended cement is higher than the ordinary Portland cement.     

复合矿物功能掺合料对粉煤灰激活增强的研究

根据激发粉煤灰活性机理研制了一种复合矿物功能掺合料,针对其对粉煤灰活性激发增强效果进行了系统研究。结果表明,用Ⅱ级粉煤灰、复合矿物功能掺合料置代50%以上水泥配制的胶砂、普通混凝土和高性能混凝土的早期强度、后期强度均大幅度提高。其中强度等级C15-C100 的混凝土不仅单方可节约水泥 50%以上,而且其强度较单掺粉煤灰有显著提高,具有显著的经济和社会效益。     

Complete Elastic Tensor for Mullite (∼2.5Al2O3·SiO2) to High Temperatures Measured from Textured Fibers

Directionally solidified mullite fibers have been grown by the laser-heated, float-zone method from starting materials with a nominal composition of 3Al₂O₃·2SiO₂. The fibers used in this study have large single-crystal regions with composition 2.5Al₂O₃·SiO₂ and (001) fiber axis orientation. The complete elastic tensor of these samples has been determined by Brillouin spectroscopy at room temperature and elevated temperatures up to 1200°C. Isotropic moduli (bulk, shear, and Young's) have been calculated using the Voigt–Reuss–Hill averaging scheme. The room-temperature values obtained are K _VRH= 173.5 ± 6.9 GPa, G _VRH= 88.0 ± 3.5 GPa, E _VRH= 225.9 ± 9.0 GPa. All moduli show gradual, linear decreases with temperature. The temperature derivatives obtained for the equivalent, isotropic moduli are d K _VRH/d T =−17.5 ± 2.5 MPa/°C, d G _VRH/d T =−8.8 ± 1.4 MPa/°C, d E _VRH/d T =−22.6 ± 2.8 MPa/°C. Substantial differences between bulk properties calculated from the single–crystal measurements in this study and the properties reported in the literature for polycrystalline sintered mullite are identified, indicating the importance of factors such as microstructure, intergranular phases, and composition to the elasticity of mullite ceramics.