全文获取类型
收费全文 | 18141篇 |
免费 | 969篇 |
国内免费 | 432篇 |
专业分类
电工技术 | 422篇 |
综合类 | 972篇 |
化学工业 | 10937篇 |
金属工艺 | 641篇 |
机械仪表 | 275篇 |
建筑科学 | 468篇 |
矿业工程 | 247篇 |
能源动力 | 82篇 |
轻工业 | 1590篇 |
水利工程 | 50篇 |
石油天然气 | 735篇 |
武器工业 | 41篇 |
无线电 | 221篇 |
一般工业技术 | 2296篇 |
冶金工业 | 345篇 |
原子能技术 | 193篇 |
自动化技术 | 27篇 |
出版年
2024年 | 42篇 |
2023年 | 86篇 |
2022年 | 227篇 |
2021年 | 289篇 |
2020年 | 308篇 |
2019年 | 269篇 |
2018年 | 263篇 |
2017年 | 356篇 |
2016年 | 435篇 |
2015年 | 532篇 |
2014年 | 740篇 |
2013年 | 1003篇 |
2012年 | 1436篇 |
2011年 | 1274篇 |
2010年 | 1001篇 |
2009年 | 1075篇 |
2008年 | 931篇 |
2007年 | 1210篇 |
2006年 | 1293篇 |
2005年 | 1012篇 |
2004年 | 870篇 |
2003年 | 827篇 |
2002年 | 702篇 |
2001年 | 612篇 |
2000年 | 544篇 |
1999年 | 506篇 |
1998年 | 410篇 |
1997年 | 261篇 |
1996年 | 224篇 |
1995年 | 190篇 |
1994年 | 155篇 |
1993年 | 125篇 |
1992年 | 117篇 |
1991年 | 57篇 |
1990年 | 38篇 |
1989年 | 33篇 |
1988年 | 16篇 |
1987年 | 15篇 |
1986年 | 12篇 |
1985年 | 19篇 |
1984年 | 10篇 |
1983年 | 9篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1959年 | 1篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
101.
If a low weight percentage of crude fine fillers can improve properties of polymer materials directly without complicated chemical treatment process involved, it will be significant for many industrial applications. Our previous study indicated that a kind of Cancun natural sand could be an effective filler material for polymer composites. In this current work, the epoxy composites reinforced by this kind of natural sand particles were prepared and thermal and mechanical properties of the composites containing up to 5 wt % of the sand particles were characterized. Results showed that the highest flexural strength appears in the epoxy composite containing 1 wt % sand particles. A damage model was used to interpret the flexural properties, which showed an acceptable agreement with the experimental results. The glass transition temperature, high temperature storage modulus, and dimensional stability of the sand/epoxy composites monotonically increased with the addition of the sand particles. The sand particle/epoxy composites also displayed a noticeable enhancement in thermal conductivity. Theoretical analysis showed that in addition to conduction, other heat transport mechanisms played roles in the improved heat transmission through the composites. As a natural porous micron-scale material, Cancun sand has the potential for applications in cost-effective composites with enhanced mechanical and thermal properties. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
102.
Polymeric oxidants in the bead form that were macroporous styrene/divinylbenzene copolymers containing N‐chlorosulfonamide functional groups (in sodium or hydrogen form) or N‐bromosulfonamide groups (in sodium form) were synthesized and investigated to determine their oxidizing powers. The redox potentials of the N‐chlorosulfonamide/sulfonamide and N‐bromosulfonamide/sulfonamide systems were determined by potentiometric studies at different pH values with aqueous solutions of Na2SO3, KCN, and KSCN as reducers. The formal redox potentials of the N‐chlorosulfonamide copolymers were 0.79, 0.44, and ?0.12 V at pH's of 1.8, 8.45, and 13.6, respectively. The formal redox potential of the N‐bromosulfonamide copolymer was about 100 mV higher in comparable conditions and in solutions over pH = 5 (e.g., 0.56 V at pH = 8.56). The comparatively higher oxidizing power of the N‐bromosulfonamide copolymer was particularly evident in a strong alkaline medium (in which the N‐chlorosulfonamide copolymer was not reactive). In contrast, the N‐chlorosulfonamide copolymer showed strong oxidative properties in acidic media (in which the N‐bromosulfonamide copolymer decomposed itself). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
103.
In the present study, the transition of a polymeric material from the linear to the nonlinear viscoelastic behavior and the determination of the nonlinearity stress threshold variation with time and temperature are investigated. For this purpose a systematic experimental program consisted of thermal and mechanical characterization of certain polymeric material followed by isothermal creep tests at different stress levels and temperatures was conducted. Through isochronal curves that occurred from creep tests, the nonlinearity threshold dependence on both time and temperature is presented. The reported results provide information that is critical for the design and development of polymer structures and components. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
104.
采用极限氧指数法、热重分析和烟密度测试法研究了氯氧镁水泥在不饱和树脂(UP)中的阻燃作用和阻燃机理。研究表明经偶联剂处理后的氯氧镁水泥对UP具有良好的阻燃抑烟效果,并通过增加UP在高温下的热稳定性和降低热失重速率等机理发挥阻燃作用:氯氧镁水泥含量在40%内对UP的力学性能影响较小,是一种新型的无机添加型阻燃剂。 相似文献
105.
106.
107.
3251系促进剂D/取代双氰胺/CTBN-双酚A环氧树脂体系,树脂体系各组份互溶性好且溶于丙酮。可制备优质均匀的预浸料,该体系能满足中温固化成型工艺要求,用E玻璃布增强的复合材料具有良好的力学性能及湿热老化性能。 相似文献
108.
以三氧六环为交联剂的COPNA树脂的合成与性能研究 总被引:4,自引:0,他引:4
以三氧六环为交联剂,萘、萘酚、蒽及其混合物为单体,可在对甲苯磺酸或三氯乙醚催化下,在80~160℃下反应得到未交联的缩合多核芳香烃树脂。对聚合反应机理作了一定的研究,并提出了聚合机理。以萘酚或萘为单体的树脂的交联较为困难,而在萘中加入蒽,不但可大大提高反应速率,也可使所得树脂的交联变得容易。交联后树脂在氮气中的热降解起始温度在400℃左右。 相似文献
109.
介绍了用常温法生产微粒状 PVB 树脂的新工艺,从而简化了传统法低温生产 PVB 树脂的工艺和设备,减少了设备投资,节省了动力和能源消耗,降低了生产成本。 相似文献
110.
通过对中温固化环氧树脂DSC、扭辫分析、凝胶时间、粘度、力学性能的测定,固化反应活化能的计算,研究了在贮存树脂的过程中环境湿度对树脂的固化反应和性能的影响。 相似文献