低熔点Cu-P基中间合金及其变质效果

利用差示扫描量热仪(DSC)、扫描电子显微镜(SEM)和金相显微镜等手段对Cu-P基中间合金进行了研究。结果表明，在二元共晶Cu-P中间合金中加入一定量的Sn可制成低熔点的Cu-16Sn-8P中间合金；在此基础上研制出一种熔点为630℃左右的低熔点的多元Cu-P基中间合金。与Cu-P中间合金相比，该低熔点多元Cu-P基中间合金对过共晶AI-24Si合金具有更好的变质效果。同时，该中间合金对ZL109合金也具有良好的变质效果。     

压铸镁合金在曲轴箱上应用的材料替代研究

以摩托车曲轴箱为例,对铸造镁合金在摩托车上应用中的材料替代技术和方法进行了系统研究.研究结果表明,通过铸件服役工况及失效形式分析,铸件服役模型建立及服役状态分析,以铸件本体材料使用性能为基础的结构再设计,铸件生产工艺虚拟现实及优化,镁合金样件生产及使用性能检测等步骤,可以合理实现镁合金铸件在摩托车上应用中的材料替代.     

ICP－AES法测定Pt－Ni和Pd－Ni合金中的镍及杂质元素

采用溶液试样的ＩＣｐ－ＡＥＳ法，测定Ｐｔ－Ｎｉ、Ｐｄ－Ｎｉ合金中的Ｎｉ和１６个杂质元素。标准中不配入Ｐｔ、Ｐｄ。其对待测元素的影响是用等效浓度差减法校正；Ｎｉ对部分待测元素的影响是用扣除其空白强度的方法校正。     

TiAl基合金与陶瓷界面反应的研究

借助电子探针微区分析仪、维氏显微硬度计、光学和电子显微镜对TiAl合金与Al2O3,ZrO2以及经CaO稳定的ZrO23种陶瓷型壳的界面反应进行了研究分析。结果表明，这3种材料的化学稳定性依次升高，而经CaO稳定的ZrO2型壳与TiAl反应层的厚度仅为50μm,故可望用作钛铝合金精密铸造型壳面层材料。     

Corrosion rate of magnesium and its alloys in buffered chloride solutions

The effect of the buffer capacity of test solution on the corrosion rate of cast pure (>99.95 mass%) and high-purity (>99.9999 mass%) magnesium, and AZ31 and AZ91E has been studied. Their corrosion rates were measured gravimetrically in a pH 6.5 and a pH 9 borate buffer including chloride ions, and in a conventional chloride solution. Except for the AZ91E in the pH 6.5, the corrosion rates of all the examined materials depended solely on the pH of the test solution, although the materials had a variety of purity and alloying elements. Higher buffer capacity probably masked the detrimental effect of the “cathodic impurities”. The corrosion rates measured in the buffers were considered as giving the resistivity of the passive film to anodic reactions. The high-purity magnesium had a fair corrosion resistance even in conventional chloride solution.     

铝合金车轮铸造模具CAD/CAE技术的应用

随着计算机应用技术的发展，CAD/CAE技术已广泛应用于各行各业的设计，主要介绍了铝合金年轮铸造模具上应用CAD/CAE技术的成效。     

钛合金冷坩埚电磁约束铸造工艺研究

针对液态下化学性质相对活泼的钛合金,采用冷坩埚技术对电磁约束铸造工艺过程进行了试验研究,考察了工艺条件对成形坯件表面质量和内部组织的影响.结果表明:试样抽拉速度变化对表面质量和宏观组织的影响明显,加热功率虽然对组织变化影响不大,但对表面质量影响较为显著.通过优化工艺,可以获得既有较光滑铸造表面又具有一次定向凝固组织的钛合金铸件.讨论了铸造过程裂纹和组织缺陷的形成机理,获得到了表面光滑无裂纹,宏观组织为柱状晶的钛合金大尺寸圆坯.     

Evaluation of high Ni-Cr-Mo alloys for the construction of sulfur dioxide scrubber plants

Corrosion in wet lime/limestone systems used for flue gas desulfurization in thermal power plants is of great concern. The frequent variations in acidity and in chloride and fluoride ion concentrations experienced by such systems pose a serious threat to the materials of construction. Currently used materials mostly type 316L stainless steel often fail to meet their life expectancy. The present study evaluates the performance of advanced Ni- Cr- Mo alloys 59 and C- 276 in a simulated sulfur dioxide scrubber environment. Accelerated tests showed that high Ni- Cr- Mo alloys have little tendency to leach metal ions such as chromium, nickel, and molybdenum at different impressed potentials. Scanning electron microscopy was used to examine the morphology of pitting attack.     

Ag—AgI指示电极电位滴定法测定钯

研究了铂、钯、金、铂镀金、石墨及Ag—AgI指示电极,提出了一个用Ag～AgI指示电极(vs.SCE),碘化钾电位滴定钯的方法。该方法可应用于钯合金、氯化钯、钯催化剂中钯的测定。对于含钯60％和O.5％的物料,变异系数分别为0.5％和4％。     

耐蚀钛合金的发展与应用

由于工业纯钛难于适应化工、采油等苛刻环境应用，促进了耐蚀钛合金的发展。本文对耐蚀钛合金的设计理论与试验作了分析，并对近期开发的耐蚀钛合金作了介绍，展望了耐蚀钛合金的应用。