汽车密封型材低摩擦系数涂料的研制

在提高汽车门窗活动部件的密封性能上，国外厂家提出采用先进的低摩擦系数涂料以代替目前使用的静电植绒，此课题在国内尚属新的领域。本文介绍对此进行的研究情况及经试验取得的结果。     

Mechanical degradation of coating systems in high temperature cyclic oxidation

Cyclic oxidation tests were performed on a large variety of commercially available overlay coatings. The results of cyclic oxidation tests confirmed that the composition of the coating as well as the processing method of the coating can affect the life of the system. Coating life was determined by the time to coating penetration and initiation of substrate attack. As this work was part of a effort to evaluate the relative protectiveness of available coating systems for Industrial Gas Turbine applications at relatively high temperature, an extensive testing programme was undertaken. The different coatings were tested to visual failure. The results presented in this paper concentrate on the surface instability of the coating. Apart from usual oxidation of the coating an additional degradation mechanism was observed. A mechanical effect caused by the instability of the coating as a result of the difference in the thermal coefficient of expansion and mechanical properties between the substrate and coating. This effect, the so-called “rumpling” effect, resulted in a significant reduction in time to penetration and was in some systems the life controlling factor.     

磨损自补偿添加剂在成品油中的摩擦学效应

利用四球试验机考察了二聚酸－3－氯－2－羟基丙单酯（DAE）在4种成品油中的摩擦学性能。试验结果表明，DAE添加剂在L－HM68液压油和L－DAB100空压机油中具有良好的适应性，使其承载能力增强，摩擦系数降低及耐磨性增强；DAE在L－CKE涡轮蜗杆油中使耐磨性增强；DAE在L－CKC150齿轮油中虽使承载能力提高，减磨性增强，但有使耐磨性减小的趋势，说明DAE在不同的油中有不同的性能。     

高温润滑涂层设计的系统考虑

航天、航空、核能等尖端技术迫切要求使用耐高温润滑涂层，以保护金属构件的表面，增加发动机、推进器的工作效率和输出功率，８０年代国际摩擦学界根据工业和国防的需要将高温润滑涂层和耐磨材料定为摩擦学学科发展的重要研究方向之一。本文对高温润滑涂层设计中遇到的典型环境、涉及到的关键问题、未来发展的途径等问题作了阐述。     

两种不同界面结合强度碳/铝复合材料的内耗特性

本文研究了两种不同界面结合强度的碳/铝复合材料经不同次数加载热循环处理后的内耗值及内耗机制。弱界面结合的C/L2复合材料的内耗值变化主要由界面脱粘引起,而强界面结合的C/LD2复合材料的内耗值变化主要由位错运动所致。     

Tribological issues in reducing piston ring friction losses

In this paper improvement in fuel economy by reducing piston ring friction is studied and reduction of piston ring tension and the use of two-ring packages are found to be effective. However, these can be accompanied by adverse effects such as excessive wear and increasing oil consumption, and measures to overcome these problems are studied in detail.     

Effect of rare-earth doping on the electrical and photoelectrical properties of furazano [ 3,4-b] piperazine (FP) thin-film devices

Schottky diodes of rare-earth, praseodymium (Pr)-doped and samarium (Sm)-doped furazano [3,4-b] piperazine (FP), sandwiched between Al and indium-tin oxide (ITO) were made by a spin-coating technique. The diodes, in which doped FP behaves as a p-type organic semiconductor, exhibit rectification behaviour. The p-type semiconductivity and rectification properties of the devices improve with rare-earth doping. The electrical effects observed in these devices are explained in terms of the p-type semiconducting behaviour of the doped FP thin films and the formation of a blocking contact (Schottky barrier) with the Al electrode and ohmic contact with the ITO electrode. Various electrical parameters such as carrier mobility, position of Fermi level, free carrier concentration, trap density, trap level and conductivity of doped FP are calculated and discussed. It is found that the position of the Fermi level shifts toward the valence band on rare-earth doping; concentration of free carriers and carrier mobility increase on doping. From the capacitance-voltage (C-V measurements, various electrical parameters such as barrier height, density of ionized acceptor atoms and depletion layer width are calculated and discussed. From the action spectra and absorption spectra it is confirmed that the Al-doped FP interface forms a Schottky barrier and the ITO-doped FP interface shows ohmic contact. The photovoltaic measurement on the two devices reveals that the short circuit current, open circuit voltage, fill factor and power conversion efficiency increase on rare-earth doping.     

含硫氰基团化合物的摩擦学性能及其摩擦化学机理研究

以三烷基磷酸酯络合硫氰酸钙为模型化合物研究了含硫氰基团的络合物的摩擦学行为，发现它有高的承载能力，良好的抗磨减摩性。用俄歇能谱（ＡＥＳ）、Ｘ－射线衍射（ＸＲＤ）、扫描电镜（ＳＥＭ）及Ｘ－射线能谱（ＥＤＸ）研究了摩擦表面元素组成及其可能物相。探讨了摩擦化学机理，认为化合物中的硫氰基团对摩擦学性能起主要作用，并在摩擦过程中发生类似于化学热处理中的硫氰共渗。     

连续驱动摩擦焊动态扭矩检测的新方法—VCMM法

连续驱动摩擦焊动态扭矩检测的新方法──ＶＣＭＭ法刘金合，罗键连续驱动摩擦焊扭矩是一个重要的工艺参数。摩擦焊扭矩是动态扭矩，具有时变性、速变性以及变化范围大等特点。现有的检测摩擦焊扭矩的方法均有一定的局限性’‘－’‘，本文提出了通过驱动主电机定子电压和...     

Microstructure and Mechanical Properties of Heat-treated GeSb_2Te_4 Thin Films

The effect of annealing on microstructure,adhesive and frictional properties of GeSb 2 Te 4 films were experimentally studied.The GeSb 2 Te 4 films were prepared by radio frequency(RF)magnetron sputtering,and annealed at 200℃and 340℃under vacuum circumstance,respectively.The adhesion and friction experiments were mainly conducted with a lateral force microscope(LFM)for the GeSb 2 Te 4 thin films before and after annealing.Their morphology and phase structure were analyzed by using atomic force microscopy(AFM)and X-ray Diffraction(XRD)techniques,and the nanoindention was employed to evaluate their hardness values.Moreover,an electric force microscope(EFM)was used to measure the surface potential. It is found that the deposited GeSb 2 Te 4 thin film undergoes an amorphous-to-fcc and fcc-to-hex structure transition;the adhesion has a weaker dependence on the surface roughness,but a certain correlation with the surface potential of GeSb 2 Te 4 thin films.And the friction behavior of GeSb 2 Te 4 thin films follows their adhesion behavior under a lower applied load.However,such a relation is replaced by the mechanical behavior when the load is relatively higher.Moreover,the GeSb 2 Te 4 thin film annealed at 340℃presents a lubricative property.