全文获取类型
收费全文 | 48067篇 |
免费 | 5481篇 |
国内免费 | 2818篇 |
专业分类
电工技术 | 8743篇 |
技术理论 | 1篇 |
综合类 | 4564篇 |
化学工业 | 2595篇 |
金属工艺 | 2659篇 |
机械仪表 | 3574篇 |
建筑科学 | 1798篇 |
矿业工程 | 1843篇 |
能源动力 | 1886篇 |
轻工业 | 1702篇 |
水利工程 | 854篇 |
石油天然气 | 1827篇 |
武器工业 | 579篇 |
无线电 | 10975篇 |
一般工业技术 | 5412篇 |
冶金工业 | 1913篇 |
原子能技术 | 504篇 |
自动化技术 | 4937篇 |
出版年
2024年 | 167篇 |
2023年 | 618篇 |
2022年 | 1111篇 |
2021年 | 1265篇 |
2020年 | 1409篇 |
2019年 | 1154篇 |
2018年 | 1168篇 |
2017年 | 1507篇 |
2016年 | 1767篇 |
2015年 | 1953篇 |
2014年 | 2827篇 |
2013年 | 2812篇 |
2012年 | 3842篇 |
2011年 | 4100篇 |
2010年 | 3140篇 |
2009年 | 3127篇 |
2008年 | 3037篇 |
2007年 | 3629篇 |
2006年 | 3222篇 |
2005年 | 2594篇 |
2004年 | 2046篇 |
2003年 | 1835篇 |
2002年 | 1532篇 |
2001年 | 1236篇 |
2000年 | 1026篇 |
1999年 | 846篇 |
1998年 | 629篇 |
1997年 | 519篇 |
1996年 | 444篇 |
1995年 | 395篇 |
1994年 | 331篇 |
1993年 | 245篇 |
1992年 | 176篇 |
1991年 | 151篇 |
1990年 | 112篇 |
1989年 | 88篇 |
1988年 | 63篇 |
1987年 | 53篇 |
1986年 | 37篇 |
1985年 | 26篇 |
1984年 | 27篇 |
1983年 | 7篇 |
1982年 | 11篇 |
1981年 | 11篇 |
1980年 | 9篇 |
1979年 | 11篇 |
1975年 | 6篇 |
1963年 | 4篇 |
1959年 | 5篇 |
1956年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 281 毫秒
11.
12.
13.
《International Journal of Hydrogen Energy》2021,46(69):34449-34462
Three-dimensional Bödewadt flow (fluid rotates at a large enough distance from the stationary plate) of carbon nanomaterial is examined. Single walled and multi walled CNTs are dissolved in water and gasoline oil baseliquids. Darcy-Forchheimer porous medium is considered. Stationary disk is further stretched linearly in radial direction. Heat transfer effect is examined in presence of radiation and convection. Effect of viscous dissipation is accounted. Entropy generation rate is studied. By using adequate transformation (von Kármán relations), the flow field equations (PDEs) are transmitted into ODEs. Solutions to these ODEs are constructed via implementation of shooting method (bvp4c). In addition to Entropy generation rate, Bejan number, heat transfer rate (Nusselt number), skin friction and temperature of fluid are examined through involved physical parameters. Axial component of velocity intensifies with increment in nanoparticles volume fraction and ratio of stretching rate to angular velocity parameter while it decays with higher porosity parameter. Higher nanoparticles volume fraction and porosity parameter lead to decay in radial as well as tangential component of velocity. However it enhances with higher ratio of stretching rate to angular velocity parameter. Temperature of fluid directly varies with higher ratio of stretching rate to angular velocity parameter, radiation parameter, Eckert number, Biot number and nanoparticles volume fraction. Rate of Entropy generation is reduced with higher estimations of porosity parameter, nanoparticles volume fraction and radiation parameter. Skin friction coefficient decays with higher porosity parameter and ratio of stretching rate to angular velocity parameter. Intensification in porosity parameter, nanoparticles volume fraction and Biot number leads to higher Nusselt number. Prominent impact is shown by multiple-walled CNTs with gasoline oil basefluid than single-walled CNTs with water basefluid. 相似文献
14.
《Ceramics International》2019,45(15):18501-18508
The modification and tuning features of nanostructured films are of great interest because of controllable and distinctive inherent properties in these materials. Here, nanocrystalline MoS2 films were fabricated on the stainless steels by a radio frequency magnetron sputtering at ambient temperature. X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction and Raman scattering spectroscopy were used to study the chemical state, chemical composition, crystal structure and vibrational properties of the fabricated MoS2 films. The bias voltage dependent structural evolution and its influence on the optical properties of MoS2 nanocrystalline films were systematically investigated. Besides, the residual stresses of MoS2 nanocrystalline films were explored by employing sin2ψ approach. X-ray diffraction demonstrates that the nanocrystalline MoS2 films have single-phase hexagonal crystal structure. All MoS2 films are polycrystalline in nature. The bandgap values are found to be intensively dependent on bias voltage. Our findings show that the nanocrystalline MoS2 films with different physical properties and intense quantum confinement effect can be realized through adjusting bias voltages. This work may provide deep insight for realizing transitional metal dichalcogenide-based nanostructured film optoelectronic devices with tunable physical properties through a traditional, very cost-effective, and large-scale fabrication method. 相似文献
15.
This paper investigates a renewable energy resource’s application to the Load–Frequency Control of interconnected power system. The Proportional-Integral (PI) controllers are replaced with Proportional-Integral Plus (PI+) controllers in a two area interconnected thermal power system without/with the fast acting energy storage devices and are designed based on Control Performance Standards (CPS) using conventional/Beta Wavelet Neural Network (BWNN) approaches. The energy storing devices Hydrogen generative Aqua Electroliser (HAE) with Fuel cell and Redox Flow Battery (RFB) are incorporated to the two area interconnected thermal power system to efficiently damp out the electromechanical oscillations in the power system because of their inherent efficient storage capacity in addition to the kinetic energy of the generator rotor, which can share the sudden changes in power requirements. The system was simulated and the frequency deviations in area 1 and area 2 and tie-line power deviations for 5% step- load disturbance in area 1 are obtained. The comparison of frequency deviations and tie-line power deviations of the two area interconnected thermal power system with HAE and RFB designed with BWNN controller reveals that the PI+ controller designed using BWNN approach is found to be superior than that of output response obtained using PI+ controller. Moreover the BWNN based PI+ controller exhibits a better transient and steady state response for the interconnected power system with Hydrogen generative Aqua Electroliser (AE) unit than that of the system with Redox Flow Battery (RFB) unit. 相似文献
16.
目的研究热风辅助射频(hot air-assisted radio frequency,HA-RF)干燥过程中维生素C随温度变化的降解动力学模型。方法在6.5 cm极板间距和60℃热风系统条件下进行HA-RF干燥,重点研究胡萝卜丁中维生素C在干燥过程中的降解动力学,包括脱氢抗坏血酸(dehydroascorbic acid,DHAA)和抗坏血酸(ascorbic acid,AA)。总维生素C含量采用2,4-硝基苯肼分光光度法测定,AA采用2,6-二氯吲哚酚滴定法测定。结果HA-RF干燥过程中维生素C的降解规律符合一级可逆模型,其降解活化能为40.54 kJ/mol。DHAA活化能为35.83 kJ/mol,表明DHAA的稳定性低于AA。结论本研究使用的干燥温度为62.5~77.5℃,较高的干燥温度下维生素C降解速率较高,较低处理温度下的降解过程具有更好的模型适应度(R2>0.98)。 相似文献
17.
Su-Il Ri Song-Il Hong Jong-Chol Kim Ju-Hyok Wi 《International Journal of Hydrogen Energy》2021,46(5):3319-3328
We investigated some properties of the hydride Mg2FeH6 substituted with yttrium by a first principles calculation. Some experimental results showed that 4d transition metal, yttrium serves as a good catalyst for magnesium based hydrogen storage alloys, but there are a few theoretical studies about magnesium based hydrides substituted with it. Mg2FeH6 is regarded as a cheaper material than pure MgH2, while it is crystalized into Fm3m structure (space group 225). Although it has high hydrogen storage capacity, many investigations have not been devoted to it due to its extremely high thermodynamic stability. The yttrium substituted Mg2FeH6 exhibits very low energy of formation, and its desorption temperature, 75 °C is very suitable for practical hydrogen storage applications. Our results showed that Mg2FeH6 is destabilized effectively by yttrium substitution and introducing vacancy defects has additive effect to the improvement of dehydrogenation performance. 相似文献
18.
Fundamental Evaluation of Power Supply and Rectifiers for Wireless Power Transfer Using Magnetic Resonant Coupling 下载免费PDF全文
This paper provides a fundamental analysis of a power supply and rectifiers for wireless power transfer using magnetic resonant coupling (MRC). MRC enables efficient wireless power transfer over middle‐range transfer distances. MRC for wireless power transfer should operate at a high frequency in the industry science medical band, such as 13.56 MHz, because the size of the transfer device decreases at higher transfer frequencies. Therefore, the output frequency of the power supply on the transmitting side should be 13.56 MHz. In addition, the rectifier on the receiving side is operated at a high frequency. This paper focuses on the reflected power in the power supply and rectifiers. Thus, the parametric design method is clarified for the power supply, including a low‐pass filter to match the output, the impedance of the power supply with the characteristic impedance of the transmission line. In addition, the effects on the rectifiers of silicon carbide and gallium nitride diodes are confirmed by performing an experiment and a loss analysis. 相似文献
19.
《Ceramics International》2022,48(21):31491-31499
In this study, an all-solid-state electrochromic device (ECD) with the structure of ITO/WO3/Al2SiO5/NiOx/ITO was prepared, and the effect of the Al2SiO5 solid electrolyte thicknesses on the opto-electrical performance was investigated. The microstructure and surface morphology were characterized using XRD, SEM and AFM, and the surface morphology and degree of surface looseness demonstrate a significant influence on the opto-electrical properties of ECDs. The charge transfer dynamics at the solid-solid interface were characterized using EIS to obtain an ionic conductivity of 4.637 × 10-8 S/cm. CV, CA and UV–Visible spectra were employed to record the in situ electrochemical and optical properties. The results revealed that the highest optical modulation was 44.58%, the coloring and bleaching times were 14.8 s and 3.7 s, and the highest coloring efficiency was 98.17 cm2/C, which indicates that excellent opto-electrical properties were obtained. When the thickness increases, the degree of surface dense morphology transforms, and the loose morphology is more favorable for ion conductivity, which improves the opto-electrical properties. The results in this study provide insights into the understanding of Al3+-based all-solid-state ECDs, which promote the exploration of new types of Al3+ ionic conductors for all-solid-state ECDs. 相似文献
20.
《Ceramics International》2022,48(13):18658-18666
Samples of the ternary system MgO–Al2O3–SiO2 with stoichiometric composition in relation to α-cordierite (Mg2Al4Si5O18), consisting of 22.2 mol% MgO, 22.2 mol% Al2O3, and 55.6 mol% SiO2, were activated in a low energy mill with a constant speed of 100 rpm, in an aqueous medium. The precursors used were corundum (Al2O3), silica gel HF254 type 60 (SiO2), and periclase (MgO). The objective of the present study was to evaluate the effect of mechanochemical activation on the solid-state synthesis of α-cordierite, using a low energy ball mill. Another objective was to shed light on the effect of mechanochemical activation on the steps of α-cordierite formation. For this end several grinding conditions were evaluated, varying the time and mass ratio of precursors/grinding elements, as well as calcination at different temperatures between 950 °C and 1350 °C for 2 h. The samples were analyzed for the determination of the formed phases by Infrared (IR) and X-ray Diffraction (XRD). The phases identified in uncalcined samples were brucite (Mg(OH)2), forsterite (Mg2SiO4), enstatite (MgSiO3), spinel (MgAl2O3), amorphous silica (SiO2), corundum (α-Al2O3), and zirconia (monoclinic and tetragonal ZrO2). The lowest temperature corresponding to the formation of α-cordierite (α-Mg2Al4Si5O18) was 1150 °C and a considerable amount of this phase (16.2%) was observed at this temperature, for the sample with the higher mechanochemical activation. In a solid-state reaction, α-cordierite is normally obtained at around 1400 °C, therefore, the formation of this phase at 1150 °C confirms that the mechanochemical activation method, using a low-cost ball mill, is efficient in reducing the solid-state reaction temperature. 相似文献